Systems for treating a hydrocarbon feed

a hydrocarbon feed and system technology, applied in the direction of catalyst activation/preparation, metal/metal-oxide/metal-hydroxide catalyst, physical/chemical process catalyst, etc., can solve the problems of high tan, high cost of corrosion-resistant metal, and inability to use corrosion-resistant metal in existing equipmen

Inactive Publication Date: 2008-04-10
SHELL OIL CO
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0035] In some embodiments, the invention provides a method of producing a crude product that includes providing one or more catalysts to a contacting zone, wherein at least one of the catalysts is a Column 6 metal catalyst, wherein the Column 6 metal catalyst is produced by the method comprising: combining one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table with a support to form a mixture; and heating the mixture to a temperature of at most 200° C. to form a dried Column 6 metal catalyst; contacting a hydrocarbon feed with the dried Column 6 metal catalyst to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25° C. and 0.101 MPa; wherein the hydrocarbon feed has a residue content of at least 0.1 grams per gram of hydrocarbon feed, and wherein contact of the hydrocarbon feed with the dried catalyst at least partially sulfides the catalyst; and controlling contacting conditions at a partial pressure of hydrogen of at least 3 MPa and a temperature of at least 200° C. such that the crude product has a residue content of at most 90% of the residue content of the hydrocarbon feed.
[0036] In some embodiments, the invention provides a method of producing a crude product that includes contacting a hydrocarbon feed with one or more catalysts to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25° C. and 0.101 MPa; the hydrocarbon feed has a residue content of at least 0.1 grams per gram of hydrocarbon feed; and at least one of the catalysts has at most 0.1 grams, per gram of catalyst, of: one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table; and one or more metals from Columns 9-10 of the Periodic Table and/or one or more compounds of one or more metals from Columns 9-10 of the Periodic Table, and a pore size distribution with a median pore diameter between 50 Å and 120 Å; and controlling contacting conditions at a partial pressure of hydrogen of at least 3 MPa and a temperature of at least 200° C. to produce the crude product, the crude product having a residue content of at most 90% of the residue content of the hydrocarbon feed.
[0037] In some embodiments, the invention provides a method of producing a crude product that includes contacting a crude feed with one or more catalysts to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25° C. and 0.101 MPa; the crude feed having a residue content of at least 0.1 grams per gram of crude feed; and wherein at least one of the catalysts has, per gram of catalyst, at least

Problems solved by technology

Disadvantaged crudes with a relatively high TAN may contribute to corrosion of metal components during transporting and/or processing of the disadvantaged crudes.
The use of corrosion-resistant metal often involves significant expense, and thus, the use of corrosion-resistant metal in existing equipment may not be desirable.
The use of corrosion inhibitors may negatively affect equipment used to process the crudes and/or the quality of products produced from the crudes.
Disadvantaged crudes often contain relatively high levels of residue.
Disadvantaged crudes having such high levels of residue tend to be difficult and expensive to transport and/or process using conventional facilities.
During processing of such crudes, metal contaminants and/or compounds of metal contaminants, may deposit on a surface of the catalyst or in the void volume of the catalyst.
Such deposits may cause a decline in the activity of the catalyst.
It may be costly to regenerate the catalytic activity of a catalyst contaminated with coke.
High temperatures used during regeneration may also diminish the activity of the catalyst and/or cause the catalyst to deteriorate.
Moreover, the metals in metal salts of organic acids may cause rapid deactivation of catalysts.
Organically bound heteroatoms may, in some situations, have an adverse effect on catalysts.
Treatment facilities that process disadvantaged crudes with an oxygen content of at least 0.002 grams of oxygen per gram of disadvantaged crude may encounter problems during processing.
Organic oxygen compounds, when heated during processing, may form higher oxidation compounds (for example, ketones and/or acids formed by oxidation of alcohols, and/or acids formed by oxidation of ethers) that are difficult to remove from the treated crude and/or may corrode/contaminate equipment during processing and cause plugging in transportation lines.
Basic nitrogen compounds may have adverse effects on catalysts used in cracking processes, thus reducing the efficiency of the crack

Method used

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Examples

Experimental program
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Effect test

example 1

Preparation of a Catalyst Support

[0269] A support was prepared by mulling 576 grams of alumina (Criterion Catalysts and Technologies LP, Michigan City, Michigan, U.S.A.) with 585 grams of water and 8 grams of glacial nitric acid for 35 minutes. The resulting mulled mixture was extruded through a 1.3 Trilobe™ die plate, dried between 90 and 125° C., and then calcined at 918° C., which resulted in 650 grams of a calcined support with a median pore diameter of 182 Å. The calcined support was placed in a Lindberg furnace. The furnace temperature was raised to 1000-1100° C. over 1.5 hours, and then held in this range for 2 hours to produce the support. The support included, per gram of support, 0.0003 grams of gamma alumina, 0.0008 grams of alpha alumina, 0.0208 grams of delta alumina, and 0.9781 grams of theta alumina, as determined by x-ray diffraction. The support had a surface area of 110 m2 / g and a total pore volume of 0.821 cm3 / g. The support had a pore size distribution with a me...

