Environmental-friendly type foamless anti-staining detergent, preparing method and application thereof
A cleaning agent and anti-fouling technology, applied in detergent compositions, chemical instruments and methods, non-surface-active detergent compositions, etc., can solve the problems of not easy biodegradation, unfavorable environment, etc., and improve color fastness. , good cleaning effect
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Embodiment 1
[0084] 1. Preparation of copolymer:
[0085] A, preparation of initiator aqueous solution: 1.5 grams of potassium persulfate is added 20 grams of water to make initiator aqueous solution;
[0086] B. Synthesis of copolymer: Add 3.5g of N-vinylpyrrolidone, 7.2g of maleic anhydride, 5.0g of itaconic acid, 22g of acrylamide, 50g of water, 6.1g of acrylic acid and 1.5g of methacrylic acid in a 500ml four-neck flask , heat up to 50-70°C, keep warm for 30-60 minutes to fully dissolve the raw materials, add 1.2g of sodium bisulfite and 7g of initiator aqueous solution, the reactants will naturally heat up to 70-90°C, maintain 80-90°C and slowly separate Add dropwise the remaining aqueous solution of potassium persulfate and a mixture of 10g of remaining acrylic acid, 2g of methacrylic acid and 50g of water. After the addition, the temperature of the reactant is raised to 80-100°C for 3-5 hours; after the reaction is completed, the temperature is lowered to below 40°C. The pH value o...
Embodiment 2
[0092] The preparation of the copolymer, the compounding process of the phosphorus-free alkali-resistant high-efficiency chelating dispersion stabilizer, and the environment-friendly non-foaming anti-contamination cleaning agent are the same as in Example 1, and its components are as follows:
[0093] A, initiator aqueous solution: potassium persulfate 4.8g, water 20g;
[0094] B. Synthesis of copolymer: Add 5.0g of N-vinylpyrrolidone, 6.6g of maleic anhydride, 4.8g of itaconic acid, 18.8g of acrylamide, 50g of water, 5.8g of acrylic acid and methacrylic acid into a 500ml four-neck flask 0g, heat up to 55-70°C, keep warm for 30-60 minutes to fully dissolve the raw materials, add 1.5g sodium bisulfite and 7g initiator aqueous solution, the reactant will naturally heat up to 70-90°C, and maintain 80-90°C slowly Add dropwise the remaining aqueous solution of potassium persulfate and the mixture of remaining 10g of acrylic acid, 0g of methacrylic acid and 50g of water. After the a...
Embodiment 3
[0098] The preparation of the copolymer, the compounding process of the phosphorus-free alkali-resistant high-efficiency chelating dispersion stabilizer, and the environment-friendly non-foaming anti-contamination cleaning agent are the same as in Example 1, and its components are as follows:
[0099] A, initiator aqueous solution: potassium persulfate 3.5g, water 20g;
[0100] B. Synthesis of copolymer: Add 6.0g of N-vinylpyrrolidone, 9.0g of maleic anhydride, 5.5g of itaconic acid, 15.0g of acrylamide, 50g of water, 4g of acrylic acid and 2g of methacrylic acid in a 500ml four-neck flask , heat up to 55-65°C, keep warm for 30-60 minutes to fully dissolve the raw materials, add 3.0g sodium bisulfite and 7g initiator aqueous solution, the reactants will naturally heat up to 70-90°C, maintain 80-90°C slowly and separate Add dropwise the remaining aqueous solution of potassium persulfate and the mixture of 10.0g of remaining acrylic acid, 2g of methacrylic acid and 50g of water....
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