Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers

Inactive Publication Date: 2011-06-23
GENERAL ELECTRIC CO
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Benefits of technology

[0007]In one aspect, the invention is directed to a method for reducing the amount of hydrogen sulfide present in heavy oil and reducing the amount of corrosion in processing equipment contacting the heavy oil. The method includes the steps of adding an aqueous-based scavenger containing one or more aldehydes to the heavy oil using a static mixer injection system and creating an aqueous-based scavenger/heavy oil emulsion using a high shear/high velocity pump. In one embodiment, the method further includes diverting

Problems solved by technology

Fossil products, and notably heavy oil, often contain significant quantities of hydrogen sulphide, H2S, which is a toxic, highly corrosive, inflammable and explosive gas.
The risk of exposure to hydrogen sulfide from handling heavy oil is a health and safety concern during stor

Method used

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  • Emulsification of hydrocarbon gas oils to increase efficacy of water based hydrogen sulfide scavengers

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[0011]The invention will now be described in the following detailed description with reference to the drawings, wherein preferred embodiments are described in detail to enable practice of the invention. Although the invention is described with reference to these specific preferred embodiments, it will be understood that the invention is not limited to these preferred embodiments. But to the contrary, the invention includes numerous alternatives, modifications and equivalents as will become apparent from consideration of the following detailed description.

[0012]The singular forms “a,”“an” and “the” include plural referents unless the context clearly dictates otherwise. The endpoints of all ranges reciting the same characteristic are independently combinable and inclusive of the recited endpoint. All references are incorporated herein by reference.

[0013]The modifier “about” used in connection with a quantity is inclusive of the stated value and has the meaning dictated by the context ...

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Abstract

A hydrogen sulfide scavenging process for heavy oil that reduces hydrogen sulfide while minimizing corrosion to processing equipment. The method includes the steps of adding an aqueous-based scavenger containing one or more aldehydes, such as glyoxal, to the heavy oil using a static mixer injection system and creating an aqueous-based scavenger/heavy oil emulsion using a high shear/high velocity pump. The aqueous-based scavenger may be added in a scavenger addition branch, with the emulsion being formed in the addition branch and then returned to the processing equipment.

Description

BACKGROUND OF THE INVENTION[0001]1. Field of the Invention[0002]This invention relates generally to processing heavy oil, and more particularly, to methods for removing hydrogen sulfide in heavy oil with an aqueous-based scavenger / oil emulsion.[0003]2. Description of Related Art[0004]Fossil products, and notably heavy oil, often contain significant quantities of hydrogen sulphide, H2S, which is a toxic, highly corrosive, inflammable and explosive gas. The risk of exposure to hydrogen sulfide from handling heavy oil is a health and safety concern during storage, transportation (shipping, truck or pipeline) and processing.[0005]Hydrogen sulfide scavengers can be used to remove hydrogen sulfide from heavy oil. It is known to be possible to reduce the hydrogen sulphide content present in aqueous mediums by using aqueous solutions of aldehydes such as formaldehyde, glyoxal, and glutaraldehyde (see for example the U.S. Pat. Nos. 4,680,127 and 5,284,635). However, simple addition of water-...

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Application Information

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IPC IPC(8): C10G17/00
CPCC10G29/24C10G2300/4075C10G2300/207B01F23/40
Inventor KARAS, LARRY JOHNANDERSON, CRAIG
Owner GENERAL ELECTRIC CO
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