Method for preparing Pd-only catalyst used for tail gas purification of universal minitype petrol engines

A small gasoline engine and exhaust gas purification technology, applied in the direction of physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of fresh gas loss, short time, high HC emissions, etc. , to improve the activity and durability, simplify the preparation process, and reduce the amount of use

A small gasoline engine and exhaust gas purification technology, applied in the direction of physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of fresh gas loss, short time, high HC emissions, etc. , to improve the activity and durability, simplify the preparation process, and reduce the amount of use

CN102580733AInactive Publication Date: 2012-07-18WUXI WEIFU ENVIRONMENT PROTECTION CATALYST

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Prepare a general-purpose small gasoline engine exhaust gas purification single Pd catalyst: first select a cylindrical carrier wound with a wire mesh, the outer dimension of the carrier is Φ20*20, the diameter of the cylindrical wire mesh carrier is 20mm, the height is 20mm, and the weight of the carrier is 5g. The material of the wire mesh is a FeCrAl alloy material whose grade is OCr20Al5. The carrier is purged with a high-pressure air gun to remove the dust on the inner core of the carrier, and the carrier is baked in an air atmosphere at 600° C. for 4 hours.

[0042] Mix 200g of high specific surface area alumina, 150g of oxygen storage material (Ce60ZrO) with a cerium oxide content of 60% and 50g of pseudoboehmite, add deionized water to adjust the solid content to 20%, the slurry is in a suspended state, and stir for 2 hours. Carry out ball milling, control the particle size D90=30 micron of slurry, add precious metal Pd solution and adjust to concentration to b...

Embodiment 2

[0062] To prepare a general-purpose small gasoline engine exhaust gas purification single Pd catalyst, first select a rectangular parallelepiped carrier wound with wire mesh, and the outer dimension of the carrier is 30*18*18. The length of the rectangular parallelepiped wire mesh carrier is 30mm, the width is 18mm, and the height is 18mm. , the weight of the carrier is 7.6g. The material of the wire mesh is FeCrAl alloy material with the grade of OCr20Al5, and the carrier is purged with a high-pressure air gun to remove the dust on the inner core of the carrier, and the carrier is roasted in an air atmosphere at 600 ° C for 4 hours.

[0063] Mix 200g of high specific surface area alumina, 150g of oxygen storage material (Ce60ZrO) with a cerium oxide content of 60% and 50g of pseudoboehmite, add deionized water to adjust the solid content to 20%, the slurry is in a suspended state, and stir for 2 hours. Carry out ball milling, control the particle size D90=30 microns of the sl...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
specific surface areaaaaaaaaaaa
specific surface areaaaaaaaaaaa
specific surface areaaaaaaaaaaa
Login to View More

Abstract

The invention relates to a method for preparing Pd-only catalyst used for tail gas purification of universal minitype petrol engines and belongs to the technical field of tail gas catalysis purification of universal minitype petrol engines. The Pd-only catalyst only contains noble metal Pd and does not contain noble metal Pt or Rh with the cost far higher than that of Pd, so that the cost of tail gas purification catalyst for universal minitype petrol engines can be reduced; a metal carrier is pre-treated through roasting at the relatively low temperature of 400 to 700 DEG C, pseudo-boehmite binding agent is added in coating slurry, and a bonding layer not containing noble metal or oxygen storage material does not need to be applied in advance, but a catalysis coating containing noble metal is applied on the metal carrier directly, so that the preparation technology of the tail gas purification catalyst for universal minitype petrol engines can be simplified; and cerium-rich tombarthite oxygen storage material and alumina material with high specific surface area are added in the coating, so that the activity and the durability of the Pd-only catalyst for tail gas purification of universal minitype petrol engines can be improved, the consumption of Pd can be reduced, and a universal minitype petrol engine with the Pd-only catalyst provided by the invention can satisfy the requirements of emission regulations.

Description

technical field [0001] The invention relates to a single Pd catalyst for purifying tail gas of a general small gasoline engine and a preparation method thereof, and belongs to the technical field of catalytic purification of tail gas of a general small gasoline engine. Background technique [0002] The supporting equipment for general small gasoline engines can be used for water pumps, generator sets, mist powder sprayers, brush cutters, wind fire extinguishers, compactors, demolition tools, wool shears, ATVs, golf carts, sleds, outboard motors, Scooters, aircraft models, boat models, etc. are involved in many fields such as industry, agriculture, insurance management, entertainment, transportation, emergency rescue and disaster relief, garden machinery, etc. With the continuous growth of my country's economy, domestic demand is gradually increasing, but it is still Mainly export to the international market, among which the European and American markets account for more than h...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
18 Jul 2012
Publication
CN102580733A
IPC
B01J23/63; B01D53/94; B01D53/56; B01D53/72
Inventors
于鹏飞; 郭秀英