Polyvinyl chloride fiber and poly butylene succinate parallel fiber
A technology of polybutylene succinate and butanediol is applied in fiber processing, fiber chemical characteristics, conjugated synthetic polymer rayon, etc., and can solve the problems of low molecular weight, yellowish color, and not easy to decompose.
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[0016] 1. Preparation of polybutylene succinate: the raw materials are butanediol and succinic acid, the added molar ratio is 1.15, the catalyst is p-toluenesulfonic acid and tetrabutyl titanate, and the synthesis of polyester mainly includes esterification and polycondensation are completed in two steps. In the continuous polymerization process, the esterification reaction is completed through two esterification tanks under normal pressure and reduced pressure, and the polycondensation reaction is completed through two tanks of pre-condensation polymerization and final polycondensation
[0017] Synthetic process of polybutylene succinate:
[0018] condition
Ester I
Esterification II
Precondensation
final polycondensation
140~150
150~160
230~240
230~240
Reaction pressure / Pa
1.3×10 5
65000
3000
70
Residence time / min
70
70
60
150
...
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