The invention discloses reactive
phosphorus triazine flame retardant for
dyeing, and a preparation method and application thereof, which belong to the technical field of
flame retardants and relate to
flame retardant for cotton. A molecular structure of the reactive
phosphorus triazine flame retardant for
dyeing is OPO3OCLO3OO3PO. The preparation method includes: mixing
pentaerythritol with dioxane under protection of
inert gases, dropwise adding
phosphorus oxychloride at 80 DEG C for two hours, adding two to three drops of
triethylamine, allowing for reaction for 4-10 hours, cooling, filtering, vacuum-
drying to obtain PEPA after rinsing; and mixing
cyanuric chloride with reaction
solvent, adjusting the temperature to 10-20DEG C, initially dropwise adding the PEPA and acid-binding agent, allowing for
continuous reaction for 6 hours, dropwise adding again the PEPA and the acid-binding agent, allowing for reaction for 6 hours, adding precipitant for
precipitation after cooling, filtering, rinsing, and
drying to obtain the fished product. The preparation method is simple, the prepared flame retardant has a
carbon source, an acid source and a gas source integrated and is higher in
thermal stability and better in carbon forming performance, and the PEPA and the
triazine structure are complemented while both being given to full play to the advantages.