example 2

Preparation of a Vanadium Catalyst Having a Pore Size Distribution with a Median Pore Diameter of at Least 230 Å

[0271] The vanadium catalyst was prepared in the following manner. The alumina support, prepared by the method described in Example, was impregnated with a vanadium impregnation solution prepared by combining 7.69 grams of VOSO4 with 82 grams of deionized water. A pH of the solution was 2.27.

[0272] The alumina support (100 g) was impregnated with the vanadium impregnation solution, aged for 2 hours with occasional agitation, dried at 125° C. for several hours, and then calcined at 480° C. for 2 hours. The resulting catalyst contained 0.04 grams of vanadium, per gram of catalyst, with the balance being support. The vanadium catalyst had a pore size distribution with a median pore diameter of 350 Å, a pore volume of 0.69 cm3 / g, and a surface area of 110 m2 / g. Additionally, 66.7% of the total number of pores in the pore size distribution of the vanadium catalyst had a pore d...

example 3

Preparation of a Molybdenum Catalyst Having a Pore Size Distribution with a Median Pore Diameter of at Least 230 Å

[0274] The molybdenum catalyst was prepared in the following manner. The alumina support prepared by the method described in Example was impregnated with a molybdenum impregnation solution. The molybdenum impregnation solution was prepared by combining 4.26 grams of (NH4)2Mo2O7, 6.38 grams of MoO3, 1.12 grams of 30% H2O2, 0.27 grams of monoethanolamine (MEA), and 6.51 grams of deionized water to form a slurry. The slurry was heated to 65° C. until dissolution of the solids. The heated solution was cooled to room temperature. The pH of the solution was 5.36. The solution volume was adjusted to 82 mL with deionized water.

[0275] The alumina support (100 grams) was impregnated with the molybdenum impregnation solution, aged for 2 hours with occasional agitation, dried at 125° C. for several hours, and then calcined at 480° C. for 2 hours. The resulting catalyst contained 0....

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Abstract

Systems for treating a hydrocarbon feed to produce a total product are described herein. The system includes an upstream contacting system and a downstream contacting system. The upstream contacting system includes one or more catalysts. The hydrocarbon feed has a viscosity of at least 100 cSt at 37.8° C. Contact of the hydrocarbon feed with one or more of the catalysts produces the total product. The total product includes a crude product having a viscosity at 37.8° C. of at most 50% of the viscosity of the first feed at 37.8° C. The downstream contacting system is coupled to the upstream contacting system and configured to receive the first feed. The downstream contacting system includes a cracking unit and/or a deasphalting unit.

Description

RELATED APPLICATION [0001] The present application claims the benefit of the filing date of U.S. Provisional patent application Ser. No. 60 / 850,109 filed Oct. 6, 2006, the disclosure of which is incorporated herein by reference.FIELD OF THE INVENTION [0002] The present invention generally relates to systems, methods, and catalysts for treating hydrocarbon feeds, and to compositions that can be produced using such systems, methods, and catalysts. More particularly, certain embodiments described herein relate to systems, methods, and catalysts for conversion of a hydrocarbon feed to a total product, wherein the total product includes a crude product that is a liquid mixture at 25° C. and 0.101 MPa and has one or more properties that are changed relative to the respective property of the hydrocarbon feed. DESCRIPTION OF RELATED ART [0003] Crudes that have one or more unsuitable properties that do not allow the crudes to be economically transported, or processed using conventional facil...

Claims

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Application Information

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IPC IPC(8): B01J8/04
CPCB01J21/04C10G2300/4012B01J23/28B01J23/882B01J23/883B01J35/002B01J35/1019B01J35/1042B01J35/1061B01J35/108B01J37/0009B01J37/0203C10G45/04C10G45/08C10G47/00C10G47/10C10G47/12C10G49/04C10G65/12C10G2300/4018C10G2300/206C10G2300/208C10G2300/302C10G2300/308C10G2300/4006B01J23/22B01J23/88C10G45/06C10G45/12C10G69/02
Inventor BHAN, OPINDER KISHANWELLINGTON, SCOTT LEE
Owner SHELL OIL CO
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