Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst and preparation method thereof

An oxidation catalyst and cotton fiber technology, applied in the field of indoor air purification, can solve the problems of high equipment requirements, complex process, increased air resistance, etc., and achieve the effect of avoiding easy breaking, firm bonding and small air resistance

Active Publication Date: 2017-05-31
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, from a practical point of view, the catalysts prepared in the above published patents are mostly made of ordinary porous inorganic nanoparticles (such as titanium dioxide, aluminum oxide, molecular sieves, cerium oxide and silicon oxide, etc.) as carriers. Filled purification equipment needs to be pressed into tablets or further loaded on other bulky carriers before it can be used, which will complicate the process, and there are problems such as reduced catalytic activity, large air resistance and easy fall off of the catalyst
In order to overcome the above defects, the patent CN201410015867.4 TiO prepared by electrospinning 2 As a carrier, the supported noble metal/TiO 2 Composite catalyst, the newly prepared catalyst does not need to be reloaded, and

Method used

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  • Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst and preparation method thereof
  • Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst and preparation method thereof
  • Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0029] (1) First, dissolve butyl titanate in absolute ethanol, add acetylacetone, stir to form a transparent solution, then add dropwise to an acidic (pH=2) aqueous solution containing 0.01% PVA, and stir for 6 days to obtain a stable solution TiO 2 Sol, wherein the molar ratio of water, absolute ethanol, acetylacetone and butyl titanate is =100:2:0.5:0.5;

[0030] (2) Soak absorbent cotton in TiO 2 In the sol, the soaking time is 5min, in which cotton and TiO 2 The mass ratio is 1:2.6; after being separated by the filter, first dry at 60°C for 5 minutes, then at 115°C for 30 minutes, and repeat the above process twice, the final drying temperature is 60°C, and the drying time is 12h. Get TiO 2 / Cotton fiber composite base material.

[0031] (3) add complexing agent trisodium citrate in the palladium nitrate solution again, stir well, the TiO obtained in the step (2) 2 / Cotton fiber composite base material is dispersed in the above-mentioned mixed solution and soaked for...

Embodiment 2

[0034] (1) First, dissolve butyl titanate in absolute ethanol, add acetylacetone, stir to form a transparent solution, then add dropwise to an acidic (pH=2) aqueous solution containing 0.01% PVA, and stir for 6 days to obtain a stable solution TiO 2 Sol, wherein the molar ratio of water, acid, absolute ethanol, acetylacetone and butyl titanate is =100:2:0.1:0.1;

[0035] (2) Soak absorbent cotton in TiO 2 In the sol, the soaking time is 5min, in which cotton and TiO 2 The mass ratio is 1:2. After being separated by the filter screen, first dry at 60°C for 5 minutes, then at 110°C for 40 minutes, and repeat the above process twice. The last drying temperature is 60°C, and the drying time is 12 hours. Get TiO 2 / Cotton fiber composite base material.

[0036] (3) add complexing agent trisodium citrate in the palladium nitrate solution again, stir well, the TiO obtained in the step (2) 2 / Cotton fiber composite base material is dispersed in the above-mentioned mixed solution...

Embodiment 3

[0038] (1) First, dissolve butyl titanate in absolute ethanol, add acetylacetone, stir to form a transparent solution, then add dropwise to an acidic (pH=2) aqueous solution containing 0.01% PVA, and stir for 6 days to obtain a stable solution TiO 2 Sol, wherein the molar ratio of water, absolute ethanol, acetylacetone and butyl titanate is =100:2:0.5:0.5;

[0039] (2) Soak absorbent cotton in TiO 2 In the sol, the soaking time is 10min, in which cotton and TiO 2 The mass ratio of TiO is 1:3. After being separated by the filter screen, the drying time is 10h at 80°C to obtain TiO 2 / Cotton fiber composite base material;

[0040] (3) add complexing agent trisodium citrate in the palladium nitrate solution again, stir well, the TiO obtained in the step (2) 2 / Cotton fiber composite base material is dispersed in the above-mentioned mixed solution and soaked for 5min, wherein palladium nitrate is relative to TiO in terms of palladium 2 The quality of / cotton fiber composite b...

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Abstract

The invention relates to a Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst and a preparation method thereof. The catalyst is prepared from a cotton fiber carrier, a TiO2 surface coating and a Pd active ingredient dispersed in the surface of the TiO2 coating; the cotton fiber carrier is absorbent cotton fiber; the TiO2 coating is a nano TiO2 coating of which the grain size ranges from 1nm to 10nm; the Pd active ingredient exists in a zero valence form, the grain size of the Pd active ingredient ranges from 1nm to 10nm and the loading capacity of the Pd active ingredient is 0.05-3wt%. The Pd/TiO2/cotton fiber composite formaldehyde indoor temperature oxidation catalyst has the characteristics of graded middle and large hole structure, light weight and flexibility, Pd and the TiO2 coating as well as carrier cotton fiber are combined firmly, the active ingredient simple substance Pd is well dispersed in the surface of the TiO2 coating and is low in grain size, formaldehyde can be efficiently subjected to catalytic decomposition at indoor temperature, the use amount of noble metal is low, the air resistance is low, and the catalyst can be used in various air purifiers.

Description

technical field [0001] The invention belongs to the field of indoor air purification, in particular to a Pd / TiO 2 Cotton fiber composite formaldehyde room temperature oxidation catalyst and preparation method thereof. Background technique [0002] With the rapid development of urbanization in my country and the rise of decoration fever, indoor formaldehyde pollution is becoming more and more serious. It is one of the most important indoor pollutants and has great toxicity. At present, eliminating indoor formaldehyde pollution has become a hot research topic in the field of environmental governance. Among the existing formaldehyde removal methods, the room temperature catalytic oxidation method is better than other methods (adsorption method, absorption method, anion oxidation method, ozone catalytic oxidation method, biological filtration / plant purification method, low temperature plasma method and photocatalytic oxidation method, etc.) It has unique advantages, it can be ...

Claims

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Application Information

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IPC IPC(8): B01J31/38B01J35/06B01J35/10B01J37/02B01D53/86
CPCB01D53/8668B01D2259/4508B01J31/38B01J35/0073B01J35/06B01J35/10B01J37/02
Inventor 聂龙辉汪杰
Owner HUBEI UNIV OF TECH
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