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Low-smoke bittern-free flame-retardant polyolefin material and braided fabric manufactured thereby

A polyolefin and polyolefin resin technology, applied in the field of polyolefin plastic woven cloth, can solve the problems of strong flame retardancy, easy combustion, environmental hazards, etc., and achieve the effect of suppressing temperature rise

Active Publication Date: 2008-07-30
上海亚都塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Plastic weaving products are an important part of plastic products. According to the statistics of "Plastic Knitting Packaging", the plastic knitting industry completed an output value of about 53 billion yuan in 2007; Higher profits require the development of new products in order to obtain innovative technical plastic woven series products with high economic growth points, such as: new functional plastic woven materials with low-smoke, halogen-free, flame-retardant, anti-static, etc.; traditional polyolefin Plastic woven polymer is a flammable and combustible material. When burning, it has a large heat release rate, high calorific value, fast flame propagation speed, not easy to self-extinguish, and strong flame retardancy. It will also produce thick smoke or poisonous and harmful when burning. , corrosive gas, causing secondary disasters, harming the environment and posing a huge threat to human life safety; this kind of woven fabric is easy to burn when it encounters fire, and its strength is not good, so the scope of use is limited

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] A low-smoke halogen-free flame-retardant polyolefin material, which is composed of polyolefin resin and inorganic flame retardant; wherein, the inorganic flame retardant (masterbatch) composition is:

[0035] Component Parts by weight

[0036] Al(OH) 3 45

[0037] Mg(OH) 2 25

[0038] ZB (zinc borate) 10

[0039] Silane coupling agent 0.8

[0040] Ca-st (calcium stearate) 0.4

[0041] Antioxidant 0.3;

[0042] The above polyolefin resin is mixed with an inorganic flame retardant (masterbatch) at a ratio of 1:1 to prepare a product.

[0043] After testing, the oxygen index OI value of the low-smoke, halogen-free, flame-retardant polyolefin composite woven fabric is ≥ 25.

Embodiment 2

[0045] A low-smoke halogen-free flame-retardant polyolefin material, which is composed of polyolefin resin and inorganic flame retardant; wherein, the inorganic flame retardant (masterbatch) composition is:

[0046] Component Parts by weight

[0047] Al(OH) 3 45

[0048] Mg(OH) 2 25

[0049] ZB (zinc borate) 10

[0050] Silane coupling agent 0.8

[0051] Ca-st (calcium stearate) 0.4

[0052] Antioxidant 0.3;

[0053] The above polyolefin resin is mixed with an inorganic flame retardant (masterbatch) at a ratio of 1:1.5 to prepare a product.

[0054] After testing, the oxygen index OI value of the low-smoke, halogen-free, flame-retardant polyolefin composite woven fabric fabric is ≥ 30.

[0055] According to the above examples 1 and 2, the polyolefin resin raw material in the present invention can be LDPE and / or HDPE and / or MDPE and / or LLDPE; the antioxidant raw material can be phenols or amines or sulfur or phosphorus. And the corrosiveness o...

Embodiment 3

[0058] A low-smoke halogen-free flame-retardant polyolefin material, which is composed of polyolefin resin and inorganic flame retardant; wherein, the inorganic flame retardant (masterbatch) composition is:

[0059] Component Parts by weight

[0060] Al(OH) 3 45

[0061] Mg(OH) 2 25

[0062] ZB (zinc borate) 10

[0063] Silane coupling agent 0.8

[0064] Ca-st (calcium stearate) 0.4

[0065] Antioxidant 0.3;

[0066] After the above components are mixed by a high-speed mixer and treated by surface activation technology, the material is in a dry and loose state. Put this inorganic flame retardant (masterbatch) into a water cup and after stirring, it can float on the water surface and become hydrophobic.

[0067]Then, the above polyolefin resin is mixed with the inorganic flame retardant (masterbatch) at a ratio of 1:1-1.5 to form a low-smoke, halogen-free flame-retardant polyolefin material.

[0068] In the above composition, the main raw materia...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention relates to low smoke non-halogen flame-resistant polyolefine material and compound weaved cloth made of the low smoke non-halogen flame-resistant polyolefine material. The low smoke non-halogen flame-resistant polyolefine material is composed of polyolefine resin and inorganic flame retardant. The manufacturing process of the weaved cloth comprises the following steps: on one hand, polyolefine material is taken to be filled into a plastic extrusion molding machine, film is extruded through the plastic extrusion molding machine, and then cooled and cut, heated and directionally stretched, the pre-heating treatment is performed to the film to be shaped, and then the film is rolled, and woven in across warp and warp direction into plastic cloth; on the other hand, the low smoke non-halogen being flame-resistant polyolefine material is taken to be filled into a clothes rack type flat frame head plastic extrusion molding machine, and film coating is extruded through the clothes rack type flat frame head plastic extrusion molding machine; after two aspects are accomplished, the film coating is hot melt and continuously compressed into the low smoke non-halogen flame-resistant polyolefine weaved cloth through a compound rolling drum. The technology of the invention can improve the low smoke non-halogen flame-resistant performance and the anti-aging performance of the polyolefine plastic weaved cloth.

Description

technical field [0001] The invention relates to a polyolefin plastic woven cloth, especially a low-smoke, halogen-free flame-retardant polyolefin material and a composite woven cloth made of the material. Background technique [0002] Plastic weaving products are an important part of plastic products. According to the statistics of "Plastic Knitting Packaging", the plastic knitting industry completed an output value of about 53 billion yuan in 2007; Higher profits require the development of new products in order to obtain innovative technical plastic woven series products with high economic growth points, such as: new functional plastic woven materials with low-smoke, halogen-free, flame-retardant, anti-static, etc.; traditional polyolefin Plastic woven polymer is a flammable and combustible material. When burning, it has a large heat release rate, high calorific value, fast flame propagation speed, not easy to self-extinguish, and strong flame retardancy. It will also produ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/04C08K13/06C08K9/06C08K3/22C08K3/38C08K5/098B27J1/02
Inventor 周宝茂陈圣拥陈圣都陈丹丹陈蓉
Owner 上海亚都塑料有限公司
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