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Molybdenum-base alloy and its preparing method

A molybdenum-based alloy and mixture technology, which is applied to the composition field of molybdenum-based alloys, can solve the problems of easy occurrence of cracks, decrease of alloy strength and other properties, influence of intermolecular diffusion, etc., and achieve the effect of improving bonding force

Inactive Publication Date: 2005-10-05
JINZHOU NEW CHINA DRAGON MOLY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the particle size of the active component is too large, the concentration of impurities on the unit crystal interface will increase, and the segregation of elements such as atomic oxygen and carbon in the impurities on the grain boundary will increase the tendency of intergranular fracture, resulting in The strength and other properties of the alloy are reduced; at the same time, the large particle size can also affect the diffusion between molecules, so that it cannot be fully alloyed during the sintering process, and there are large pores in the alloy matrix, which is prone to cracks and serious affect its service life

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Embodiment 1, get TiC powder 0.65kg, ZrH 2 Powder 0.15kg, CeC 2 Powder 0.5kg, Y 2 o 3 Powder 0.25kg, C powder 0.2kg, Mo powder 3.5kg, stir evenly with a shovel in a stainless steel pan, sieve, put into a small V-shaped mixer and mix for 90 minutes. Take 44.75kg of Mo powder and the added material after initial mixing, put it in the mixer and mix for 36 hours. The obtained alloy powder is sampled and analyzed at multiple points, and if there is no segregation phenomenon, manual charging is used. Weigh the molybdenum alloy powder and put it into the rubber sleeve of the head product, tamp and seal it, and carry out isostatic pressing. The compression pressure is 200Mpa, and the pressure is maintained for 5 minutes. The pressed parts that pass the density inspection are turned into plug blanks with a certain taper shape. Vacuum intermediate frequency sintering at 2000°C, heat preservation for 3 hours, to obtain molybdenum plug products for piercing and rolling alloy ...

Embodiment 2

[0019] Embodiment 2: get TiH 2 Powder 0.35kg, ZrH 2 Powder 0.1kg, CeC 2 Powder 0.25kg, Y 2 o 3 0.2kg of powder C, 0.1kg of C powder, and 2kg of Mo powder were pre-mixed in the mixer for 80 minutes, and 47kg of Mo powder and pre-mixed additives were taken and mixed in the mixer for 32 hours. After sampling and analysis without segregation, weigh the molybdenum alloy powder and put it into the crucible or the rubber sleeve of the electrode product, and carry out isostatic pressing with a pressing pressure of 180Mpa and hold the pressure for 3 minutes. After turning and compacting the blank, vacuum medium frequency sintering at 1980°C and heat preservation for 4 hours to obtain molybdenum alloy crucible or electrode products.

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PUM

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Abstract

This invention relates to a Mo-base alloy and its preparation method, and the components of the Mo-base alloy are: 0.1-0.8% hydrozirconium, 0.1-0.8% carbon, 0.4-2.2% titanium carbon with its grain size less than 0.6 micron, and 0.5-2.5% rare earth oxide with grain size less than 40 nm, and the rest is Mo. The above materials pass through homogeneity, pressing and agglomeration to form the Mo-base alloy. The Mo-base alloy can strength the solid solution and make it become dispersed carbonizing phase to improve the sticking strength of crystal lattices.

Description

Technical field: [0001] The invention relates to a molybdenum-based alloy composition and a method for preparing the composition, in particular to a molybdenum-based alloy composition suitable for the mandrel plug of a steel pipe rolling mill and a crucible in the rare earth smelting industry and the preparation thereof Methods. Background technique: [0002] The detection data of pure molybdenum shows that the intensity δ of pure polonium at 20°C B =40kg / mm 2 About, the strength at 1000°C is 7kg / mm 2 , while the strength at 2000°C is only 1.2kg / mm 2 , Therefore, pure molybdenum does not have unique physical properties such as high temperature strength and oxidation resistance. But molybdenum is a metal that can maintain the high temperature strength and corrosion resistance of its alloys, that is, molybdenum can have unique physical properties in the form of alloys, for example, mandrel plugs and crucibles used in steel pipe rolling mills are made of molybdenum alloys ...

Claims

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Application Information

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IPC IPC(8): B22F3/12C22C1/05C22C27/04
Inventor 王治国张新辉孔祥华
Owner JINZHOU NEW CHINA DRAGON MOLY
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