The invention discloses an immersion-type heat 
radiation cooling liquid used for power 
lithium batteries, and a preparation method thereof, and belongs to the field of 
chemistry. The immersion-type heat 
radiation cooling liquid used for power 
lithium batteries is composed of, by weight, 30 to 70 parts of a 
hydrofluoroether compound, 30 to 50 parts of a halogenated 
hydrocarbon, 1 to 10 parts of analcohol compound, 0.01 to 0.5 part of an 
antioxidant, 0.01 to 0.5 part of a 
preservative, and 0.01 to 0.5 part of a nano 
metal oxide. According to the preparation method, the 
hydrofluoroether compoundis taken as a main component, and is mixed with the halogenated 
hydrocarbon, the 
alcohol compound, and the like to form an 
azeotrope, and the 
antioxidant, the 
preservative, and the non-conductive nano 
metal oxide additives are adopted as auxiliary additives to form the cooling 
liquid composition. The immersion-type heat 
radiation cooling liquid is excellent in heat 
radiation effect, is high in 
specific heat, low in expansion performance, low in 
toxicity, high in insulation performance, excellent in 
flame resistance, 
inert performance, and material compatibility, is capable of realizing 
heat transfer effect rapidly, is capable of solving power 
lithium battery heating and heat radiation problems effectively, prolonging battery service life, reducing 
failure risk, and improving battery safety performance.