Additive capable of reducing methanol gasoline saturated vapor pressure

A technology of methanol gasoline and additives, which is applied in the direction of fuel additives, petroleum industry, liquid carbon-containing fuels, etc., and can solve the problem of less consideration of the impact of additives on the physical and chemical properties and service performance of gasoline, affecting the physical and chemical properties of products and storage stability, Investment and construction costs high device operating costs to achieve the effect of low cost, prevent air resistance, and use less materials

Inactive Publication Date: 2013-01-16
RES INST OF SHAANXI YANCHANG PETROLEUM GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The invention patent 101948396A published on January 19, 2011 discloses a polyetheramine and its production method and its application in methanol gasoline. The polyetheramine is generally used as a curing agent raw material, which has excessive volatility, toxicity and Disadvantages such as high corrosiveness
The equipment investment and construction cost of this method is high
[0012] Invention patent 101285010B announced on April 27, 2011 discloses "a multifunctional alcohol fuel additive", wherein the vapor pressure inhibitor is ethyl formate and / or ethyl acetoacetate, wherein the price of ethyl acetoacetate is expensive, The density and viscosity are too high, the boiling point is as high as 180.8 ° C, and it will also form a purple complex with iron (III). These factors will affect other physical and chemical properties and storage stability of the product.
In the prior art, the method of increasing equipment for reaction has the defects of high investment and construction costs and device operating costs, and although the method of adding one or more chemical substances can reduce the saturated vapor pressure of methanol gasoline to a certain extent, it is not effective for Less consideration is given to the impact of added substances on the physical and chemical properties and performance of gasoline

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] An additive for reducing the saturated vapor pressure of methanol gasoline, the additive is 100% fatty alcohol; the fatty alcohol is composed of n-butanol and n-octanol, wherein n-butanol accounts for 50% and n-octanol accounts for 50%. The above-mentioned percentages are volume percentages, and the following examples are the same.

[0036] The preparation method of this embodiment is as follows: mix the raw materials uniformly in proportion.

[0037] Compared with other methanol-gasoline saturated vapor pressure regulators, the additive in this example has the advantages of simple formula, easy purchase of raw materials, low cost, less addition amount, good effect, etc., and is suitable for industrial production. Adding 3% of the additive of this embodiment to methanol gasoline can reduce the vapor pressure of methanol gasoline by 4.5 units, and the distillation temperature of 50% of the distillation range rises by 8.5°C, which effectively corrects the excessive vapor ...

Embodiment 2

[0039] This example is the same as Example 1, except that the fatty alcohol is n-pentanol and n-hexanol. The preparation method of this example is the same as that of Example 1.

[0040] Compared with other methanol-gasoline saturated vapor pressure regulators, the additive in this example has the advantages of simple formula, easy purchase of raw materials, low cost, less addition amount, good effect, etc., and is suitable for industrial production. Adding 3% of the additive of this embodiment to methanol gasoline can reduce the vapor pressure of methanol gasoline by 4.5 units, and the distillation temperature of 50% of the distillation range rises by 8.5°C, which effectively corrects the excessive vapor pressure caused by the addition of methanol. The phenomenon that the temperature of the 50% distillation range is greatly reduced, thereby reducing the volatile loss caused by the excessive volatility of methanol gasoline, and reducing the tendency of air resistance during use...

Embodiment 3

[0042] An additive for reducing the saturated vapor pressure of methanol gasoline, which is prepared by mixing the following raw materials in volume percentage: 55% of fatty alcohol, 22% of ethers, and 23% of esters; the fatty alcohol is n-butanol, and the ether The class is diisopropyl ether and the ester is dimethyl carbonate.

[0043] The preparation method of this embodiment is as follows: mix the raw materials uniformly in proportion.

[0044] Compared with other methanol-gasoline saturated vapor pressure regulators, the additive in this example has the advantages of simple formula, easy purchase of raw materials, low cost, less addition amount, good effect, etc., and is suitable for industrial production. Adding 7% of the additive of this embodiment to methanol gasoline can reduce the vapor pressure of methanol gasoline by 8.5 units, and the distillation temperature of 50% distillation range rises by 10°C, which effectively corrects the excessive vapor pressure caused by...

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PUM

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Abstract

The invention relates to an additive capable of reducing methanol gasoline saturated vapor pressure. The additive is characterized in that the additive is prepared by mixing raw materials of, by volume, 50%-100% of fatty alcohol, 0%-38% of ethers and 0%-29% of esters. The saturated vapor pressure of the additive can be reduced by 4-9 units, and distillation range data, especially the distillation volume number at the temperature of 70 DEG C, are closer to those of car gasoline, so that air resistance is effectively prevented, volatilization loss is reduced, and production and usage requirements of methanol gasoline are satisfied.

Description

technical field [0001] The invention relates to an additive for reducing the saturated vapor pressure of methanol gasoline. Background technique [0002] As a new type of clean alternative fuel, methanol gasoline has become the development direction of automobile alternative fuel due to its high octane number, good combustibility, high efficiency and cleanliness. [0003] The saturated vapor pressure of methanol is 32kPa, and the saturated vapor pressure of gasoline is 50-75kPa. When methanol is mixed into gasoline, the saturated vapor pressure of methanol gasoline obtained is obviously higher than that of gasoline. This is mainly because certain hydrocarbons in methanol and gasoline form a low-boiling azeotrope, which increases the volatility of the fuel, increases the vapor pressure, increases the volatilization loss during the production process, and tends to cause air lock when used in summer. , causing the engine to stall. The occurrence of air lock phenomenon serious...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/182C10L1/185C10L1/19C10L10/00
Inventor 王香增张娟利高瑞民张书勤杨天华黄勇张新庄
Owner RES INST OF SHAANXI YANCHANG PETROLEUM GRP
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