Supercharge Your Innovation With Domain-Expert AI Agents!

Retroreflection sheet and outer illumination type illumination system

一种逆反射、薄片的技术,应用在反射式反射器、化学仪器和方法、仪器等方向,能够解决成本升高、无法满足市场的需求、光量减少等问题

Active Publication Date: 2006-09-27
KIWA CHEM IND CO LTD
View PDF6 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

That is, there is a problem that since the car driving in the leftmost lane observes the light irradiated from the external light projector at a small viewing angle, the amount of light returned from the sign is relatively large, so it can be seen clearly, but it is difficult for driving The viewing angle of the car in the far right lane is very large, so the amount of light returning from the sign is greatly reduced and it looks very dark
[0014] In addition, when the microprism-type retroreflective sheeting is exposed to light from an oblique or lateral direction, it is difficult to maintain the retroreflective performance, so the wave reflector makes the shape of the aforementioned microprism-type retroreflective sheeting wave-shaped, and the light irradiated from oblique or lateral directions is opposite to each other. As the incident angle of the aforementioned retroreflective sheeting decreases to allow light to enter, the brightness of the retroreflection increases as a result, but the retroreflective sheeting itself does not have wide-angle performance.
In addition, it is extremely difficult to print on the wave reflector by methods such as screen printing in order to shape it into a wave shape, so there is a problem that the necessary information is incorporated into the retroreflective sheet before the wave shape is formed, and then the shaping process must be performed. , which has the problem of raising the cost of
In addition, the inner surface of the wave reflector has a large wavy depression, and when it is attached to the side wall of the road, impurities such as garbage will be stored in the depression, and there is also a problem that the appearance of the film will be significantly damaged.
[0015] In addition, the aforementioned wide-angle prism-type retroreflective sheeting (VIP) is not designed to irradiate light from oblique or lateral directions and exhibit retroreflective performance at relatively large viewing angles.
For example, at an observation angle of 4° and an incident angle of 40° or more, there is a problem that retroreflection performance can no longer be maintained
[0016] In addition, in the case of a wide-angle prism type retroreflective sheeting for side display (EV-9010 manufactured by 3M Company), when the observation point is located in the lateral direction (display direction) of the sheeting, even at a large observation angle and a large incidence Retroreflection performance can be maintained at any angle, but when the observation point is in the longitudinal direction (up and down direction) of the sheet, there is a problem that if the incident angle exceeds 60°, the retroreflection performance will be extremely low.
[0022] In addition, as the reflective sheet proposed in the aforementioned Patent Document 4 ( Figure 8 As shown in D), if the focus layer is formed so that the side surface of the glass bulb retroreflects the reflected light as the reflected light g2 approximately parallel to the incident light g1, the incident light f1 from the front direction diffuses from the incident direction as reflection The problem of light f2 retroreflection
Therefore, the status quo is that even if the reflective performance can be obtained at a large viewing angle, it is far from meeting the Japanese Industrial Standard (JIS) and overseas marking standard values ​​of the reflective performance required in the frontal direction with a relatively small viewing angle.
Therefore, the use is limited, and it cannot be used for general traffic signs, and it is also difficult to be used for license plates of automobiles, etc., so that it cannot meet the needs of the market in terms of practicality.
[0023] As mentioned above, the existing lens-enclosed retroreflective sheeting has a large angle dependence, and cannot sufficiently ensure wide-angle reflection performance at relatively large observation angles and relatively large incident angles.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Retroreflection sheet and outer illumination type illumination system
  • Retroreflection sheet and outer illumination type illumination system
  • Retroreflection sheet and outer illumination type illumination system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0133] Shrinkage in the curl direction of the annealed biaxially oriented polyethylene terephthalate film used as the first surface layer (manufactured by Teijin DuPont Film, trade name MX534) at 150°C for 30 minutes Ratio of 0.3%, film thickness of 97 μm) was coated with the following glass sphere dispersion resin solution as a focus layer.

[0134] (1) Polyvinyl butyral resin solution: 75.0 parts (degree of polymerization: 680, polyvinyl alcohol unit 23% by weight, glass transition temperature 66°C, solid content 21%, n-butanol / toluene 1:1)

[0135] (2) Super Beckamine J-820-60: 3.3 parts (manufactured by Dainippon Ink Chemical Industry Co., Ltd., butylated melamine resin, solid content 60%)

[0136] (3) Beckamine P-198: 0.2 part (manufactured by Dainippon Ink Chemical Industry Co., Ltd., curing accelerator, acid value 400)

[0137] (4) BYK-053: 0.5 part (manufactured by BYK Chemie Japan, alkyl vinyl ether copolymer, antifoaming agent)

[0138] (5) Polysider W-360-ELS: 7.0...

