Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers

a technology of cellulose and cellulose molecules, applied in the field of cellulose-containing materials processing methods and systems, can solve the problems of exacerbated waste disposal problems, high and variable raw material costs of natural fibers, and resource-intensive growing and harvesting of cotton fibers, and achieve the effect of low environmental impa

Inactive Publication Date: 2016-12-22
EVRNU SPC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012]Isolated cellulose polymers produced using the processes described herein may be used in a variety of downstream applications, as described in more detail below and, in some embodiments, may be extruded to form regenerated cellulosic fibers. In some aspects, isolated cellulose polymers may be re-generated to provide longer chain polymers and fibers (or polymers and fibers having other desirable characteristics different from the characteristics of the cellulose-containing feedstock) that are useful in various industrial processes, including textile production. In addition to employing a raw feedstock materials that are typically discarded (wasted, at a cost), processing steps having generally low environmental impacts are preferred.

Problems solved by technology

This cycle wastes valuable materials and the considerable resources required to produce them, and it exacerbates waste disposal issues.
Natural fibers, including cotton, have a generally high and variable raw material cost due, in part, to natural disasters and climate unpredictability, regional socio-economic and political instability, human rights issues, and resource requirements.
Growing and harvesting cotton fibers is resource-intensive.
Growing cotton frequently involves heavy pesticide use, significant land resources, and produces significant levels of heat-trapping gases.
With demand for agricultural land use increasing and fresh water supplies decreasing, the cost of producing natural cotton is increasing.
At some point, the current scale of cotton production may become unprofitable and unsustainable.
Re-processing methods that convert used cotton into rags, mattress ticking, seat stuffing, insulating materials, and the like are also available, but these processing methods have been adopted in limited applications because the value of the converted material is relatively low.

Method used

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  • Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers
  • Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers
  • Methods and systems for processing cellulose-containing materials and isolating cellulose molecules; methods for regenerating cellulosic fibers

Examples

Experimental program
Comparison scheme
Effect test

example i

[0082]A small scale experiment was conducted to establish feasibility of cellulose pulping and fiber regeneration using shredded cotton garment material as a feedstock. The shredded feedstock material was treated with Schweizer's Reagent to form a dissolved pulping solution, and the pulp solution was acidified by treatment with sulfuric acid. Fibers were regenerated as a result of the acidification.

Chemical Reactions

[0083]1. 2 NaOH(aq)+CuSO4(aq)→Cu(OH)2(s)+Na2SO4(aq)[0084]2. Cu(OH)2(aq) Cu2(aq)+2OH−(aq)[0085]3. n Cu2+(aq)+(cellulose)n+2n OH−→(CuC6H8O5)n+2n H2O[0086]4. Cellulose is actually dissolved in [Cu(NH3)4](OH)2 solution and then regenerated as cotton or rayon when extruded into sulfuric acid.[0087]5. Note: Filtration of Cu(OH)2 can be a problem; small amounts of precipitate should be filtered and then combined in one container.

Process Instructions

[0088]1. Dissolve 25.0 g of CuSO4.5H2O in 100 mL distilled water. Heat the water to accelerate the dissolving process.[0089]2. Diss...

example ii

[0095]Analyses were conducted to compare regenerated cellulosic fibers, processed as described herein, with virgin cotton fibers. Regenerated cellulosic fiber produced as described above was tested using the ASTM D 2256-02 test method for tensile properties of yarns by single-strand method. The regenerated cellulosic fibers exhibited uniform-diameter fiber properties, with the tenacity of cotton and the fineness of silk. Tenacity is a measure of the breaking strength of a fiber divided by the denier. FIG. 9A shows a magnified image of a regenerated cellulosic fiber produced as described above (on the left, labeled Evrnu) and FIG. 9B shows a magnified image of a premium long-staple cotton fiber as tested in Harzallah, Benzina & Drean, 2009 (right-side image, labelled “cotton,” reproduced without permission from aforementioned paper). The comparative fiber properties of the regenerated cellulosic fiber produced as described above and the premium long-staple cotton fiber, as reported i...

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Abstract

Methods and systems of the present invention use cellulose-containing materials, which may include post-consumer waste garments, scrap fabric and/or various biomass materials as a raw feed material to produce isolated cellulose molecules having desirable properties that can be used in the textile and apparel industries, and in other industries. A multi-stage process is provided, in which cellulose-containing feed material is subjected to one or more pretreatment stages, followed by a pulping treatment, to isolate cellulose molecules. The isolated cellulose molecules may be used in a variety of downstream applications. In one application, isolated cellulose molecules are extruded to provide regenerated cellulose fibers having desirable (and selectable) properties that are usable in various industrial applications, including textile production.

Description

REFERENCE TO RELATED PATENT APPLICATIONS[0001]This application is a continuation-in-part application of U.S. patent application Ser. No. 14 / 255,886, filed Apr. 17, 2014, which claims priority from U.S. Provisional Patent Application No. 61 / 812,931, filed Apr. 17, 2013. The disclosures of the previous applications are incorporated by reference herein in their entireties.FIELD[0002]The present disclosure relates to methods and systems for processing cellulose-containing materials such as textiles, including textile garments (used and un-used) and scraps, biomass, wood pulp, and the like and for isolating cellulose molecules for use in a variety of downstream applications. In particular applications, the present disclosure relates to methods and systems for treatment of cellulose-containing materials to isolate cellulose molecules and to produce regenerated polymers, fibers, and / or fabrics from the isolated cellulose molecules. Recycling and regeneration of textiles is described in det...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D21H17/00D21H17/65D21H13/08
CPCD21H17/74D21H17/65D21H17/005D21H13/08D21B1/02D21C1/02D21C3/20D21C5/005D21C9/001D21C9/10
Inventor FLYNN, STACYSTANEV, CHRISTOPHER
Owner EVRNU SPC
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