Salt-free rolling, baking, dying and low-temperature soaping method for fiber reactive dyes
A technology of reactive dyes and low-temperature soap, applied in the field of printing and dyeing, can solve the problems of unrealized industrial production, low dyeing and fixing rate, low dyeing and fixing rate, etc., and achieves simple and easy operation, good reproducibility, The effect of reducing steam usage
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Embodiment 1
[0024] Embodiment 1: Preparation of polyene polyamine quaternary ammonium salt
[0025] In an ice bath at -10°C, add 20 grams of diethylenetriamine dropwise to 10 grams of epichlorohydrin. After the dropwise addition, keep the temperature at 20°C for 6 hours, then add 1 gram of caustic soda and react for 2 hours to produce The compound a of structure shown in formula (I); Compound a is warmed up to 50 ℃, dropwise adds 200 grams of quaternizing reagent benzyl chloride, after dropping, keep warm for 5 hours, obtain the polyphenol with structure shown in formula (II) Polyamine quaternary ammonium salt, wherein R is benzyl;
[0026]
Embodiment 2
[0027] Embodiment 2: Preparation of polyene polyamine quaternary ammonium salt
[0028] In an ice bath at 30°C, add 1000 g of diethylenetriamine dropwise to 500 g of epichlorohydrin, keep warm at 0°C for 4 hours after the dropwise addition, then add 10 g of caustic soda and react for 1 hour to generate (I) compound a of the shown structure; compound a is heated up to 120 DEG C, dropwise add 2000 grams of quaternization reagent benzyl chloride, after the dropwise addition is completed, it is incubated for 2 hours to obtain a polyene having a structure shown in formula (II) Polyamine quaternary ammonium salt, wherein R is benzyl;
[0029]
Embodiment 3
[0030] Embodiment 3: Preparation of polyene polyamine quaternary ammonium salt
[0031] In an ice bath at 10°C, add 500 g of diethylenetriamine dropwise to 200 g of epichlorohydrin, keep the temperature at 30°C for 3 hours after the dropwise addition, then add 5 g of caustic soda and react for 2 hours to produce a formula (I) Compound a of the shown structure; Compound a is heated up to 90°C, 1000 grams of benzyl chloride, a quaternizing agent, is added dropwise, and after the dropwise addition, it is incubated for 4 hours to obtain a polyene having a structure shown in formula (II) Polyamine quaternary ammonium salt, wherein R is benzyl;
[0032]
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