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Method for producing high-iron low-sulfur iron ore concentrate from pyrite cinder

A technology for pyrite slag and iron concentrate, which is applied in the field of pyrite roasting for acid production and slag selection of iron concentrate, can solve the problems of high production cost, long process route and high energy consumption, and achieves reduction of pollutants. production, shorten the process flow, and increase the effect of processing equipment

Inactive Publication Date: 2012-07-25
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Therefore, the black type slag is easy to improve the iron grade but has high sulfur content; the red type slag can obtain iron concentrate with relatively low sulfur content, but it is not easy to improve the iron grade, and the magnetization roasting-grinding treatment method is adopted, and the process route Long-term, large investment, and high-temperature roasting process, resulting in high energy consumption and high production costs, and the roasting process using coal as fuel and reducing agent produces a large amount of CO x , NO x , SO x 、H 2 Harmful gases such as S cause secondary pollution, making it uncompetitive in terms of economic and environmental benefits.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: Using pyrite with a sulfur content of 34.5%, roasting at a temperature of 900°C and an excess air coefficient of 1.20 to obtain a slag with a sulfur content of 0.42%, which is discharged into the cooler at the same time Straw charcoal accounting for 3.5% of the weight of the slag and an average particle size of 1.1mm is added. The fixed carbon content of the straw charcoal is 70.20%, the volatile matter is 18.55%, and the ash content is 11.25%. The pyrite slag is magnetized and roasted in a cooler and then cooled, ground to -0.045mm accounting for 90.15%, and then magnetically separated under a magnetic field strength of 1240GS, the iron grade is 64.35% and the S content is 0.15% , Iron concentrate with iron recovery rate of 83.66%.

Embodiment 2

[0026] Example 2: Using pyrite with a sulfur content of 36.7%, roasting at a temperature of 925°C and an excess air coefficient of 1.25 to obtain a slag with a sulfur content of 0.35%, which is discharged into the cooler at the same time Hawthorn stone charcoal with a weight of 3.2% by weight of the slag and an average particle size of 0.9mm is added. The fixed carbon content of the stone charcoal is 75.11%, the volatile matter is 14.28%, and the ash content is 10.61%. The pyrite slag is magnetized and roasted in a cooler and then cooled, ground to -0.045mm accounting for 91.62%, and then magnetically separated under a magnetic field strength of 1240GS. The iron grade is 64.71% and the S content is 0.10%. , Iron concentrate with an iron recovery rate of 82.57%.

[0027] Compared with the conventional method, using low roasting temperature and low air excess coefficient to obtain Fe 3 O 4 The main black type slag is then ground and magnetically separated. The iron concentrate obta...

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Abstract

The invention relates to a method for producing high-iron low-sulfur iron ore concentrate from pyrite cinder, comprising the steps of controlling a calcination temperature of pyrite to be 900-950 DEG C and an excess air ratio to be 1.15-1.25 to produce red low-sulfur cinder with Fe2O3 as a principal component in a furnace in fluid bed; then adding 2-6% of biomass with an average particle size of 0.5-2mm containing 70-90% of fixed carbon, 5-25% of volatile matter and 5-20% of ash content in the cinder for magnetizing roasting by the own temperature of the cinder so as to reduce hematite in the cinder into magnetite; and finally implementing processes of ore grinding and magnetic separation to obtain the high-iron low-sulfur iron ore concentrate with an iron grade of more than 63%, the sulfur content of lower than 0.2%, and the iron recovery rate of higher than 80%.

Description

Technical field [0001] The invention belongs to the technical field of pyrite roasting acid production and slag selection iron concentrate technology, and relates to a method for producing high-iron and low-sulfur iron concentrate by using pyrite slag. Background technique [0002] Pyrite slag is a by-product of the process of pyrite sulphuric acid production. The annual discharge of pyrite slag in my country has exceeded 12 million tons. Pyrite slag is a valuable secondary resource, but the utilization rate of pyrite slag in my country is low. In my country, most of the pyrite slag is piled up or discarded, except partly used as raw materials for ironmaking and cement clinker additives. Abandoned pyrite slag will cause a waste of resources and occupy a large amount of land, and its harmful components are extremely harmful to the environment. [0003] Because the pyrite slag is rich in iron and has a fine average particle size, it is an ideal way to use the slag as a raw material...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/02
Inventor 范晓慧甘敏陈许玲姜涛李光辉郭宇峰杨永斌白国华张元波李骞袁礼顺朱忠平许斌邓琼
Owner CENT SOUTH UNIV
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