Environmentally Pollution-Free Anti-Corrosion Pigment Composition

Inactive Publication Date: 2007-01-18
DAI NIPPON TORYO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0015] The environmentally pollution-free, anti-corrosive pigment composition according to the present invention is free of any environmental pollution since it never comprises any harmful heavy metal element such as lead and/or chromium as well as zinc and thus shows an excellent anti-corrosive effect. This anti-corrosive pigment composition can be incorporated into various kinds of resin-containing paints and therefore, it is quite useful as a pigment used in anti-corrosi

Problems solved by technology

More specifically, it is apprehended that they may hurt the human health.
These environmentally pollution-free anti-corrosive pigments are much less problem concerning the safety and hygiene, but the anti-corrosive properties thereof are in general inferior to those observed for the lead-containing and chromate-containing anti-corrosive pigments.
Furthermore, these environmentally pollution-free pigments cause various problems, for example, in that they require a high production cost and further they are deteriorated in their physical properties, dispersibility and storage stability.
Nevertheless, it has been considered questionable whether zinc-containing compounds, in particular, zinc oxide used as a pigment component is safe or not mainly in the United States and Europe, along with the recent intensified regulation of the environmental pollution.
This is because, it has been proved that zinc oxide may adversely affect the oceanic life or the marine animals and accordingly, there have been such a tendency to start self-controlling of the use of zinc oxide in the coating or painting of, for instance, container

Method used

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Examples

Experimental program
Comparison scheme
Effect test

examples

[0045] The present invention will hereunder be described in more detail with reference to the following Working Examples and Comparative Examples, but the scope of the present invention is not restricted to these specific Examples and Comparative Examples at all. In the following Examples and Comparative Examples, the terms “%” and “part” used for specifying the concentrations and contents therein means “% by mass” and “part by mass”, unless otherwise specified.

1. Synthesis of Condensed Calcium Phosphate A

[0046] To a flask, there were added 100 g of calcium carbonate and 173 g of commercially available 85% phosphoric acid (molar ratio: Ca / P:0.67), followed by the reaction of these substances at 80° C. for 3 hours with stirring. After allowing the reaction solution to cool, it was fired for 30 hours in a dryer maintained at a temperature of 250° C. to thus form condensed calcium phosphate A. This condensed calcium phosphate A is a mixture of, for instance, CaH2P2O7 and Ca4H2(P3O10...

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Abstract

The present invention provides an environmentally pollution-free, anti-corrosive pigment composition which is free of any heavy metal such as lead and/or chromium, which is free of zinc and/or water-soluble ions and which is excellent in the anti-corrosive effect. The anti-corrosive pigment composition comprises condensed calcium phosphate prepared by firing a mixture which comprises a calcium-containing component and a phosphorus-containing component and in which the molar ratio (Ca/P=m) of calcium to phosphorus present in these components falls within the following range: 0.50<m<1.00, at a temperature ranging from 180 to 350° C.

Description

TECHNICAL FIELD [0001] The present invention relates to an anti-corrosive pigment composition which can be incorporated into, for instance, anti-corrosive paints and, more particularly, to an environmentally pollution-free anti-corrosive pigment composition which is free of any heavy metal such as lead, chromium and / or zinc, which can be applied to, for instance, a variety of anti-corrosive paints and anti-corrosive oils, which has a wide variety of applications and which is excellent in the anti-corrosive effect. BACKGROUND ARTS [0002] Until now, as anti-corrosive pigments, there have widely been used lead-containing anti-corrosive pigments such as red lead, lead cyanamide and lead suboxide; and chromate-containing anti-corrosive pigments such as zinc chromate and strontium chromate. [0003] These lead-containing and chromate-containing anti-corrosive pigments have excellent anti-corrosive characteristics, but the use thereof has gradually been regulated while taking into considerat...

Claims

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Application Information

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IPC IPC(8): C01B15/16C01B25/26C09D5/08C09D17/00
CPCC09D17/004C09D5/084C09D5/08C09D17/00
Inventor MATSUDA, TAKASHIOGAWA, OSAMUTAKI, TORU
Owner DAI NIPPON TORYO CO LTD
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