Fe-based amorphous alloy ribbon and magnetic core formed thereby
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[1] Composition
[0022] The first Fe-based amorphous alloy of the present invention is represented by the general formula: FeaSibBcMx, wherein M is Cr and / or Ni, a is 78 to 86 atomic %, b is 0.001 to 5 atomic %, c is 7 to 20 atomic %, and x is 0.01 to 5 atomic %, (a+b+c+x) being 100.
[0023] The second Fe-based amorphous alloy of the present invention is represented by the general formula: FeaSibBcCdMx, wherein M is Cr and / or Ni, a is 78 to 86 atomic %, b is 0.001 to 5 atomic %, c is 7 to 20 atomic %, d is 0.001 to 4 atomic %, and x is 0.01 to 5 atomic %, (a+b+c+d+x) being 100.
[0024] When the Fe-based amorphous alloy of the present invention containing Cr and / or Ni is used, stress generated at the time of producing a magnetic core is sufficiently relaxed by a heat treatment. Cr functions to provide the alloy with a reduced melt viscosity, and improved wettability with a roll and surface conditions. Cr and Ni also have an effect of accelerating the relaxation of stress in the Fe-base...
Example
EXAMPLE 1
[0036] Alloy melts having compositions represented by FeaSibBcMx (a+b+c+x=100) as shown in Table 1 were rapidly quenched by a single roll method to produce amorphous alloy ribbons of 5 mm in width and 25 μm in thickness.
[0037] Each Fe-based amorphous alloy ribbon was wound to form a toroidal magnetic core of 19 mm in outer diameter and 15 mm in inner diameter, which was heat-treated in an Ar gas atmosphere. During the heat treatment, a magnetic field of 1 kA / m was applied in a direction aligned with the magnetic path of the core, and the temperature was elevated to an optimum heat-treating temperature between 320° C. and 370° C., at which the highest saturation magnetic flux density and other soft magnetic properties were obtained, over 2 hours, kept at each heat-treating temperature for 1 hour, and then cooled to 200° C. over 1 hour. The heat-treated ribbons were mostly amorphous. The resultant toroidal magnetic cores were measured with respect to a saturation magnetic f...
Example
EXAMPLE 2
[0043] 20 Samples 2-1 to 2-11 and 2-12 to 2-16 of various compositions were produced and heat-treated in the same manner as in Example 1. The core loss increase ratio Wr of each resultant Fe-based amorphous alloy ribbon is shown in Table 2 together with a composition, a heat treatment temperature, a saturation magnetic flux density Bs, a stress relaxation rate Rs, an average surface roughness Ra, and a space factor. The saturation magnetic flux density Bs and the stress relaxation rate Rs were measured in the same manner as in Example 1.
[0044] The core loss increase ratio Wr is a parameter expressing an increase ratio of the core loss when the operating magnetic flux density increases from 1.3 T to 1.4 T, which is represented by the following equation:
Wr=(W14 / 50−W13 / 50) / W13 / 50×100 [%] (2),
wherein W13 / 50 represents a core loss at a magnetic flux density of 1.3 T and a frequency of 50 Hz, and W14 / 50 represents a core loss at a magnetic flux density of 1.4 T and a freque...
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