Method for preparing jatropha curcas shell-based activated carbon

A technology based on activated carbon and tung nut shell, applied in chemical instruments and methods, inorganic chemistry, non-metallic elements, etc., can solve the problems of long preparation time, environmental hazards, high energy consumption, etc., to improve yield, reduce pollution, improve effect of structure

Inactive Publication Date: 2010-05-19
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are few domestic studies on the preparation of active carbon from Jatropha husks as raw materials. The Chinese patent application with the publication number CN-101112984A discloses "the method for preparing activated carbon by using waste Jatropha husks", although physical and chemical activation methods are used to prepare Jatropha jatropha respectively. Shell activated carbon, but on the one hand, although the product made by chemical method has better performance, it introduces chemical agent in the preparation process, which has certain dangers to the environment; on the other hand, although the physical activation method avoids the damage of chemical agent Introduced, but its activation time reaches 1-3 hours, and the performance of the obtained product is not ideal
Patent 200510010671.7 announced "A method for making mechanism charcoal from agricultural and forestry waste". This method obtains mechanism charcoal through three-stage low-temperature carbonization, but the preparation time of this method is long. Although the preparation is carried out at low temperature, the consumption of energy still bigger
Patent 200510010669.X published "A Method of Physically Treating Tobacco Stem Waste to Make Activated Carbon". This method uses microwave heating to activate water vapor to prepare tobacco stem-based activated carbon. Although the activation time is shortened by microwave heating, the preparation process The flow rate of water vapor is high, which has certain requirements on the quality and corrosion resistance of the equipment. At the same time, more energy is needed to obtain high-flow water vapor, which is not conducive to the simplification and popularization of the process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Put the prepared jatropha shell in a carbonization furnace, raise the temperature to 800°C at a heating rate of 20°C / min and keep it warm for 0.5 hours, and crush the obtained carbonized material to 4 to 20 meshes as an activated material. The temperature was raised to 600°C at a heating rate of ℃ / min, kept for 10 minutes, and then raised to 950°C at a heating rate of 15°C / min, and activated with a water vapor flow rate of 1.21g / min for 35 minutes to obtain a finished activated carbon product. The iodine adsorption value is 1165.3mg / g, and the yield is 29.2%.

Embodiment 2

[0017] Put the prepared jatropha shell in a carbonization furnace, raise the temperature to 800°C at a heating rate of 30°C / min and keep it warm for 1 hour, and crush the obtained carbonized material to 4 to 6 mesh as the activated material. Raise the temperature to 600°C at a heating rate of ℃ / min, keep it warm for 10 minutes, then raise the temperature to 870°C at a heating rate of 10°C / min, and activate with a water vapor flow rate of 4.3g / min for 50 minutes to obtain a finished activated carbon product. The iodine adsorption value is 1087.1 mg / g, and the yield is 23.7%.

Embodiment 3

[0019] Put the prepared jatropha shell in a carbonization furnace, raise the temperature to 800°C at a heating rate of 20°C / min and keep it warm for 0.5 hours, and crush the obtained carbonized material to 4 to 6 mesh as the activated material. Raise the temperature to 600°C at a heating rate of ℃ / min, keep it warm for 8 minutes, then raise the temperature to 960°C at a heating rate of 12°C / min, and activate with a CO2 flow rate of 100ml / min for 40 minutes to obtain a finished activated carbon product. The iodine adsorption value is 1143.1mg / g, and the yield is 31.3%.

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Abstract

The invention relates to a method for preparing jatropha curcas shell-based activated carbon, which uses vapor or a carbon dioxide gas as an activator to activate waste jatropha curcas shells to obtain high-quality activated carbon. The method adopts high-temperature carbonization in the carbonization process, adopts different rates of temperature rise for raising the temperature sectionally in the activating process, and has the advantages of short activating time, low energy consumption, high product yield, cleanness, environment protection and the like. The point adsorption capacity of the product namely the activated carbon reaches the national primary standard. The method has a rich material source, can make full use of the waste jatropha curcas shell resource, decreases the stack of the waste jatropha curcas shells, solves the problem of environmental pollution caused by combustion and opens up a new path for the comprehensive use of jatropha curcas.

Description

1. Technical field [0001] The invention relates to a method for preparing jatropha shell-based activated carbon, which belongs to the technical field of material preparation. 2. Background technology [0002] Jatropha jatropha, also known as bright tung tree and stink tung tree, is one of the important native tree species in dry-hot valleys. At present, Jatropha jatropha is used in agriculture, medicine, environmental protection and ecological construction. In recent years, with the increasing energy consumption, the ensuing environmental problems have become increasingly serious, and people are paying more and more attention to the utilization of bio-energy. Jatropha seeds can be used as raw materials for diesel production, and limited fossil Compared with energy resources, using energy plants such as jatropha to obtain biodiesel is one of the ways to solve the energy crisis and has the advantage of being renewable. However, the processing of jatropha has resulted in the p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/10C01B32/336
Inventor 彭金辉张利波段昕辉张泽彪郭胜惠张正勇
Owner KUNMING UNIV OF SCI & TECH
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