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Resin solution for preparing melamine formaldehyde resin foam plastics and preparation method thereof

A technology of melamine and formaldehyde resin, which is applied in the field of resin solutions, can solve the problems of short pot life, gelation, and only 4-5 hours of resin, and achieve excellent mechanical properties, convenient preparation, and good storage stability.

Inactive Publication Date: 2010-03-17
SHANGHAI HAOHAI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] To prepare melamine-formaldehyde foamed plastics, melamine-formaldehyde resin (MF resin for short) must first be prepared. At present, the chemical composition of MF resin used to prepare melamine-formaldehyde foamed plastics is polymethylolmelamine, because polymethylolmelamine has reactivity , It is easy to further react and gel during storage. Therefore, when melamine formaldehyde resin is used to prepare foamed plastics, the resin has a short service life, usually only 4-5 hours, which brings great inconvenience to production.
[0005] Although the aqueous solution of melamine-formaldehyde resin can be spray-dried to make powdered MF resin, which can solve the storage problem of MF resin, but when preparing melamine-formaldehyde foamed plastics, it is still necessary to dissolve the powdery MF resin into a solution, because MF There are inevitably a small amount of gel particles in the powder. During the dissolution process, these gel particles cannot be dissolved again, but are dispersed in the MF aqueous solution. In the process of preparing foam plastics, once these particles cannot be removed, these undissolved Particles in the foam will cause local breakage of the foam, or even collapse of the foam

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Preparation of MF resin solution:

[0032] Add 400g of formaldehyde solution with a weight concentration of 37% into a 1000ml three-necked reaction flask equipped with a condenser, a stirrer and a thermometer, adjust the pH value to 8.0 with a weight concentration of 10% sodium hydroxide solution, and then add 250g of melamine to the reaction In the bottle, heated to 78°C, reacted for 2 hours, cooled to 50°C, added 20g of sodium citrate, stirred evenly, and obtained MF resin solution, the viscosity of the solution changed with time is shown in Table 1.

Embodiment 2

[0034] Add 400g of 37% formaldehyde solution into a 1000ml three-necked reaction flask equipped with a condenser, agitator and thermometer, adjust the pH value to 9.5 with sodium hydroxide solution, then add 250g of melamine into the reaction flask, heat to 83°C, After reacting for 2.5 hours, cool to 50° C., add 25 g of sodium borate, and stir evenly to obtain a MF resin solution. See Table 1 for the viscosity of the solution over time.

Embodiment 3

[0041] In the embodiments, the consumption of each material is the weight consumption.

[0042] Preparation of melamine foam:

[0043] The above-mentioned MF resin solution is mixed with relevant foaming aids to make a foamed MF resin solution, and foamed in a microwave foaming device. The foaming formula and the properties of the foam are shown in Table 2.

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PUM

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Abstract

The invention discloses resin solution for preparing melamine formaldehyde resin foam plastics and a preparation method thereof. The preparation method for melamine formaldehyde resin solution comprises the following steps: adding weak-acid-strong-alkali salts into the resin solution, and evenly mixing to prepare the melamine formaldehyde resin solution, wherein the resin solution is a reaction product of melamine and formaldehyde. The melamine formaldehyde resin solution has good storage stability, and has shelf life of above 72 hours when preparing the melamine formaldehyde resin foam plastics so as to greatly facilitate preparing the melamine formaldehyde resin foam plastics. Experiments show that the melamine formaldehyde resin flexible foam plastics prepared from the melamine formaldehyde resin solution have good mechanical property, physiochemical performance and flame resistance.

Description

technical field [0001] The invention relates to a resin solution for preparing melamine-formaldehyde resin foam plastics. Background technique [0002] Melamine foam plastic is a new type of foam plastic with high opening rate and three-dimensional network structure. It has excellent sound absorption performance, flame retardant performance, heat insulation performance, moisture and heat resistance stability, safety and sanitation and secondary processing performance. [0003] Foams made from melamine-formaldehyde resins have better heat resistance, flame retardancy, and insulation than polystyrene and polyurethane foams. Melamine-formaldehyde resin foam can be used as flame-retardant and sound-absorbing materials for buildings and vehicles, and has the functions of light weight, convenient operation, flame-retardant and noise reduction. [0004] To prepare melamine-formaldehyde foamed plastics, melamine-formaldehyde resin (MF resin for short) must first be prepared. At pre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/28C08K5/098C08K3/38C08J9/00
Inventor 徐强王学军季新林刘远中
Owner SHANGHAI HAOHAI CHEM
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