Image-forming apparatus and cartridge
By using a combination of specific electrophotographic photoreceptors and toners in the image forming device, problems such as image white bottom contamination, afterimages, and scattering are solved, and high-resolution and high-quality printing is achieved, which satisfies high-speed and long-term use. requirements.
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[0530] Hereinafter, the present invention will be described more specifically by way of examples, but the present invention is not limited to the following examples unless the gist is exceeded. In the following examples, unless otherwise specified, "part" means "weight part", and "%" means "mass %".
[0531]
[0532] For particles with a volume average particle diameter (Mv) of less than 1 μm, the volume average particle diameter (Mv) is measured as follows: Microtrac Nanotrac 150 (model) manufactured by Nikkiso Co., Ltd. (hereinafter, abbreviated as "NANOTRAC") ), according to the operation manual of NANOTRAC, and using the analytical software Microtrac Particle Analyzer Ver10.1.2.-019EE compiled by Nikkiso Co., Ltd., using ion-exchanged water with a conductivity of 0.5 μS / cm as the dispersion medium, under the following conditions or The following conditions were input, and the volume average particle diameter (Mv) was measured by the method described in the instruction ma...
manufacture example 1
[0607]
[0608] 27 parts (540g) of paraffin (HNP-9 manufactured by Nippon Seika Co., Ltd., surface tension 23.5mN / m, thermal characteristics: melting point peak temperature 82°C, heat of fusion 220J / g, melting peak width at half maximum 8.2°C, crystallization temperature 66°C, crystallization peak half width 13.0°C), 2.8 parts of octadecyl acrylate (manufactured by Tokyo Chemical Industry Co., Ltd.), 1.9 parts of 20% by mass sodium dodecylbenzenesulfonate aqueous solution (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd., NEOGEN S20A ) (hereinafter abbreviated as "20% DBS aqueous solution"), 68.3 parts of deionized water were heated to 90° C., and stirred for 10 minutes using a high-speed mixer (manufactured by Tokube Kikka Kogyo Co., Ltd., model: mark II f).
[0609] Next, the dispersion liquid was heated to 90° C., and using a homogenizer (manufactured by Gaulin, 15-M-8PA type), circulation emulsification was started under a pressurized condition of 25 MPa, and disper...
manufacture example 2
[0670]
[0671] In the aggregation process (nuclear material aggregation process and cladding process), circularization process, cleaning process, and drying process of "production of toner base particles A", the "nuclear material aggregation process" and "shell process" Toner mother particles B were obtained in the same manner as in "Manufacturing of toner mother particles A" in Example 1 except that the "circularization step" was changed as follows.
[0672] ○Nuclear material condensation process
[0673] Add polymer primary particle dispersion A1 and 20 to the mixer (capacity 12L, inner diameter 208mm, height 355mm) equipped with stirring device (double propeller blade), heating and cooling device, concentration device and feeding device of various raw materials and additives % DBS aqueous solution, mixed uniformly for 5 minutes at an internal temperature of 7°C. Then keep the internal temperature at 7°C, and add 0.52 parts of a 5% by mass aqueous solution of ferrous sul...
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