Erbium-base lorge-cube non-crystal alloy and making method
An amorphous alloy and bulk technology, which is applied in the field of erbium-based bulk amorphous alloy and its preparation, can solve the problem of rare rare earth-based amorphous alloy, and achieve the effects of low cost, broad application prospect and strong crystallization ability.
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Embodiment 1
[0023] Example 1. Erbium-based bulk amorphous alloy Er 36 Y 20 Al 24 Co 20 Preparation
[0024] After mixing the four components of Er, Y, Al and Co with a raw material purity of 99.9wt% or more (weight percentage) in a molar ratio of 36:20:24:20, the arc is in an argon atmosphere where titanium is adsorbed. The furnace is evenly mixed and smelted 5 times. After cooling, the master alloy ingot of Er-Y-Al-Co quaternary alloy is obtained; then the conventional metal mold casting method is used to re-melt the ingot, using the electric arc furnace The suction casting device sucks the master alloy melt into the water-cooled copper mold, and the composition is Er 36 Y 20 Al 24 Co 20 , A bulk amorphous alloy with a diameter of 8mm.
[0025] The X-ray diffraction (XRD) shown in Figure 1 shows that the alloy is a completely amorphous alloy.
[0026] Figure 2 shows Er 36 Y 20 Al 24 Co 20 The thermal analysis (DTA) diagram of the erbium-based bulk amorphous alloy, as can be seen from the dia...
Embodiment 2
[0027] Example 2. Erbium-based bulk amorphous alloy Er 46 Y 10 Al 24 Co 20 Preparation
[0028] After preparing the four components of Er, Y, Al and Co with a raw material purity of 99.9wt% or more (weight percentage) at a molar ratio of 46:10:24:20, in an electric arc furnace with an argon atmosphere adsorbed by titanium Mix uniformly and repeatedly smelt 6 times, and after cooling, the master alloy ingot of Er-Y-Al-Co quaternary alloy is obtained; then the conventional metal mold casting method is used to re-melt the ingot, using suction casting in the electric arc furnace Device, suck the master alloy melt into the water-cooled copper mold to get the composition Er 46 Y 10 Al 24 Co 20 , A bulk amorphous alloy with a diameter of 5mm.
[0029] The X-ray diffraction (XRD) shown in Figure 1 shows that the alloy is a completely amorphous alloy.
[0030] Figure 3 shows Er 46 Y 10 Al 24 Co 20 The thermal analysis (DSC and DTA) diagrams of erbium-based bulk amorphous alloys can be seen...
Embodiment 3
[0031] Example 3: Erbium-based bulk amorphous alloy Er 50 Y 6 Al 24 Co 20 Preparation
[0032] After preparing the four components of Er, Y, Al and Co with a raw material purity of 99.9wt% or more (weight percentage) at a molar ratio of 50:6:24:20, in an electric arc furnace with an argon atmosphere adsorbed by titanium Mix uniformly and repeatedly smelt 5 times. After cooling, the master alloy ingot of Er-Y-Al-Co quaternary alloy is obtained; then the conventional metal mold casting method is used to re-melt the ingot and use the suction casting in the electric arc furnace Device, suck the master alloy melt into the water-cooled copper mold to get the composition Er 50 Y 6 Al 24 Co 20 , A bulk amorphous alloy with a diameter of 5mm.
[0033] The X-ray diffraction (XRD) shown in Figure 1 shows that the alloy is a completely amorphous alloy.
[0034] Figure 4 shows Er 50 Y 6 Al 24 Co 20 The thermal analysis (DSC and DTA) diagrams of erbium-based bulk amorphous alloys can be seen fro...
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