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Method for improving water and moisture absorbing performance of acrylic fiber by using gamma-polyglutamic acid hydrogel

A technology of polyglutamic acid and hydrogel, applied in textiles and papermaking, fiber type, fiber treatment, etc., can solve the problems of static electricity, fire, low hygroscopicity, etc., and achieve the effect of improving water absorption and hygroscopicity

Inactive Publication Date: 2012-09-19
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although acrylic fiber has excellent performance, it still has serious disadvantages in wearing performance, mainly manifested in low hygroscopicity and serious static electricity.
These shortcomings not only seriously affect the wearing comfort of acrylic fabrics, but also affect the production safety of enterprises. The static electricity generated by acrylic fabrics may ignite flammable and explosive products and cause fires.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Embodiment 1: The concentration of γ-polyglutamic acid is 8%, and the consumption of ethylene glycol diglycidyl ether is 40% of the quality of γ-polyglutamic acid, and the acrylic fabric is soaked in the finishing liquid for 10min, and the temperature is 25° C. Dip two rolls, the excess rate is 65%, wrap it with a plastic wrap and react at a constant temperature of 50°C for 5h. Remove the plastic wrap and dry it; the water absorption of 1 gram of fabric is 15.3g, and the standard moisture regain is 4.0%.

Embodiment 2

[0013] Embodiment 2: the concentration of γ-polyglutamic acid is 10%, and the consumption of ethylene glycol diglycidyl ether is 20% of the quality of γ-polyglutamic acid, and the acrylic fabric is soaked in the finishing solution for 5min, and the temperature is 20° C. Dip two rolls, the excess rate is 75%, wrap it with a plastic wrap and react at a constant temperature of 50°C for 10h. Then remove the preservative film and dry it; the water absorption of 1 gram of fabric is 11.6g, and the standard moisture regain is 4.1%.

Embodiment 3

[0014] Embodiment 3: the concentration of γ-polyglutamic acid is 15%, and the consumption of ethylene glycol diglycidyl ether is 60% of the quality of γ-polyglutamic acid, and the acrylic fabric is soaked in the finishing solution for 8min, and the temperature is 26° C. Soak twice and roll, the excess rate is 85%, wrap with plastic wrap and react at a constant temperature of 60°C for 15h. Then remove the preservative film and dry it; the water absorption of 1 gram of fabric is 13.6g, and the standard moisture regain is 4.7%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a method for improving water and moisture absorbing performance of acrylic fiber by using gamma-polyglutamic acid hydrogel. The method is used for settling fabric by using gamma-polyglutamic acid as a finishing agent and ethylene glycol diglycidyl ether as a cross-linking agent. The method includes the steps of dissolving the gamma-polyglutamic acid in distilled water or tap water, preparing a 4%-20% solution, adding ethylene glycol diglycidyl ether according to 20%-60% of the mass of the gamma-polyglutamic acid, and stirring evenly so as to mix evenly. Acrylic fiber is soaked in a fishing liquid for 5-10 minutes, soaked and rolled twice by using a padder, rolling surplus rate of the fabric is 65-110%, the soaked and rolled fabric is wrapped by a preservative film and reacts for 5h-25h in an oven at the temperature of 40-80 DEG C, then the preservative film is removed, and the fabric is dried. Or the soaked and rolled fabric is baked for 5-10 minutes in a baking machine at the temperature of 110-140 DEG C. Standard moisture regain and moisture absorbing amount of the settled acrylic fiber are greatly increased, and wearing comfortableness is remarkably improved.

Description

Technical field: [0001] The invention relates to a method for finishing acrylic fiber fabrics for water absorption and hygroscopicity, in particular to a method for finishing acrylic fiber fabrics with biomacromolecule material gamma-polyglutamic acid hydrogel to improve water and hygroscopicity. technical background: [0002] Acrylic fiber is a synthetic fiber made of a copolymer of more than 85% acrylonitrile and the second and third monomers through wet spinning or dry spinning. The fibers obtained by spinning copolymers with acrylonitrile content between 35% and 85% are called modified polyacrylonitrile fibers. [0003] The performance of polyacrylonitrile fiber is very similar to that of wool. It has good elasticity. When it is stretched by 20%, the rebound rate can still maintain 65%. 1 to 2.5 times higher. Excellent light fastness, one year of exposure in the open air, the strength will only decrease by 20%, the fiber softening temperature is 190-230 ℃, it can resis...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M15/59D06M13/11D06M101/28
Inventor 李政张健飞严建军乔长晟巩继贤李秋瑾李辉芹
Owner TIANJIN POLYTECHNIC UNIV
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