Preparation method and usage of mineral stabilizer for controlling release of phosphor and heavy metals in dredged sediment
A technology for dredging sediment and minerals, applied in chemical instruments and methods, sludge treatment, water/sludge/sewage treatment, etc., and can solve the problems of high treatment costs and difficult large-scale application.
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example 1
[0017] Example 1 (static experiment)
[0018] The red mud and fly ash are ground separately until the particle size is less than 0.425mm, and compounded according to the mass ratio of 1:1, the mineral stabilizer can be prepared.
[0019] The dredged sediment and the mineral stabilizer are evenly mixed according to the mass ratio of 0%, 1%, 3%, 5%, 7%, and 10%. The proportion increases, and the degree of compaction of the dredged bottom mud is strengthened. Take out the cultured dredged sediment and freeze-dry it or dry it naturally, grind and crush it through a 100-mesh sieve; take 2.5g samples respectively, add deionized water according to the solid-liquid ratio of 1:20, and set the temperature at 25°C at a speed of 30r / min. Shake on a tumble shaker for 18 hours; measure the pH of the leachate, then filter through a 0.45 micron membrane, and measure phosphorus with a spectrophotometer.
[0020] Experiments show that: mixing 1%-10% mineral stabilizer in the dredged sediment ...
example 2
[0021] Example 2 (dynamic experiment)
[0022] Red mud and phosphogypsum are respectively ground to a particle size of less than 0.425 mm, and compounded at a mass ratio of 3:7 to prepare a mineral stabilizer.
[0023] The dredged bottom mud and the mineral stabilizer are uniformly mixed according to the weight ratio of 0%, 3%, 5%, and 10%, and are respectively loaded into columns with an inner diameter of 40mm and a height of 500mm. Cultivate in airtight shade for 3 days. Add acidic extractant once every four days, add 125ml acidic extractant 8 times in a row (pH = 4.2 extractant in the US Environmental Protection Agency SPLP method is used for leaching experiments to evaluate the fixation of heavy metals in dredged sediment by mineral stabilizers effect), pass through a 0.45 micron membrane filter, measure copper, lead, zinc, and chromium heavy metals with inductively coupled plasma emission spectroscopy, and measure arsenic with atomic fluorescence.
[0024] Experiments s...
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