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Open-cell foam of ethylene-propylene-diene rubber

A technology of EPDM rubber and foam, which is applied in the field of continuous cell foam of EPDM rubber, which can solve problems such as difficult filling, high proportion of independent cells, and rupture of continuous cell foam, and achieve resilience small, well-filling effect

Active Publication Date: 2006-07-12
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the EPDM foam that forcibly generates continuous cells in this way is actually a foam with semi-closed and semi-continuous cells. The proportion of independent cells is high, and the resilience cannot be sufficiently reduced. Such an EPDM foam is filled as a sealing material. When there is a gap, there is a problem that it is difficult to fill the gap
[0006] In addition, since such an EPDM foam is to form open cells after forming a foam with independent cells, when it is highly vulcanized during foaming, it may become difficult to generate open cells and the foam may cracked problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] In the formula shown in Table 1, first mix 100 parts by weight of EPDM (manufactured by Mitsui Chemicals Co., Ltd., trade name "EPT4021", diene content 8.0% (5-ethylidene-2-norbornene), ethylene content 51 %), 100 parts by weight of heavy calcium carbonate (manufactured by Maruo Calcium Co., Ltd., trade name "heavy calcium carbonate"), 40 parts by weight of paraffin-based process oil (manufactured by Idemitsu Kosan Co., Ltd., trade name "Dianna proses PW-90 ”), 50 parts by weight of pitch (manufactured by Nippon Oil Corporation, trade name “Pro-n Asphalt”), 10 parts by weight of carbon black (manufactured by Asahi Ka-bon Co., Ltd., trade name “Asahi Ka-bon #50”) , 5 parts by weight of zinc oxide (manufactured by Mitsui Kinzoku Industries Co., Ltd., trade name "zinc oxide 2 kinds"), 3 parts by weight of stearic acid (manufactured by NOF Corporation, trade name "powder stearic acid"), which were used After kneading in a Banbury mixer, the mixture was further kneaded by a ...

Embodiment 2

[0065] In addition to changing 25 parts by weight of azodicarbonamide (manufactured by Yongwa Chemical Industry Co., Ltd., trade name "ビニホ-ルAC#LQ") to 20 parts by weight, sodium bicarbonate (manufactured by Yongwa Chemical Industry Co., Ltd., trade name " 3 parts by weight of FE-507") was changed to 15 parts by weight; In addition, by the same operation as in Example 1, an EPDM continuous cell foam with an expansion ratio of 10 was obtained.

Embodiment 3

[0067] In addition to changing 25 parts by weight of azodicarbonamide (manufactured by Yonghe Chemical Industry Co., Ltd., trade name "ビニホ-ルAC#LQ") to 20 parts by weight of N, N'-dinitrosopentamethylenetetramine and urea (Celura-CK#54, foaming agent / foaming aid: 1 / 1 (weight ratio) mixture), sodium bicarbonate (manufactured by Eiwa Chemical Industry Co., Ltd., trade name "FE-507") 3 parts by weight were changed to 5 parts by weight, and no urea-based foaming aid (manufactured by Yongwa Chemical Industry Co., Ltd., trade name "Selpe-Stock K-5") was added, and the foaming was obtained by the same operation as in Example 1. EPDM continuous cell foam with a multiple of 15.

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PUM

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Abstract

Open-cell foam of ethylene-propylene-diene rubber that can convert to open-cell foams at the foaming of EPDM, rather than after the foaming of the same, and can produce low impact resiliency and improved filling capability. After 0.1·40 parts by weight of organic foaming agent, 2-40 parts by weight of inorganic foaming agent, and 2-40 parts by weight of foam auxiliary agent per 100 parts by weight of ethylene-propylene-diene rubber are mixed, the mixture is vulcanized and foamed to thereby produce open-cell foam of ethylene-propylene-diene rubber. This open-cell foam of ethylene-propylene-diene rubber has low impact resilience and good sealing performance so that it can be used as sealing materials of a variety of industrial products.

Description

technical field [0001] The invention relates to an EPDM continuous-cell foam, in particular to an EPDM continuous-cell foam suitable for use as a sealing material for various industrial products. Background technique [0002] Conventionally, as a sealing material for various industrial products, an EPDM foam obtained by foaming ethylene-propylene-diene rubber (hereinafter referred to as EPDM) with a foaming agent is known from the viewpoint of durability. [0003] The blowing agent that makes described EPDM foam, can use N-nitroso compounds such as azodicarbonamide (ADCA) and N,N'-dinitrosopentamethylenetetramine (DPT), etc. base compounds. (Refer to, for example, Japanese Patent Application Laid-Open No. 2003-160685) [0004] EPDM foams using such blowing agents generally form closed cells. Since the closed-cell foam has high resilience, in order to use such an EPDM foam as a sealing material, closed cells are forcibly generated using a roller or a needle to reduce the r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08J9/04C08K5/23
CPCC08J9/06C08J9/0023C08J9/08C08J2205/05C08J2323/16
Inventor 来島誠治
Owner NITTO DENKO CORP
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