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Halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and preparation method thereof

A wood-plastic composite material and flame-retardant technology, which is applied in the field of polyolefin halogen-free flame-retardant injection-grade wood-plastic composite materials, and can solve the problem that ammonium polyphosphate is easily decomposed, the fluidity of wood-plastic composite materials is poor, and the amount of flame retardant added Large and other problems, to achieve the effect of good halogen-free flame retardant effect, wide range of molding methods, and less amount of flame retardant

Inactive Publication Date: 2010-10-06
KINGFA SCI & TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, it is an inevitable trend to research and develop halogen-free flame-retardant wood-plastic composite materials. Chinese patent application 200610039985.4 discloses a flame-retardant wood-plastic composite material and its preparation method, using intumescent flame retardant ammonium polyphosphate and carbon forming agent Flame-retardant modification of polypropylene or polyethylene-based wood-plastic composite materials with foaming agents, etc., but there are disadvantages such as large amount of flame retardants, ammonium polyphosphate is easy to decompose at processing temperature, and the product is easy to absorb moisture; Chinese patent application 200710072794.2 discloses a flame-retardant and smoke-suppressing wood-plastic composite material, which also uses intumescent flame retardant ammonium polyphosphate, starch, etc. to modify polystyrene or polyvinyl chloride, and still exists as an intumescent flame retardant The above shortcomings; in addition, Chinese patent application 200710173607.X discloses a halogen-free flame-retardant wood-plastic composite material and its preparation method. Soak the cellulose material after the agent, and then prepare the halogen-free flame-retardant wood-plastic composite material, because it still uses the intumescent flame retardant, and the step of processing the fiber is added separately, so its practicability is greatly reduced
[0005] In addition, the existing wood-plastic preparation technology is mainly based on extrusion molding, hot pressing molding and extrusion molding technology, which are mainly used for the production of plate products. The injection molding parts with complex molding structures are greatly restricted. The main problem is It is due to the poor fluidity of the wood-plastic composite material with a large amount of wood powder, the low strength of the part, and the poor appearance quality
Although Chinese patent application 200710020012.7 discloses injection molding grade wood-plastic composite material and processing technology, the melt flow rate range of the wood-plastic composite material prepared by it is only 0.3-1.0g / 10min, and can only be used for polypropylene, high Density polyethylene or polyvinyl chloride, its practical application range is very limited

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Raw material components are calculated by mass percentage as:

[0038] Copolymerized PP: 37.4%

[0039] 100 mesh wood flour: 25%

[0040] PP-g-MAH: 5%

[0041] POE: 5%

[0042] Liquid paraffin: 1%

[0043] Dibutyl phthalate: 0.5%

[0044] N,N'-bisethylene stearamide: 1%

[0045] RDP: 15%

[0046] Epoxy: 5%

[0047] 3000 mesh superfine magnesium hydroxide: 5%

[0048] Antioxidant 1010: 0.1%

[0049] The preparation method includes: (1) first drying the plant fiber at 130°C for 6 hours, so that the moisture content of the plant fiber is below 2%;

[0050] (2) In the high mixer, use the fuel injection system of the high mixer to carry out fuel injection premixing treatment to the plant fiber, dispersant and flame retardant synergist with a flame retardant to obtain a flame retardant plant fiber;

[0051] (3) Mix the flame retardant plant fiber and all other components in a high mixer in proportion to obtain a premix;

[0052] (4) Add the premixed material into a...

Embodiment 2

[0063] Raw material components are calculated by mass percentage as:

[0064] Homopolymer PP: 39.4%

[0065] 100 mesh bamboo powder: 25%

[0066] POE-g-MAH: 5%

[0067] EPDM: 5%

[0068] Liquid paraffin: 1%

[0069] Silane coupling agent: 0.5%

[0070] N,N'-bisethylene stearamide: 1%

[0071] TPP: 13%

[0072] Pentaerythritol: 5%

[0073] 3000 mesh superfine magnesium hydroxide: 5%

[0074] Antioxidant 1010: 0.1%

[0075] According to the preparation process described in Example 1, the halogen-free flame-retardant injection molding grade PP wood-plastic composite material was obtained by extrusion granulation.

