Hydrogenation for producing high-bioctyl-value and low-freezing-point diesel oil
A technology for the production of high cetane and diesel oil, which is applied in the direction of refining to remove heteroatoms, etc., and can solve the problems of reducing the yield of diesel products
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Embodiment 1
[0030] The raw material oil A and hydrogen are mixed at a hydrogen partial pressure of 6.4MPa, a reaction temperature of 360°C, and a liquid hourly space velocity of 1.0h -1 , volume hydrogen oil ratio 700Nm 3 / m 3 Under certain conditions, the first reaction zone is in contact with the hydrofining catalyst, and the reaction effluent does not separate hydrogen sulfide and ammonia into the second reaction zone. The hydrogen partial pressure is 6.4MPa, the reaction temperature is 360°C, and the liquid hourly space velocity is 1.5h. -1 , volume hydrogen oil ratio 700Nm 3 / m 3 The reaction effluent from the second reaction zone is cooled and separated, and the separated liquid product enters the fractionation system, and the hydrogen-rich hydrogen is recycled back to the reactor.
[0031] The reaction conditions and product properties are listed in Table 2. It can be seen from Table 2 that the cetane number of the diesel product is 38.8, which is 10.9 units higher than that of...
Embodiment 2
[0033] The raw material oil B and hydrogen are mixed at a hydrogen partial pressure of 6.4MPa, a reaction temperature of 365°C, and a liquid hourly space velocity of 1.34h -1 , volume hydrogen oil ratio 800Nm 3 / m 3 Under certain conditions, the first reaction zone is in contact with the hydrorefining catalyst, and the reaction effluent does not separate hydrogen sulfide and ammonia into the second reaction zone. At a hydrogen partial pressure of 6.4MPa, a reaction temperature of 370°C, and a liquid hourly space velocity of 2.0h -1 , volume hydrogen oil ratio 800Nm 3 / m 3 The reaction effluent from the second reaction zone is cooled and separated, and the separated liquid product enters the fractionation system, and the hydrogen-rich hydrogen is recycled back to the reactor.
[0034] The reaction conditions and product properties are listed in Table 2. It can be seen from Table 2 that the cetane number of the diesel product is 41.2, which is 13 units higher than that of th...
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