The invention discloses a composite
fiber for in-situ growth of a COF
coating on a
nickel-
titanium matrix and a preparation method and application of the composite
fiber. The method comprises the following steps: firstly, carrying out
acid etching and hydrothermal oxidation treatment on
nickel-
titanium fibers, and forming a
phosphorus-doped
titanium oxide nanosheet substrate on the surfaces of the
nickel-titanium fibers; the COFDVA-ETTA
coating is prepared by the following steps: firstly, preparing a COFDVA
monomer, then performing amino functionalization through
silanization, sequentially
grafting an
aldehyde group
monomer DVA, and finally performing
Schiff base reaction with an amino
monomer ETTA under the assistance of ultrasonic
waves to quickly construct the COFDVA-ETTA
coating in situ. According to the coating, efficient and
selective adsorption of various BPs is achieved through
hydrogen bonds, pi-pi accumulation and hydrophobic interaction between functional groups such as
imine bonds and vinyl of the coating and
bisphenol compounds. When the
fiber is used as a
solid-phase microextraction fiber to be combined with
high performance liquid chromatography, the fiber shows high sensitivity, wide
linear range, low
detection limit and good precision in detection of five BPs, and the
fiber coating is high in stability, excellent in
reusability and suitable for rapid analysis and detection of trace BPs in an
environmental water sample.