Modifying method of the carbon carrier particle for catalyzer
A carbon carrier and catalyst technology, which is applied in the field of modification of carbon carrier particles for catalysts, can solve the problem that catalysts cannot take into account catalyst stability and catalytic activity at the same time, and achieves the effects of improving stability and catalytic activity.
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Embodiment 1
[0040] This example is used to illustrate the modification method of the catalyst carbon carrier particles provided by the present invention and the catalyst using the carbon carrier particles.
[0041] Add 10.0 grams of Vulcan XC72R into the anode chamber 21 of the electrolyzer shown in Figure 2, wherein the anode chamber 21 and cathode chamber 23 with a volume of 2.5 liters are respectively equipped with 1 liter of 0.1 mol / liter dilute H 2 SO 4 solution, the anode plate 211 and the cathode plate 231 are cylindrical graphite electrodes with a surface area of 0.1 square meters, and the diaphragm 22 is a perfluorosulfonic acid membrane with a pore diameter of 5 microns. Stir with a stirrer 24 at a speed of 200 rpm for 1 hour at room temperature, so that Vulcan XC72R is evenly dispersed in the dilute H in the anode chamber 2 SO 4 A suspension is formed in the solution, and then a direct current with a density of 0.05 ampere / square centimeter is applied through the anode plat...
Embodiment 2
[0044] This example is used to illustrate the modification method of the catalyst carbon carrier particles provided by the present invention and the catalyst using the carbon carrier particles.
[0045] 8.0 grams of carbon nanotubes (average particle diameter is 0.002 microns) are added in the anode chamber 21 of the electrolyzer shown in Fig. 2, wherein the anode chamber 21 and the cathode chamber 23 that volume is 2.5 liters are respectively equipped with 1 liter of 0.05 mole / L of HNO 3 solution, the anode plate 211 and the cathode plate 231 are cylindrical graphite electrodes with a surface area of 0.075 square meters, and the diaphragm 22 is a polyethylene microporous membrane. Stir at 30°C with stirrer 24 at a speed of 300 rpm for 2 hours, so that the carbon nanotubes are evenly dispersed in the dilute HNO in the anode chamber 3 solution, then apply a current with a density of 0.20 ampere / square centimeter through the anode plate 211 and the cathode plate 231 while st...
Embodiment 3
[0051] This example is used to illustrate the modification method of the catalyst carbon carrier particles provided by the present invention and the catalyst using the carbon carrier particles.
[0052] 1.0 gram of Vulcan XC72R is added in the anode chamber 21 of the electrolytic cell shown in Fig. 2, wherein the anode chamber 21 and the cathode chamber 23 with a volume of 2.5 liters are respectively equipped with 1 liter of 2.5 mol / liter H 3 PO 4 solution, the anode plate 211 and the cathode plate 231 are rod-shaped graphite electrodes with a surface area of 0.05 square meters, and the diaphragm 22 is a perfluorosulfonic acid membrane with a pore diameter of 5 microns. At 40°C, the agitator 24 was stirred at a speed of 200 rpm for 30 minutes, so that the Vulcan XC72R was uniformly dispersed in the dilute H in the anode chamber 21 3 PO 4 solution, then apply a current with a density of 5.0 amperes / square centimeter through the anode plate 211 and the cathode plate 231 whil...
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Abstract
Description
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