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Composite carrier of metal fiber and inorganic fiber and preparation method

A technology of inorganic fibers and metal fibers, applied in chemical instruments and methods, separation methods, catalyst carriers, etc.

Inactive Publication Date: 2012-05-02
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the above information, it can be seen that FCC uses paper skeleton, not a mixed carrier of metal fibers, and no relevant patents have been retrieved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The metal fiber is a fiber braid purchased from the market. The gas-liquid filter is woven with metal wires with a wire diameter of 0.2~0.6mm. The gas-liquid filter is folded into a thickness of 8~24 layers and a width of 8~350mm metal braided mesh substrate, or directly rolled into a waved metal braided mesh with a width of 8~350mm. Among them, if the width is 8mm, each system needs 3~4 such carrier segments to be combined in series. On the contrary, if the width is 350mm, each system only needs 1 such carrier segment to meet the volume requirement; the wire mesh of the present invention is only as a skeleton, and more importantly, it is the composite technology of the inorganic fiber of the present invention; The invented metal fiber material has to go through wire drawing, diameter reduction and weaving process before leaving the factory. The fiber material is often coated with lubricating oil or anti-rust oil. Burn out; then transfer to a treatment solution containi...

Embodiment 2

[0022] Select a commercially available 2-layer vapor-liquid filter with a wire diameter of 0.2mm as the metal fiber mesh, and calculate the vapor-liquid filter required for rolling the entire carrier for the vapor-liquid filter cake folded into 16 layers and a width of 350mm. The total length of the net cake is about 8000mm; Weigh 20 parts of alumina, 6.4 parts of nano-titanium dioxide powder, 2 parts of mullite fiber, 0.1 part of sepiolite fiber, 20 parts of silica sol, 1 part of aluminum dihydrogen phosphate, 0 parts of calcium, 0 parts of magnesium oxide, 0.5 parts of carboxymethyl cellulose, 5 parts of alcohol, and 45 parts of water are sequentially added to the container, and stirred at room temperature to form a viscous slurry; In the "papermaking coating", use 0.05Mpa compressed air to blow it once, roll it manually into a concentric carrier with a diameter of 300mm, and weld it with a stainless steel shell with a thickness of 1.5mm; For the carrier wet billet, use 0.4M...

Embodiment 3

[0024] Select a commercially available 2-layer vapor-liquid filter with a wire diameter of 0.6mm as the metal fiber mesh, and calculate the vapor-liquid filter required for rolling the entire carrier for the vapor-liquid filter cake folded into 8 layers and a width of 350mm. The total length of the net cake is about 6000mm;

[0025] Weigh 5 parts of alumina, 20 parts of nano titanium dioxide powder, 0.1 part of mullite fiber, 2 parts of sepiolite fiber, 35 parts of silica sol, 0 part of aluminum dihydrogen phosphate, 0.5 part of calcium oxide, 0.2 part of magnesium oxide, Add 0.1 parts of carboxymethyl cellulose, 3 parts of alcohol, and 34.1 parts of water into the container in sequence, and stir at room temperature to form a viscous slurry;

[0026] Put the above-mentioned gas-liquid filter cake into the slurry for 'papermaking coating', use 0.1Mpa compressed air to blow, and manually roll it into a concentric carrier with a diameter of 300mm, using stainless steel with a thi...

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PUM

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Abstract

The invention relates to a composite carrier of metal fiber and inorganic fiber and a preparation method. The method comprises the following steps of: (1) preserving heat of the metal fiber for 2 hours under the condition of 650-750 DEG C; and transferring into treatment solution containing 1 percent H3PO4 and 0.2 percent SO4 to treat at the temperature of 50 DEG C for 4 hours, washing with water for three times, and drying the moisture; (2) mechanically stirring and mixing each ingredient of an inorganic fiber coating, and then making a layer of wet mixed slurry on a metal fiber screen by using a paper making method; blowing with compressed air of 0.05-0.1 MPa; and rolling into a carrier blank of a concentric circle, a double-core circle or a three-core circle in a wet state; and (3) finally, integrally and simultaneously blowing one end of each the rolled carrier blank at one time by using the compressed air of 0.2-0.4 MPa; raising temperature in a high-temperature furnace along with the furnace at the rate of 80 DEG C / 60 minutes, 120 DEG C / 60 minutes, 200 DEG C / 30 minutes, 300 DEG C / 60 minutes or 500 DEG C / 120 minutes; and then cooling to room temperature along with the furnace. The carrier is sintered into the carrier with the composite structure of spatially and three-dimensionally crossed metal fiber and inorganic fiber after being rolled, is tidy in the macroscopic level and confused in the microscopic level, and is used for SCR (Selective Catalytic Reduction) and POC (Particle Oxidation Catalyst) post-treatment; a back pressure problem is avoided; the process is simple and convenient; and the cost is equivalent to 1 / 2 that of an imported product under the condition of equivalent performance, so that the cost is saved.

Description

technical field [0001] The invention relates to a composite carrier of metal fibers and inorganic fibers and a preparation method, which is applied in the automobile engine industry and meets the requirements of environmental protection standards above Euro 4. Background technique [0002] Low-emission engines have become a hot spot for new technology competition. Select appropriate after-treatment technology strategies and equipment, such as SCR, DPF, DOC, POC and other after-treatment measures to meet Euro 4 or Euro 5 emission standards. [0003] The SCR post-processor uses urea to decompose NH 3 , as a reducing agent and the NOX in the engine exhaust react on the carrier loaded with the catalyst to generate non-toxic N 2 and H 2 O, so as to achieve the purpose of purification; the essence of DPF post-processor technology is to use a special carrier, such as the 'wall flow' ceramic or silicon carbide carrier after the honeycomb holes at the inlet and outlet ends are ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/20B01D53/96B01J32/00B01J35/06
Inventor 张克金崔龙王丹米新艳张苡铭刘国军于丽娜
Owner CHINA FIRST AUTOMOBILE
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