Sealing material for cap and process for producing cap using the same
A technology for sealing materials and manufacturing methods, applied in the directions of sealing, transportation, packaging, packaging, etc., which can solve the problems of difficulty in ensuring the balance of lipophilicity and hydrophilicity, swelling of polyurethane elastomers, and low affinity of lower alcohols, and achieve swelling It has the effect of low absorbency and fragrance, less exudate, and high production efficiency.
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[0078] Hereinafter, the present invention will be described in more detail by way of examples, but the present invention should not be construed as limited to these examples.
[0079] In the following synthesis examples, "%" all means "mass %".
[0080] The measurement of the isocyanate group content was performed in accordance with JIS K7301, and the measurement of the hydroxyl value was performed in accordance with the method prescribed in JIS K1601.
[0081] Raw materials used in synthesis examples and the like are as follows.
[0082] HDI: Hexamethylene diisocyanate
[0083] PTG-1000SN: polytetramethylene ether glycol, hydroxyl value = 112 mgKOH / g, average number of functional groups = 2, manufactured by Hodogaya Chemical Industry Co., Ltd.
[0084] P-1010: adipate-based polyester diol, hydroxyl value = 112 mgKOH / g, average number of functional groups = 2, manufactured by Kurare Co., Ltd.
[0085] F-510: adipate-based polyester triol, hydroxyl value = 336 mgKOH / g, avera...
Synthetic example 1
[0093] 70.7g of HDI, 7.6g of 1,3-BG, 6.6g of NPG and 15.2g of hydrogenated bisphenol A were added to the reaction vessel and reacted at 70°C for 5 hours to obtain a viscose with an average functional group number of 2 and an isocyanate group content of 17.6%. thick liquid. This is called polyisocyanate A.
Synthetic example 2
[0095] 178.9 g of HDI and 21.1 g of 1,3-BG were added to a reaction vessel, and reacted at 70° C. for 5 hours to obtain a viscous liquid having an average functional group number of 2 and an isocyanate group content of 19.7%. This is called polyisocyanate B.
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