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Foaming synthetic leather manufacturing technology based on waterborne polyurethane (WPU)

A water-based polyurethane and manufacturing method technology, applied in the field of synthetic leather manufacturing, can solve the problems of difficult control of cell uniformity, lack of large-scale application, and high solid content of water-based resin, so as to improve international market competitiveness and excellent adhesion. The effect of high degree and strong leather feeling

Active Publication Date: 2013-06-19
DONGTAI FUAN SYNTHETIC MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The uniformity of bubble size and production efficiency produced by mechanical stirring and foaming have been greatly improved in recent years, but in the foaming process, it is required that the water-based resin has a high solid content (more than 50%), and it is necessary to add a foam stabilizer to stabilize the foam. Additives such as additives have defects such as high cost, high process requirements, and difficult control of cell uniformity. Since the 1990s, they have not been used on a large scale.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The manufacture of embodiment 1 garment leather

[0046] (1) Preparation of water-based polyurethane surface layer slurry, water-based polyurethane foam layer slurry and water-based adhesive:

[0047](a) Preparation of water-based polyurethane surface layer slurry

[0048] Use 100 parts of aromatic water-based polyurethane for the surface layer with an elastic modulus of 50MPa, 20 parts of water-based color paste, 0.2 parts of water-based leveling agent, 0.1 part of water-based defoamer, 0.3 parts of water-based non-ionic PU thickener, water-based polycarbonate Mix 2 parts of diimine evenly to prepare a surface layer slurry with a viscosity of 2500mPa.s;

[0049] (b) Preparation of water-based polyurethane microsphere foam layer slurry

[0050] Mix 100 parts of water-based polyurethane with an elastic modulus of 25MPa, 3 parts of microsphere foaming agent with a particle size of 25 μm, 0.2 parts of water-based leveling agent, 0.1 part of water-based defoamer, and 0.3 ...

Embodiment 2

[0065] The manufacture of embodiment 2 luggage leather

[0066] (1) Preparation of water-based polyurethane surface layer slurry, water-based polyurethane foam layer slurry and water-based adhesive:

[0067] (a) Preparation of water-based polyurethane surface layer slurry

[0068] 100 parts of aliphatic polyurethane for the water-based surface layer with an elastic modulus of 60MPa, 20 parts of water-based color paste, 0.3 parts of water-based leveling agent, 0.2 parts of water-based defoamer, 0.4 parts of water-based thickener, and 3 parts of water-based polyethylenimine Mix evenly to form a surface layer slurry with a viscosity of 2700mPa.s;

[0069] (b) Preparation of water-based polyurethane microsphere foam layer slurry

[0070] Mix 100 parts of water-based aliphatic polyurethane with an elastic modulus of 45 MPa, 4 parts of microsphere foaming agent with a particle size of 40 μm, 0.3 parts of water-based leveling agent, 0.2 parts of water-based defoamer, and 0.4 parts ...

Embodiment 3

[0085] The manufacture of embodiment 3 upper leather

[0086] (1) Preparation of water-based polyurethane surface layer slurry, water-based polyurethane foam layer slurry and water-based adhesive:

[0087] (a) Preparation of water-based polyurethane surface layer slurry

[0088] 100 parts of water-based aromatic polyurethane for the surface layer with an elastic modulus of 70MPa, 20 parts of water-based color paste, 0.5 parts of water-based leveling agent, 0.3 parts of water-based defoamer, 0.5 parts of water-based non-ionic polyurethane, and epoxy resin crosslinking agent Mix 2 parts with 3 parts of blocked water-based polyurethane mixed cross-linking agent evenly, and make a surface layer slurry with a viscosity of 3000mPa.s;

[0089] (b) Preparation of water-based polyurethane microsphere foam layer slurry

[0090] Mix 100 parts of aromatic waterborne polyurethane with elastic modulus of 50MPa, 6 parts of microsphere foaming agent with particle size of 30 μm, 0.5 part of ...

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Abstract

The invention provides a foaming synthetic leather manufacturing technology based on waterborne polyurethane (WPU). In the manufacturing technology, the WPU is taken as a main raw material, and a hollow microsphere foaming agent is taken as a foaming material; and the technology can be widely used for manufacturing synthetic leathers such as clothing leathers, luggage leathers, shoe upper leathers, sofa leathers, home interior trim leathers and the like. The content of volatile organic compounds (VOC) in the finished leather is lower than 2mg / kg (leather), and the air permeability and moisture penetrability are good, thus meeting the EU (European Union) requirements for the ecological synthetic leather; and in addition, the foaming synthetic leather has the advantages of moderate foaming multiplying power, uniform and compact foaming holes, bulky and firm hand feel as well as good comprehensive performance which is equivalent to or superior to that of a solvent-borne product. The foaming synthetic leather manufacturing technology based on the WPU provided by the invention has the beneficial effects that by adopting the WPU instead of the traditional solvent-borne PU, organic pollution is eliminated from a source, organic solvent resources are saved, the comprehensive energy consumption is lowered, the employment environment of laborers is improved, and the ecological grade of the synthetic leather and the international market competitiveness of the product are enhanced, thus achieving obvious innovativeness and remarkable social and economic benefits.

Description

technical field [0001] The invention relates to an environmentally friendly manufacturing method of foamed synthetic leather, which belongs to the field of synthetic leather (PU leather) manufacturing. Background technique [0002] With the improvement of people's living standards, people gradually pursue high-quality daily products, and the demand for leather products is increasing. With the increasing awareness of animal protection, animal leather can no longer meet people's needs. At present, synthetic leather products have gradually become a popular trend in the future. PU synthetic leather has the advantages of exquisite appearance, low price, good physical properties, breathability, and moisture permeability. It has been widely used in the production of luggage, clothing, footwear, furniture, sporting goods, etc. , the synthetic leather industry has also become a pillar industry of the light industry. [0003] Traditional synthetic leather manufacturing processes mai...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06N3/14B32B27/12B32B27/18B32B27/40
Inventor 范浩军刘以东王珊珊徐广梅
Owner DONGTAI FUAN SYNTHETIC MATERIAL CO LTD
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