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Interconnect device, fuel cell and fuel cell stack

a technology of interconnection device and fuel cell, which is applied in the direction of fuel cell auxilaries, inorganic chemistry, fuel cells, etc., can solve the problems of large heat input, severe temperature gradients within the cell, and endothermic steam reforming reaction, so as to reduce the thermal gradient and the tensile strength of the fuel cell, and the effect of reducing the tensile strength of the cell

Inactive Publication Date: 2007-11-22
TOPSOE FUEL CELL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This solution minimizes temperature gradients and mechanical stress within the fuel cell, reducing the risk of malfunction and extending the cell's operational lifespan by ensuring uniform heat distribution and utilization, particularly beneficial when using hydrocarbon feedstocks.

Problems solved by technology

The steam reforming reaction is, however, very endothermic and a large heat input is therefore required.
A typical temperature distribution in a fuel cell stack with a hydrocarbon feedstock therefore shows a dramatic temperature drop near the inlet of the fuel cell due to the fast endothermic reforming reaction resulting in severe temperature gradients within the cell.
Ceramic SOFCs have low mechanical strength and in particular low tensile strength.
When the tensile strength in the fuel cell exceeds a given threshold value the cell will crack and the fuel cell will malfunction.
This will increase the problem dramatically as the endothermic reforming of hydrocarbons will reduce the temperature of the fuel cell in the fuel-inlet area significantly, thereby increasing the temperature gradients and the tensile strength in the fuel cell to an unacceptable level.
Such changes are often connected to increased operation cost of the fuel cell system.

Method used

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  • Interconnect device, fuel cell and fuel cell stack
  • Interconnect device, fuel cell and fuel cell stack
  • Interconnect device, fuel cell and fuel cell stack

Examples

Experimental program
Comparison scheme
Effect test

second embodiment

[0028] In a second embodiment the flow of the fuel is not limited to occur entirely through the porous anode material. It can also flow partly through gaps created between the anode surface and the interconnect surface. This reduces the pressure drop. Such gaps are obtained by making a second layer of channels 6 in the interconnect surface 3, which are at an angle to the supply and collection channels 2 and 4, i.e. they intersect the channels of the channel system, and located on the surface of the channel system shown in FIG. 1. This is shown in FIG. 2, where the interconnect has open supply and collection channels with surface channels 6 created perpendicular to the supply and collection channels. Other angles can be chosen such that the second layer of surface channels 6 are not at right angles to the supply and collection channels 2 and 4. The second layer of surface channels 6, which are closed at both ends, can for instance be diagonally placed relative to the supply and colle...

third embodiment

[0030] In a third embodiment the supply channels are closed and the closed interconnect surface 3 is perforated in the area of the channels. In this embodiment the closed, perforated surface 3 corresponds to the second layer of channels being closed at their surface and at both ends, and perforated in the area of the channels. The channels of the second layer are placed parallel to and directly above those of the channel system. This ensures that fuel passing through a perforation will be reformed only in the vicinity of the perforation. FIG. 3 shows an interconnect with closed gas supply and collection channels, where the fuel flows through perforations made in the interconnect surface 3 above the supply channels and into the porous anode material. The reformed gas leaves the anode and enters the collection channel through the perforations placed above the collection channels 4.

[0031]FIG. 3a shows the presence of small fuel distribution holes 7 in the supply channel 2 and fuel exha...

fourth embodiment

[0032] In a fourth embodiment the flow is partly through a second layer of channels 6 in the interconnect surface 3 at an angle to the supply and collection channels 2 and 4. This reduces the pressure drop. This is shown in FIG. 4 where the second layer of channels 6 are perpendicular to the supply and collection channels 2 and 4 of the channel system. The channels 2 and 4 are partly closed. The second layer of channels 6 can also be at another angle to channels 2 and 4, for instance diagonal. They are closed at both ends.

[0033]FIG. 4a shows a side view of the path followed by the fuel gas indicating the presence of fuel distributing holes 7 in the supply channel 2 and exhaust collecting holes 8 in the collection channel 4.

[0034] In the various embodiments, it can be practical to construct the anode side of the interconnect from two or more interlayers instead of a single layer. This can for instance be done by constructing an interlayer provided with the channel system, and placin...

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Abstract

The invention provides an interconnect device for a fuel cell comprising an electrolyte, an anode and a cathode, the interconnect device comprising a channel system having a plurality of channels, each channel being closed in one end and having either an inlet side or an outlet side at the open end of the channel, each channel having an inlet side placed in alternating order with a channel having an outlet side, the inlet side of each channel placed in consecutive order on one side of the interconnect, and the outlet sides of each channel placed in consecutive order on the opposide side of the interconnect relative to the inlet side, and a second layer of channels is located on the surface of the channel system. The invention also provides a fuel cell and a fuel cell stack in which the interconnect device is used.

Description

[0001] The invention concerns a high temperature fuel cell, in particular a Solid Oxide Fuel Cell (SOFC) or a Molten Carbonate Fuel Cell (MCFC), in which reforming of hydrocarbons takes place in the anode chamber or within the anode itself. In particular it concerns an interconnect device in a SOFC or MCFC fuel cell in which the mechanical tension within the fuel cell is reduced. BACKGROUND OF THE INVENTION [0002] A SOFC comprises an oxygen-ion conducting electrolyte, a cathode at which oxygen is reduced and an anode at which hydrogen is oxidised. The overall reaction in a SOFC is that hydrogen and oxygen electrochemically react to produce electricity, heat and water. [0003] The anode also comprises a high catalytic activity for the steam reforming of hydrocarbons into hydrogen, carbon dioxide and carbon monoxide. Steam reforming can be described by the reaction of a fuel such as natural gas with steam and the reactions which take place can be represented by the following equations:...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01M2/14H01M8/02C01B3/38H01M2/18H01M8/00H01M8/04H01M8/12H01M8/14H01M8/24
CPCB01J2219/00783Y02E60/526B01J2219/00869B01J2219/00873B01J2219/00891C01B3/38C01B2203/0233C01B2203/066H01M8/0254H01M8/0258H01M8/0637H01M8/12H01M8/14H01M8/24H01M2008/1293Y02E60/521Y02E60/525B01J2219/00853H01M8/2457H01M8/2484Y02E60/50H01M8/244H01M8/2483
Inventor OLSEN, CHRISTIANUSTERUD, HARALDNIELSEN, JENS ULRIK
Owner TOPSOE FUEL CELL