The invention relates to a method for efficiently preparing an A-site Ba-containing
proton conductor
electrolyte by using a precursor
combustion method, which innovatively adopts a technology for preparing
electrolyte powder by using the precursor
combustion method, is coupled with a
flame synthesis technology and a
sol-gel technology, and comprises the following steps: weighing raw materials according to the stoichiometric ratio of the
proton conductor
electrolyte, preparing precursor liquid, and preparing the A-site Ba-containing
proton conductor electrolyte; adjusting the pH value of the precursor liquid, controlling the
combustion condition, heating and
drying the precursor liquid, combusting the obtained
powder, and calcining at high temperature to form a corresponding
crystal structure. Compared with the prior art, the preparation method has the advantages that the BCY, BZY, BZCY or BZCYYb electrolyte
powder which is smaller and more uniform in particle size and higher in
sintering activity is successfully prepared by controlling the chemical proportion and combustion conditions of the precursor. The electrolyte powder can be sintered to be compact at 1300 DEG C (the density is gt; and the temperature is far lower than 1600 DEG C required by the traditional method, so that the volatilization of Ba element in the high-temperature
sintering and electrolyte densification processes is effectively avoided, and the battery performance and the
sintering temperature are both considered.