Binder used between urethane foam and glass fiber reinforced plastic of LNG ships
A technology for polyurethane foam and LNG ships, which is applied in the field of ultra-low temperature and water-resistant adhesives and epoxy-modified silicone polyurethane ultra-low temperature and water-resistant adhesives. And other problems, to achieve high shear strength and water resistance, the effect of mechanical properties unchanged
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Embodiment 1
[0024] The adhesive is prepared according to the following composition ratio (mass percentage):
[0025] Silicone polyurethane modified prepolymer 30%,
[0026] epoxy resin 5%,
[0027] Solvent 10%,
[0028] 1,4 Butanediol 15%,
[0029] Expanded Vermiculite 2%,
[0030] SiO 2 18%,
[0031] CaCO 3 12%,
[0032] CaCl 2 8%.
[0033] The preparation method of this adhesive is:
[0034] 1. Mix the silicone polyurethane modified prepolymer with the solvent and stir evenly in the reaction kettle, and pack it as component A;
[0035] 2. Add the above-mentioned mixed filler, chain extender and appropriate solvent to the epoxy resin, and gradually stir evenly, and pack it as component B;
[0036] 3. When bonding materials, add B to component A in proportion, and stir evenly, then apply and bond.
[0037] Embodiment effect: resistance to low temperature -196 degrees, high temperature 180 degrees, b...
Embodiment 2
[0039] The adhesive is prepared according to the following composition ratio (mass percentage):
[0040] Silicone polyurethane modified prepolymer 40%,
[0041] epoxy resin 5%,
[0042] Solvent 10%,
[0043] Ethylene glycol 15%,
[0044] Expanded Vermiculite 1%,
[0045] SiO 2 5%,
[0046] CaCO 3 14%,
[0047] CaCl 2 10%.
[0048] The preparation method of this adhesive is the same as in Example 1.
[0049] Embodiment effect: resistance to low temperature -200 degrees, high temperature 180 degrees, bonding shear force between FRP and polyurethane foam is 22MPa.
Embodiment 3
[0051] The adhesive is prepared according to the following composition ratio (mass percentage):
[0052] Silicone polyurethane modified prepolymer 40%,
[0053] epoxy resin 10%,
[0054] Solvent 10%,
[0055] Chain Extender MOCA 10%,
[0056] Expanded Vermiculite 3%,
[0057] SiO 2 10%,
[0058] CaCO 3 12%,
[0059] CaCl 2 5%.
[0060] The preparation method of this adhesive is the same as in Example 1.
[0061] Embodiment effects: low temperature resistance -196 degrees, high temperature 200 degrees, bonded glass fiber reinforced plastic and polyurethane foam joint shear force 21MPa.
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