Regeneration polyethylene resin combination for sheath production and preparation method thereof

A technology for regenerating polyethylene and resin composition, applied in the field of recycled polyethylene resin composition and its preparation, can solve problems such as environmental pollution, waste of social wealth, unfavorable development of national economy, etc., and achieve the effect of excellent physical and mechanical properties

Inactive Publication Date: 2012-08-22
QINGZHOU LUCHUANG RENEWABLE RESOURCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A large number of waste plastics that cannot be degraded naturally not only cause serious environmental pollution, but also are not conducive to the development of the national economy
At the same time, plastics are prepared by synthesis of natural resources such as oil, natural gas, and coal. In the case of increasingly scarce natural resources, especially when my country's per capita oil resources are scarce, the abandonment of a large number of waste plastics has undoubtedly caused Great waste of social wealth

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1—5

[0025] Embodiment 1-5 is all prepared according to the following preparation method:

[0026] (1) Put recycled polyethylene water pipe material, polyethylene bottle cap recycled material, LLDPE film recycled material, ethylene-vinyl acetate copolymer, antioxidant, carbon black masterbatch and processing aid into a high-speed mixer and mix them, The stirring speed is 1000-2000 rpm, the stirring time is 10-15min, and the stirring temperature is 30-50°C;

[0027] (2) Put the uniformly mixed material into the twin-screw extruder for melting, plasticizing, extruding and granulating.

[0028] In the above examples, the preferred stirring speed is 1300 rpm, the stirring time is 11 min, and the stirring temperature is 38°C.

[0029] Wherein, the length-to-diameter ratio of the screw in the twin-screw extruder affects the plasticizing performance and conveying performance of the material, so the screw length-to-diameter ratio of the twin-screw extruder is 30-40, more preferably 33-37....

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Abstract

The invention discloses a regeneration polyethylene resin combination for sheath production and a preparation method thereof. The regeneration polyethylene resin combination for sheath production is prepared by the following raw materials, by weight: 70-80 parts of polyethylene pipe reworked materials, 8-10 parts of polyethylene bottle cover reworked materials, 10-15 parts of linear low density polyethylene (LLDPE) film reworked materials, 2-5 parts of ethylene-vinyl acetate ester copolymers, 0.2-0.4 parts of antioxidants, 5-7 parts of carbon black master batches and 0.01-0.03 parts of processing agents. The raw materials are put into a high-speed mixer to perform stirring and mixing, and evenly-mixed materials are fed into a double-screw extruder to perform melting, plasticization, extrusion and pelleting. The combination has excellent physical and mechanical properties, environmental stress crack resistance (ESCR), thermal aging resistance and processability, wherein the ESCR (10%, F0) is larger than or equal to 500 hours, thermal aging elongation at break at the temperature of 110 DEG C for 1500 hours is larger than or equal to 650%, tensile strength is larger than or equal to 28MPa, and the processing traction speed is larger than or equal to 30m / min.

Description

technical field [0001] The invention belongs to the technical field of chemical synthesis of polymer materials, and in particular relates to a recycled polyethylene resin composition used in sheath production and a preparation method thereof. Background technique [0002] my country is a country with a large demand for crude oil. According to statistics, in 2011, the national crude oil processing volume reached 448 million tons, and the import volume was 253.78 million tons, a year-on-year increase of 6%, and the foreign dependence reached 56.5%. At present, the annual production of waste plastics in China is about 10 million tons, plus the annual import of nearly 5 million tons, the overall possession is about 15 million tons per year. A large number of waste plastics that cannot be naturally degraded not only cause serious environmental pollution, but are also not conducive to the development of the national economy. At the same time, plastics are prepared by synthesis of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08K3/04C08K5/134C08K5/526C08J3/22
Inventor 侯安奎侯方银
Owner QINGZHOU LUCHUANG RENEWABLE RESOURCE
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