Polymeric stents and other surgical articles
a technology of polymer stents and surgical articles, which is applied in the direction of prosthesis, surgery, blood vessels, etc., can solve the problems of haphazard approach to the treatment of heart conditions, too little or too much, etc., and achieve the effect of completely inappropriate heart condition treatmen
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example i
50:50 Blend of Polyetherurethane (Elastomeric) with Poly-L-lactic Acid (Non-Elastomeric)
[0050]Materials: The polyetherurethane (PEU) was prepared by reacting poly-tetramethyleneglycol (soft segment; MW 2000 with methylene bis(phenylisocyanate), followed by reaction of the initial product with butanediol as chain extender. The molar ratio of these reactants was 1:2:1. Poly-L-lactic Acid (PLLA) had a MW 2000 and Tg 30-45° C. Dimethylacetamide (DMA) was used as solvent.
Method: PEU (1 g) and PLLA (1 g) were mixed with DMA (40 ml) at 60° C., using a magnetic stirrer, until complete dissolution of the polymers, giving a transparent solution, was achieved. A film of the polymer blend was prepared after casting the solution and evaporation of the solvent at 60° C. in an oven overnight. The film was subsequently dried at 40-50° C. under vacuum for a further 16 hours. The resulting film was semi-transparent which changed to an opaque white milky film when it was stressed and loaded.
example ii
75:25 Blend of Polyetherurethane (Elastomeric) with Poly-L-lactic Acid (Non-Elastomeric)
[0051]Materials: The polyetherurethane (PEU) was prepared by reacting poly-tetramethyleneglycol (soft segment; MW 2000 with methylene bis(phenylisocyanate), followed by reaction of the initial product with butanediol as chain extender. The molar ratio of these reactants was 1:2:1. Poly-L-lactic Acid (PLLA) had a MW 2000 and Tg 3045° C. Dimethylacetamide (DMA) was used as solvent.
Method: PEU (1.5 G) and PLLA (0.5 g) were mixed with DMA (40 ml) at 60° C., using a magnetic stirrer, until complete dissolution of the polymers, giving a transparent solution, was achieved. A film of the polymer blend was prepared and subsequently subjected to the same procedure as in Example 1. The resulting film was semi-transparent which changed to an opaque white milky film when it was stressed and loaded, but the product was less flexible and harder than the product of Example I.
example iii
50:50 Blend of Polyetherurethane (Elastomeric) with Poly-DL-lactic Acid (Non-Elastomeric)
[0052]Materials: The polyetherurethane (PEU) was prepared by reacting poly-tetramethyleneglycol (soft segment; MW 2000 with methylene bis(phenylisocyanate), followed by reaction of the initial product with butanediol as chain extender. The molar ratio of these reactants was 1:2:1. Poly-DL-lactic Acid (PDLLA) had a MW 2000 and Tg 30-45° C. Dimethylacetamide (DMA) was used as solvent.
Method: PEU (1.3 g) and PDLLA (0.7 G) were mixed with DMA (40 ml) at 60° C., using a magnetic stirrer, until complete dissolution of the polymers, giving a transparent solution, was achieved. A film of the polymer blend was prepared and subsequently subjected to the same procedure as in Example 1. The resulting film was semi-transparent which changed to an opaque white milky film when it was stressed and loaded.
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