Halogen-free flame-retardant polyolefin injection-grade wood-plastic composite and preparation method thereof
A wood-plastic composite material and flame-retardant technology, which is applied in the field of polyolefin halogen-free flame-retardant injection-grade wood-plastic composite materials, and can solve the problem that ammonium polyphosphate is easily decomposed, the fluidity of wood-plastic composite materials is poor, and the amount of flame retardant added Large and other problems, to achieve the effect of good halogen-free flame retardant effect, wide range of molding methods, and less amount of flame retardant
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Embodiment 1
[0037] Raw material components are calculated by mass percentage as:
[0038] Copolymerized PP: 37.4%
[0039] 100 mesh wood flour: 25%
[0040] PP-g-MAH: 5%
[0041] POE: 5%
[0042] Liquid paraffin: 1%
[0043] Dibutyl phthalate: 0.5%
[0044] N,N'-bisethylene stearamide: 1%
[0045] RDP: 15%
[0046] Epoxy: 5%
[0047] 3000 mesh superfine magnesium hydroxide: 5%
[0048] Antioxidant 1010: 0.1%
[0049] The preparation method includes: (1) first drying the plant fiber at 130°C for 6 hours, so that the moisture content of the plant fiber is below 2%;
[0050] (2) In the high mixer, use the fuel injection system of the high mixer to carry out fuel injection premixing treatment to the plant fiber, dispersant and flame retardant synergist with a flame retardant to obtain a flame retardant plant fiber;
[0051] (3) Mix the flame retardant plant fiber and all other components in a high mixer in proportion to obtain a premix;
[0052] (4) Add the premixed material into a...
Embodiment 2
[0063] Raw material components are calculated by mass percentage as:
[0064] Homopolymer PP: 39.4%
[0065] 100 mesh bamboo powder: 25%
[0066] POE-g-MAH: 5%
[0067] EPDM: 5%
[0068] Liquid paraffin: 1%
[0069] Silane coupling agent: 0.5%
[0070] N,N'-bisethylene stearamide: 1%
[0071] TPP: 13%
[0072] Pentaerythritol: 5%
[0073] 3000 mesh superfine magnesium hydroxide: 5%
[0074] Antioxidant 1010: 0.1%
[0075] According to the preparation process described in Example 1, the halogen-free flame-retardant injection molding grade PP wood-plastic composite material was obtained by extrusion granulation.
[0076] The tested properties of the above-mentioned wood-plastic composite materials are as follows:
[0077] Specific gravity 1.15g / cm 3
[0078] Tensile strength 28.8Mpa
[0079] Elongation 16.1%
[0080] Izod beam unnotched impact strength 276J / m
[0081] Bending strength 40.1MPa
[0082] Flexural modulus 2418Mpa
[0083] Melt index (200°C, 5kg) 8.3...
Embodiment 3
[0086] Raw material components are calculated by mass percentage as:
[0087] HDPE: 37.9%
[0088] 100 mesh bamboo powder: 25%
[0089] PE-g-MAH: 5%
[0090] POE: 5%
[0091] Liquid paraffin: 0.5%
[0092] Dibutyl phthalate: 0.5%
[0093] N,N'-bisethylene stearamide: 1%
[0094] RDP: 15%
[0095] Phenolic resin: 5%
[0096] 3000 mesh magnesium hydroxide: 5%
[0097] Antioxidant 1010: 0.1%
[0098] According to the preparation process described in Example 1, the halogen-free flame-retardant injection molding grade HDPE wood-plastic composite material was obtained by extrusion granulation.
[0099] The tested properties of the above-mentioned wood-plastic composite materials are as follows:
[0100] Specific gravity 1.13g / cm 3
[0101] Tensile strength 22.4Mpa
[0102] Elongation 21.6%
[0103] Izod beam unnotched impact strength 348J / m
[0104] Bending strength 29.7MPa
[0105] Flexural modulus 1819Mpa
[0106] Melt index (200°C, 5kg) 7.6g / 10min
[0107] Flame...
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