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Method for infiltrating aluminum molybdenum rare earth coating on surface of steel

A steel surface and coating technology, applied in coating, metal material coating process, solid-state diffusion coating, etc., can solve the problems of environmental pollution, high labor intensity, and large dust, so as to reduce labor intensity and save effective space , the effect of avoiding dust pollution

Active Publication Date: 2011-05-11
CHINA PETROCHEMICAL CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] There is also a common problem in the above inventions, that is, the infiltrated components need to be embedded in powder, which is labor intensive, dusty, and pollutes the environment.

Method used

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  • Method for infiltrating aluminum molybdenum rare earth coating on surface of steel
  • Method for infiltrating aluminum molybdenum rare earth coating on surface of steel
  • Method for infiltrating aluminum molybdenum rare earth coating on surface of steel

Examples

Experimental program
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Effect test

Embodiment 1

[0048] The co-penetrating agent of the present invention is formulated, wherein the weight % is based on the total weight of the co-penetrating agent. The 2.5% MoO 3 , 35% Al, 54% FeAl, 8% Rare Earth Oxide and 0.5% NH 4 Cl is fully mixed, the mixed co-penetrating agent, the binder polyvinyl alcohol and water are fully mixed and stirred to prepare a slurry; the slurry is coated on the surface of the metal workpiece 9 with a thickness of 0.8mm, and then the workpiece 9 is placed. Put it into the drying furnace, dry it at 80℃ for 60min, put the dried metal workpiece 9 into the infiltration box 8, see figure 1 . Formulated Sealer 6, 35% Al, 56.4% FeAl, 8% Rare Earth Oxide, 0.6% NH 4 Cl is fully mixed, the evenly mixed sealing agent 6 is put into the box body 5, then the box body 5 is placed on the open end of the infiltration box, and the infiltration box cover 2 is installed with bolts 4 through the flange 3 on the box body 8 on box 8, see figure 1 . Then put the infiltrati...

Embodiment 2

[0050] The preparation process of the co-penetrating agent, the slurry and the sealing agent and the coating, drying and boxing process of the workpiece are the same as those in Example 1. The composition of the co-penetrant is 5% MoO 3 , 28% Al, 60.4% FeAl, 6% Rare Earth Oxide and 0.6% NH 4Cl, the slurry coating thickness is 1.2mm. The composition of the sealer is 28% Al, 66.2% FeAl, 5% Rare Earth Oxide, 0.8% NH 4 Cl. The co-infiltration heat treatment process is as follows: heating from room temperature to 450°C at a heating rate of 10°C / min, holding for 0.5h, then heating from 450°C to 980°C at a heating rate of 8°C / min, holding for 5h, and then cooling to room temperature with the furnace in air , to obtain aluminum-molybdenum rare-earth co-infiltration workpieces and samples. The functions of the vent holes and the ventilation holes are the same as those in Example 1.

Embodiment 3

[0052] The preparation process of the co-penetrating agent, the slurry and the sealing agent and the coating, drying and boxing process of the workpiece are the same as those in Example 1. The composition of the co-penetrant is 8% MoO 3 , 26% Al, 62.8% FeAl, 2% Rare Earth Oxide and 1.2% NH 4 Cl, the slurry coating thickness is 1.5mm. The composition of the sealer is 26% Al, 70.6% FeAl, 2% Rare Earth Oxide, 1.4% NH 4 Cl. The co-infiltration heat treatment process is as follows: the temperature is raised from room temperature to 450°C at a heating rate of 10°C / min, and the temperature is kept for 0.5h. Then, the temperature was increased from 450 °C to 1000 °C at a heating rate of 8 °C / min, and the temperature was maintained for 4 hours, and then air-cooled to room temperature in the furnace to obtain aluminum-molybdenum rare-earth co-infiltration workpieces and samples. The functions of the vent holes and the ventilation holes are the same as those in Example 1.

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Abstract

The invention provides a method for infiltrating an aluminum molybdenum rare earth coating on the surface of steel, which mainly solves the problem of dust caused by powder embedding, realizes aluminum molybdenum rare earth co-infiltrating, and comprises the following steps of: (a) mixing a co-infiltrating agent, a binder and water to form slurry, coating on the surface of a workpiece, and drying; (b) putting the dried workpiece into an infiltrating box, sealing the inlet of the infiltrating box by using a box body filled with a sealing agent, and sealing by using an infiltrating box cover; and (c) putting the sealed infiltrating box into a furnace, heating, preserving heat, discharging and performing air cooling, wherein the co-infiltrating agent consists of 2.5 to 15 percent of MoO3, 17 to 35 percent of Al, 54 to 66 percent of FeAl, 0.5 to 8 percent of rare earth oxide and 0.5 to 1.5 percent of NH4Cl; and the sealing agent consists of 17 to 35 percent of Al, 56 to 77 percent of FeAl, 2 to 8 percent of rare earth oxide and 0.6 to 2 percent of NH4Cl. The method can realize the aluminum molybdenum rare earth co-infiltrating, ensures that the coating has high corrosion resistance and heat stability, does not need the powder embedding and avoids dust pollution.

Description

technical field [0001] The invention relates to a method for infiltrating aluminum-molybdenum rare-earth coatings on steel surfaces. Background technique [0002] In the past ten years, metal surface multi-infiltration has been widely developed in metal surface strengthening. A large number of literatures show that the addition of molybdenum element to the aluminized layer can further improve the corrosion resistance, thermal stability and erosion resistance of the aluminized layer. Adding rare earth elements to the aluminized layer can not only improve the adhesion and plasticity of the oxide film on the surface of the aluminized layer, but also effectively prevent the diffusion of oxygen and sulfur into the matrix. Therefore, it is expected to obtain a coating with excellent comprehensive properties by co-infiltration of aluminum, molybdenum and rare earth on the surface of carbon steel. [0003] Chinese patent CN1526849 "a process for generating a molybdenum-containing ...

Claims

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Application Information

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IPC IPC(8): C23C10/30
Inventor 盛长松李选亭晁君瑞刘文亮刘希武苗普
Owner CHINA PETROCHEMICAL CORP