Electroconductive color slurry and low-resistance polyurethane material thereof

A polyurethane material and color paste technology, which is applied in the field of polyurethane materials, can solve the problems of insufficient improvement in the antistatic performance of polyurethane materials, such as the physical and mechanical properties of polyurethane materials, and achieve control of cell nucleation rate, low humidity dependence, and improved electrical conductivity Effect

Active Publication Date: 2012-01-25
SHENZHEN SELEN SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention is that adding low-molecular antistatic agents to the color paste in the prior art is not enough to improve the antistatic performance of polyurethane materials, and excessive addition of color pastes with antistatic agents will easily affect the physical properties of polyurethane materials. To overcome the defects in mechanical properties, provide a conductive color paste that can obtain good antistatic performance with a small amount of addition

Method used

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  • Electroconductive color slurry and low-resistance polyurethane material thereof
  • Electroconductive color slurry and low-resistance polyurethane material thereof
  • Electroconductive color slurry and low-resistance polyurethane material thereof

Examples

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Effect test

Embodiment 1

[0028] Embodiment 1, a kind of conductive color paste, including the following raw materials by weight: carbon powder (0.7 μm) 55, 1-ethyl-3-methylimidazolium chloride 43, DA dispersant (sodium polyacrylate) 0.5, Titanate coupling agent 0.2.

[0029] Preparation method: fully stir and mix carbon powder, ionic liquid (1-ethyl-3-methylimidazolium chloride), dispersant and titanate coupling agent, and then use a three-roll mill at a rate of one kilogram per 10 minutes. Grind at a speed for 3 times, or use a ball mill for 3 times at a speed of 1 kg per 15 minutes, so that the mixture forms a homogeneous phase, that is, a conductive color paste A is obtained.

Embodiment 2

[0030] Embodiment 2, a kind of conductive color paste, including the following raw materials by weight: carbon powder (0.7 μm) 50, 1-ethyl-3-methylpyridine bisfluoroalkylsulfonylamide salt 53, DA dispersant (sodium polyacrylate) 0.5, phosphate coupling agent 1.

[0031] Preparation method: fully stir and mix carbon powder, ionic liquid (1-ethyl-3-methylpyridine bisfluoroalkylsulfonylamide salt), dispersant and titanate coupling agent, and then use a three-roll mill Grind 4 times at a speed of 1 kg per 10 minutes, or use a ball mill for 3 times at a speed of 1 kg per 15 minutes, so that the mixture forms a homogeneous phase, that is, conductive paste B is obtained.

Embodiment 3

[0032] Embodiment 3, a kind of conductive color paste, including the following raw materials by weight: carbon powder (0.7 μm) 45, 1-ethyl-3-methylimidazole nitrate 52, DA dispersant (sodium polyacrylate) 0.5, Titanate coupling agent 0.5.

[0033]Preparation method: fully stir and mix carbon powder, ionic liquid (1-ethyl-3-methylimidazolium nitrate), dispersant and titanate coupling agent, and then use a three-roll mill at a rate of one kilogram per 10 minutes. Grind at a speed for 5 times, or use a ball mill for 4 times at a speed of 1 kg per 15 minutes, so that the mixture forms a homogeneous phase, that is, a conductive color paste C is obtained.

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Abstract

The invention discloses electroconductive color slurry and a low-resistance polyurethane material thereof. The electroconductive color slurry is prepared from the following raw materials in parts by weight: 35-55 parts of carbon powder, 30-60 parts of ionic liquid and 0.2-1 part of dispersant. The low-resistance polyurethane material is prepared from the following raw materials in parts by weight: 100 parts of polyester polyol, 0.8-9 parts of electroconductive color slurry, 100-120 parts of isocyanate and 0.5-3 parts of catalyst. The electroconductive color slurry provided by the invention has low addition amount and good electrical conductivity; and the low-resistance polyurethane material provided by the invention is applicable to dust-free room and other clean places, and has good antistatic property, low humidity dependence and good physical and mechanical properties.

Description

technical field [0001] The invention relates to a color paste and a polyurethane material using the color paste, in particular to a conductive color paste and a low-resistance polyurethane material thereof. The color paste can be widely used in polyurethane microcellular elastomer and polyurethane foam (foam density > 0.05g / cm 3 ), effectively reducing the volume resistance of elastomers and foams. Background technique [0002] Black color paste is generally made of carbon black, talc powder and base resin after grinding and mixing. It is an auxiliary agent commonly used in the preparation of polyurethane materials. Adding this auxiliary agent can give polyurethane materials a uniform black tone. However, when used in the production of antistatic materials, black colorants are added together with commonly used low molecular antistatic agents, but the antistatic effect of polyurethane materials is not good and is highly dependent on humidity. Increasing the amount of col...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K5/42C08K5/3445C08K5/3432C08K13/02C08G18/66C08G18/42C08K5/36C08K3/04
Inventor 张强管映亭王晓强
Owner SHENZHEN SELEN SCI & TECH CO LTD
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