[0076] The tested properties of the above-mentioned wood-plastic composite materials are as follows:

[0077] Specific gravity 1.15g / cm 3

[0078] Tensile strength 28.8Mpa

[0079] Elongation 16.1%

[0080] Izod beam unnotched impact strength 276J / m

[0081] Bending strength 40.1MPa

[0082] Flexural modulus 2418Mpa

[0083] Melt index (200°C, 5kg) 8.3...

Embodiment 3

[0086] Raw material components are calculated by mass percentage as:

[0087] HDPE: 37.9%

[0088] 100 mesh bamboo powder: 25%

[0089] PE-g-MAH: 5%

[0090] POE: 5%

[0091] Liquid paraffin: 0.5%

[0092] Dibutyl phthalate: 0.5%

[0093] N,N'-bisethylene stearamide: 1%

[0094] RDP: 15%

[0095] Phenolic resin: 5%

[0096] 3000 mesh magnesium hydroxide: 5%

[0097] Antioxidant 1010: 0.1%

[0098] According to the preparation process described in Example 1, the halogen-free flame-retardant injection molding grade HDPE wood-plastic composite material was obtained by extrusion granulation.

[0099] The tested properties of the above-mentioned wood-plastic composite materials are as follows:

[0100] Specific gravity 1.13g / cm 3

[0101] Tensile strength 22.4Mpa

[0102] Elongation 21.6%

[0103] Izod beam unnotched impact strength 348J / m

[0104] Bending strength 29.7MPa

[0105] Flexural modulus 1819Mpa

[0106] Melt index (200°C, 5kg) 7.6g / 10min

[0107] Flame...

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Abstract

The invention discloses a halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and a preparation method thereof. The halogen-free flame-retardant polyolefin injection-grade wood-plastic composite comprises the following components in percentage by mass: 25 to 70 percent of polyolefin resin, 5 to 50 percent of plant fiber, 0.5 to 20 percent of compatilizer, 0 to 30 percent of flexibilizer, 0.5 to 8 percent of dispersant, 5 to 40 percent of fire retardant and synergist and 0 to 1 percent of antioxidant. Compared with the conventional wood-plastic composite, the halogen-free flame-retardant polyolefin injection-grade wood-plastic composite prepared by the invention has the characteristics of simple production flow, less fire retardant dosage, good halogen-free flame-retardant effect, wide molding mode range and the like, and is suitable for various injection-molded products such as shells of electrical appliance products, furniture, materials for automobiles, artworks, building products with complex construction and the like.

Description

technical field [0001] The invention relates to a wood-plastic composite material preparation process and its application field, in particular to a polyolefin halogen-free flame-retardant injection molding-grade wood-plastic composite material. Background technique [0002] Wood-plastic composite material is a new type of environmentally friendly material prepared by using plant fiber and thermoplastic resin as the main raw materials and adding certain processing aids. This material can alleviate the consumption of petroleum, and at the same time, a large amount of waste plant fibers and recycled plastics are used, which can not only alleviate the consumption of petroleum resources in modern society, but also reduce the consumption of wood resources. It is an effective means to protect the environment and reduce energy consumption. [0003] In view of the many advantages of wood-plastic composite materials, its market has grown rapidly in recent years, especially in interior...

Claims

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Application Information

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IPC IPC(8): C08L23/00C08L23/12C08L23/14C08L23/06C08L23/08C08L97/02C08K13/06C08K9/04C08K5/523C08K5/12C08K5/20C08K3/22C08K5/54C08K5/053
Inventor 胡志华付锦锋刘建中王林郭少华黄恒梅
Owner KINGFA SCI & TECH CO LTD
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