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Recovery process and equipment for ammonia leachate in sanitary landfill of domestic waste

A technology for landfill leachate and domestic waste, which is applied in the recovery process and equipment field of waste leachate ammonia in sanitary landfills of domestic waste. It can solve the problems of high equipment cost, frequent equipment maintenance, and pipeline blockage, so as to reduce emissions. The effect of improving the water quality, improving the quality of water environment, and improving the living conditions of residents

Active Publication Date: 2011-11-30
武汉循环经济研究院 +3
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In particular, it solves the equipment problem of reaction between ammonia-containing gas and sulfuric acid after deamination, overcomes the problems of high cost of ammonium sulfate saturator process equipment, easy blockage of pipelines by ammonium sulfate crystals, frequent equipment maintenance and other problems, high absorption efficiency, and simple operation and management.

Method used

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  • Recovery process and equipment for ammonia leachate in sanitary landfill of domestic waste
  • Recovery process and equipment for ammonia leachate in sanitary landfill of domestic waste
  • Recovery process and equipment for ammonia leachate in sanitary landfill of domestic waste

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Embodiment Construction

[0042] The removal principle of ammonia in the leachate of domestic garbage sanitary landfill:

[0043] Ammonia in landfill leachate is generally expressed as ammonium ion (NH 4 + ) and free ammonia (NH 3 ) form, and maintain the following ionization balance in water:

[0044] (1)

[0045] This balance is affected by pH. When the pH value increases, the balance shifts to the right and free ammonia increases; when the pH value decreases, the balance shifts to the left and the ammonium ions increase. When the pH of the water rises to about 11, the ammonia in the water is almost all in the form of NH 3 Exists in the form of ammonia, if it is stirred, aerated, etc., it can promote the transfer of ammonia from the water to the atmosphere.

[0046] Absorption principle of ammonia-containing gas in leachate of sanitary landfill of domestic waste:

[0047] Sulfuric acid absorbs ammonia in ammonia-containing gas to obtain ammonium sulfate, and its chemical reaction formula is:...

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Abstract

The invention provides a process and equipment for recovering ammonia from landfill leachate of domestic waste sanitary landfill. The first step is to remove ammonia from the landfill leachate: adding alkaline chemicals to the leachate to adjust the pH of the leachate The value is 9-11; the ammonia in the landfill leachate is removed in the deammonization tower by air stripping; the second step is the recovery of ammonia: the ammonium sulfate is recovered by the sulfuric acid solution absorption method for the ammonia-containing gas. Two absorption reactors are used for absorption. In the first absorption reactor, 85% to 95% of the ammonia-containing gas is treated. The concentration of ammonium sulfate in the circulating mother liquor of the first absorption reactor is lower than the saturation concentration of ammonium sulfate. Avoid the generation of ammonium sulfate crystallization; the unsaturated circulating mother liquor in the first absorption reactor is sent to the second absorption reactor to continue to react with 5% to 15% ammonia-containing gas, so that the second absorption reaction circulates in the mother liquor The concentration of ammonium sulfate is higher than the saturation concentration of ammonium sulfate, which promotes the generation of ammonium sulfate crystals; the third step is the separation of ammonium sulfate crystals.

Description

technical field [0001] The invention relates to a recovery process and equipment for ammonia leachate in domestic garbage sanitary landfills, and in particular to the technical field of domestic garbage treatment and utilization. Background technique [0002] Sanitary landfill is a method of disposing solid waste widely used in my country in recent years. For an anaerobic landfill, its mechanism is to use anaerobic fermentation method to convert organic matter in garbage into gaseous products such as carbon dioxide and methane through the degradation of anaerobic and facultative microorganisms. Since municipal solid waste itself contains a lot of water, it will leach out in the form of leachate during the bioconversion process. At the same time, affected by factors such as rainfall and runoff, landfills will also pass through percolation to form landfill leachate. [0003] The composition of landfill leachate is complex, and its composition depends not only on the landfill...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/20C01C1/10
Inventor 李武梁顺文黄凯兴李育杰徐殿广陈石孟了王克虹冯向明李智勤顾飞孙志军
Owner 武汉循环经济研究院
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