High barrier coextruded stretch film
A co-extrusion, high-barrier technology, applied in the direction of chemical instruments and methods, layered products, synthetic resin layered products, etc., can solve the problems of inability to arrange molecular chains or crystal planes in an orderly manner
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Embodiment 1
[0125] Embodiment one: the structural expression is: A-P i -B-P j -C
[0126] In the formula, A is specifically PP; P i Specifically, it is a three-layer structure: HDPE / EVA / anhydride-modified low-density polyethylene; B is specifically EVOH; P j Specifically, it is a four-layer structure: anhydride-modified low-density polyethylene / EVA / LDPE / MPE; C is specifically an ion-type polymer.
[0127] Its specific structure has 10 layers:
[0128] PP / HDPE / EVA / anhydride modified low density polyethylene / EVOH / anhydride modified low density polyethylene / EVA / LDPE / MPE / ionic polymer
[0129] Among them, the melting point of PP (A) is about 215°C, the melting point of EVOH (B) is about 183°C, and the melting point of ionic polymer (C) is about 98°C. Therefore, the aggregation state between A and B The transformation temperature difference is 32°C, and the aggregate transformation temperature difference between B and C is 85°C; therefore, an internal stress gradient distribution bridge P...
Embodiment 2
[0130] Embodiment two: the structural expression is: A-P i -B-P j -C
[0131] In the formula, A is specifically PA66; P i Specifically, it is a five-layer structure: anhydride-modified high-density polyethylene blended HDPE / HDPE / LDPE / EAA / EVA; B is specifically PVDC; P j Specifically, it is a three-layer structure: EVA / MPE / HDPE; C is specifically COPP.
[0132] Its specific structure has 11 layers:
[0133] PA66 / anhydride modified HDPE blend HDPE / HDPE / LDPE / EAA / EVA / PVDC / EVA / MPE / HDPE / COPP
[0134] Among them, the melting point of PA66 (A) is about 265°C, the softening temperature of PVDC (B) is about 100°C, and the melting point of COPP (C) is about 210°C. Therefore, the aggregated state transformation between A and B The temperature difference is 165°C, and the temperature difference between B and C is 110°C; therefore, an internal stress gradient distribution bridge P is set between A and B i , set internal stress gradient distribution bridge P between B and C j . The 1...
Embodiment 3
[0135] Embodiment three: the structural expression is: A-P i -B-P j -C
[0136] In the formula, A is specifically HDPE blended MPE; P i Specifically, it is a three-layer structure: LLDPE / LDPE / anhydride-modified low-density polyethylene; B is specifically PA; P j Specifically, it is a three-layer structure: anhydride-modified ethylene-vinyl acetate copolymer / EVA / EMAA; C is VLDPE (ultra-low-density polyethylene).
[0137] Its specific structure has 9 layers:
[0138] HDPE blend MPE / LLDPE / LDPE / anhydride modified low density polyethylene / PA / anhydride modified ethylene-vinyl acetate copolymer / EVA / BMAA / VLDPE
[0139] Among them, the melting point of HDPE blended MPE (A) is about 130°C, the melting point of PA (B) is about 220°C, and the melting point of VLDPE (C) is about 90°C. Therefore, the aggregation state between A and B The transformation temperature difference is 90°C, and the aggregate transformation temperature difference between B and C is 130°C; therefore, an interna...
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