Titanium hydride hydrogen storage emulsion explosive

A technology of emulsified explosives and titanium hydride, which is applied in explosives, non-explosive/non-thermal agent components, offensive equipment, etc., can solve problems that have not been discovered, and achieve the effect of uniform distribution, low price and small size

Inactive Publication Date: 2012-05-02
UNIV OF SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, there is no report on the use of hydrogen storage material t

Method used

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  • Titanium hydride hydrogen storage emulsion explosive
  • Titanium hydride hydrogen storage emulsion explosive
  • Titanium hydride hydrogen storage emulsion explosive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The total mass of titanium hydride and emulsification matrix is ​​50 g, and the content of titanium hydride is 2% (=1 g) of the total mass. After titanium hydride was added to the emulsified matrix, the mixture was continuously stirred for 30 minutes with a stirrer, and the underwater explosion test was carried out after standing for 10 hours.

[0021] The formulation of the emulsified matrix used is the same as that of the prior art, and the basic formulation is shown in Table 1.

[0022] Table 1 The emulsification matrix formula used in Example 1

[0023] components Nitrate water Span-80 Composite oil phase other content 78 15 2 4 1

[0024] In order to conduct a comparative experiment, the matrix of the emulsion explosive was sensitized by glass microspheres, a conventional sensitizer in the production of emulsion explosives. Existing experiments have shown that: when the content of glass microspheres is 4%, the output energy of th...

Embodiment 2

[0031] The total mass of titanium hydride and emulsification matrix is ​​50g, and the content of titanium hydride is 4% (=2 g) of the total mass. After titanium hydride was added to the emulsified base, it was continuously stirred with a stirrer for 25 minutes, and then the underwater explosion test was carried out after standing for 48 hours. Shock wave curve see image 3 .

[0032] The formulation of the emulsified matrix used is the same as that of the prior art, see Table 3 for details.

[0033] Table 3 The emulsified matrix formula used in Example 2

[0034] components Nitrate water LZ2731 Composite oil phase other content 77 16 2 4 1

[0035] In the underwater explosion test, the shock wave curve obtained is shown in image 3 . In the figure: the abscissa represents time (unit: s), the ordinate represents pressure (unit: MPa), and the underwater explosion shock wave curve is recorded by an oscilloscope. The test parameters are s...

Embodiment 3

[0040] The total mass of titanium hydride and emulsification matrix is ​​50g, and the content of titanium hydride is 6% (=3g) of the total mass. After adding titanium hydride to the emulsification matrix, the stirrer was used to continuously stir for 25 minutes, and the underwater explosion test was carried out after standing for 25 days. The obtained shock wave curve is shown in Figure 4 .

[0041]The formulation of the emulsified matrix used is the same as that of the prior art, see Table 5 for details.

[0042] Table 5 The emulsification base formulation used in Example 3

[0043] components Nitrate water LZ2731 Composite oil phase other content 77 16 2 4 1

[0044] In the underwater explosion test, the shock wave curve obtained is shown in Figure 4 . In the figure: the abscissa represents time (unit: s), the ordinate represents pressure (unit: MPa), and the underwater explosion shock wave curve is recorded by an oscilloscope. Th...

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Abstract

The invention, belonging to the technical field of explosive preparation, particularly relates to an emulsion explosive prepared by using hydrogen storage materials. The explosive comprises an emulsion base and a sensitizing agent, wherein, the sensitizing agent is titanium hydride, the weight of the sensitizing agent accounts for 0.6-8 % of the total weight of the titanium hydride hydrogen storage emulsion explosive, and the purity of titanium hydride is no less than 95 %. During the detonation process, partial titanium hydride reacts with water in the emulsion base to release a little hydrogen, thus a certain foaming effect on the emulsion base is achieved, and the emulsion base is allowed to detonate, so that titanium hydride plays a role as the sensitizing agent. Simultaneously, the rest titanium hydride is subject to thermal decomposition under the effect of high temperature generated by the reaction between emulsion base and hydrogen bubbles to rapidly release hydrogen, and hydrogen continues participating the detonation reaction with the emulsion base to allow the output energy to contain the energy released by the emulsion base and titanium hydride together. The titanium hydride hydrogen storage emulsion explosive disclosed herein has the characteristics of low output explosion pressure, large impulse, long decay time, and high energy.

Description

technical field [0001] The invention belongs to the technical field of explosive preparation, and in particular relates to an emulsion explosive prepared by using a hydrogen storage substance. Background technique [0002] In the production process of emulsion explosives, the W / O emulsion is called emulsion matrix, which is the basic body of emulsion explosives and has good stability and potential detonation performance. The ammonium nitrate aqueous phase solution (oxidant) in the emulsified matrix is ​​dispersed into extremely small particles in the oil phase solution (combustible agent), and its core is a supersaturated inorganic salt solution, which is surrounded by a very thin but high-strength oil film. Shows a higher viscosity. The emulsion matrix is ​​an unsensitized emulsion explosive. It has a high density, requires a lot of detonation energy, and is very difficult to propagate. Therefore, in the process of preparing emulsion explosives, it must be sensitize...

Claims

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Application Information

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IPC IPC(8): C06B31/28C06B31/02C06B23/00
Inventor 马宏昊程扬帆沈兆武杜建国
Owner UNIV OF SCI & TECH OF CHINA
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