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Oil absorbent and oil absorbent manufacturing method

A technology of oil separation and inorganic particles, which is applied in chemical instruments and methods, adsorption water/sewage treatment, centrifugal separation water/sewage treatment, etc. It can solve the problems of reduced strength of oil adsorption materials, poor workability, and labor-intensive separation. Achieve high oil absorption and high strength

Inactive Publication Date: 2012-05-23
KK TOSHIBA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in such a method, not only is it labor-intensive to separate the adsorbed polymer from water, but also there is a problem that the strength of the oil-absorbing material decreases due to the softening of the oil-adsorbed polymer, thereby deteriorating workability.

Method used

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  • Oil absorbent and oil absorbent manufacturing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] Polystyrene (G590; manufactured by Japan Polystyrene Co., Ltd., density 1.05g / cm 3 ) 6 parts by weight are dissolved in the tetrahydrofuran of 300ml to make a solution, and the average particle diameter is 40 parts by weight of octahedral iron ferric oxide particles of 1000nm (density 5.0g / cm 3 , specific surface area 3.0m 2 / g) was dispersed in the solution to obtain a composition.

[0060] This composition was sprayed at 100° C. using a small spray dryer (B-290 type; manufactured by Shibata Scientific Co., Ltd.) to produce spherical resin composites with an average secondary particle diameter of about 20 μm, ie, oil adsorption particles.

[0061] As a result of SEM observation, the oil adsorbed particles were porous. The SEM photograph of the cross section of the oil-adsorbed particles was taken, binarized, and the particle density was obtained. As a result, the particle area was 60%, and particles with gaps in the middle and particle density differences were obtain...

Embodiment 2~5

[0065] Samples were produced in the same manner as in Example 1 except that the amount of resin (content rate of inorganic particles) was changed. The results are shown in Table 1. When the amount of resin decreases (the content of inorganic particles increases), the number of particles in the direction of the cross section decreases, and voids tend to appear. The less the amount of resin, the better the oil absorption rate.

Embodiment 6~8

[0071] Samples were prepared in the same manner as in Example 1 except that the spray temperature was changed. The results are shown in Table 1. When the temperature is raised, the density of the inorganic particles in the cross-section of the composition is inclined. When the spray temperature is above 120°C (boiling point +63.5°C), about half of them are hollow particles, and when the spray temperature is 140°C, about 70% are hollow particles. hollow particles. The oil adsorption rate was higher than that of samples prepared at lower temperature.

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Abstract

Disclosed are an oil absorbent and an oil absorbent manufacturing method for the purpose of recovering oil from water. The oil absorbent is characterized in comprising inorganic particles and a polymer formed on the surface of or between these inorganic particles; the content rate of inorganic particles is no less than 50 vol% and no more than 97 vol% with respect to the inorganic particles and the polymer; and the surface area of the inorganic particles is no less than 30% and no more than 60% with respect to the cross section of the inorganic particles and the polymer. Furthermore, the manufacturing method for oil absorbent particles has a step wherein inorganic particles, a polymer, and a solvent are mixed and a slurry solution is prepared, and a step wherein the slurry solution is sprayed in an environment wherein the temperature is at least 30 DEG C higher than the boiling point of the solvent.

Description

technical field [0001] The present invention relates to an oil adsorbent for recovering oil from water and a method for producing the oil adsorbent. Background technique [0002] In recent years, along with the development of industry and the increase of population, effective use of water resources has been demanded. Therefore, the reuse of wastewater such as industrial drainage is very important. In order to achieve the above objectives, it is necessary to purify the water, that is to separate other substances from the water. [0003] Various methods are known for separating other substances from liquids, and examples thereof include membrane separation, centrifugation, activated carbon adsorption, ozone treatment, flocculation, and removal of suspended matter using a predetermined adsorbent. By such a method, chemical substances such as phosphorus and nitrogen contained in water that have a large impact on the environment can be removed, and oils, clay, etc. dispersed in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01J20/30C02F1/28
CPCC02F2303/16C02F1/288B01J20/26C02F1/281C02F1/285B01J20/3204C02F1/38B01J2220/46C02F1/681C02F2001/007B01J20/06B01J20/3268C02F1/488C02F2101/32
Inventor 深谷太郎藤枝新悦村井伸次铃木昭子辻秀之河野龙兴山田有纱足利伸行
Owner KK TOSHIBA