Embodiment 2

[0150] Annealed biaxially oriented polyethylene terephthalate film (manufactured by TeijinDuPontFilm, trade name MX534, shrinkage in the curling direction of the film when heated at 150°C for 30 minutes, 0.3%, film thickness 97 μm) On, the following glass ball resin dispersion solution was coated.

[0151] (1) Polyvinyl butyral resin solution: 98.0 parts (polymerization degree: 1100, polyvinyl alcohol unit 18% by weight, glass transition temperature 76°C, solid content 16%, n-butanol / toluene 1:1)

[0152] (2) Beckamine P-196-M: 3.0 parts (manufactured by Dainippon Ink Chemical Industry Co., Ltd., butylated urea resin, solid content 60%)

[0153] (3) Beckamine P-198: 0.1 part (manufactured by Dainippon Ink Chemical Industry Co., Ltd., curing accelerator, acid value 400)

[0154] (4) BYK-053: 0.5 part (manufactured by BYK Chemie Japan, alkyl vinyl ether copolymer, antifoaming agent)

[0155] (5) PolysiderW-360-ELS: 2.0 parts (manufactured by Dainippon Ink Chemical Industry Co....

Embodiment 3

[0191] In the same manner as in Example 1, a glass bead-dispersed resin solution for a focus layer was produced. Next, in order to manufacture yellow, red, orange, green, and blue retroreflective sheeting, the following colorants were mixed with the aforementioned glass bead-dispersed resin solutions for focus layers of different colors.

[0192] (1) Focus layer glass sphere dispersion resin solution for yellow: 20% solution of toluene / n-butanol (1 / 1) of AWB-CP201 ​​orange (manufactured by Nikko Bics: pigment concentration 40%) of 0.2 g, AWB of 3.5 g -Toluene / n-butanol (1 / 1) 20% solution of CP310 yellow (manufactured by Nikko Bics: pigment concentration 50%)

[0193] (2) Red focal layer glass sphere dispersion resin solution: 20% solution of toluene / n-butanol (1 / 1) of AWB-CP102 red (manufactured by Nikko Bics: pigment concentration 50%) of 5.5 g

[0194] (3) Focus layer glass sphere dispersion resin solution for orange: 20% solution of toluene / n-butanol (1 / 1) of 4.9 g of AWB-CP...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
glass transition temperatureaaaaaaaaaa
angle of incidenceaaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The retroreflective sheet of the present invention comprises a surface layer ( 1 ) including at least one layer, a focusing layer ( 2 ) containing glass spheres ( 3 ), and a metal reflective layer ( 4 ) on the back side of the focusing layer ( 2 ), wherein the glass spheres ( 3 ) are disposed at random locations in the thickness direction of the focusing layer ( 2 ). The external illumination system of the present invention comprises a sign having a sign face including the above-mentioned retroreflective sheet, and an external illumination source, and the distance from the illumination source to the sign face is within a range of at least 1 m and no more than 100 m. The present invention thereby provides a retroreflective sheet and an external illumination system with which wide-angle reflective performance with a wider incidence angle and observation angle can be ensured.

Description

technical field [0001] The invention relates to a retroreflective sheet and an externally illuminated lighting system used for road signs, guide signs, safety guide sign boards, safety instructions, billboards and the like. Background technique [0002] Retroreflection (retroreflection) sheets are widely used in various purposes such as traffic signs, guide signs, warning signs, regulatory signs, car license plates, and billboards. As an example of this retroreflective sheet, there is a so-called enclosed lens type retroreflective sheet, which is laminated with a surface layer formed of at least one layer, high refractive index glass beads, and a focus layer (also called a focus resin layer) in the following order. , Metal reflective layer. In addition, as another structure, there is a retroreflective sheet called a capsule lens type, which is composed of a plurality of transparent balls provided with mirrors in the lower hemisphere, a supporting resin sheet holding the afo...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/128B32B7/02B32B15/04B32B15/08B32B27/18C08J7/043
CPCC08J2423/06C08J7/04C08J2367/00G02B5/128C08J7/043G02B5/12
Inventor 汤川重男冲秀之浦由宜
Owner KIWA CHEM IND CO LTD
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More