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Flocculant for removing synedra from water and removing method

A needle algae and flocculant technology, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of algal cell rupture, influence of water environment, increase of potassium permanganate dosage, etc., to achieve high removal efficiency and operation. Simple, low-cost effects

Inactive Publication Date: 2013-02-13
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, the potassium permanganate pre-oxidation method, such as the patent "Potassium permanganate pre-oxidation method and air flotation combined with algae removal water treatment method" with the publication number CN102295363A, has certain inactivation and inhibition of algae cell activity. function, but there are shortcomings such as weak ability to oxidize and destroy algae cell walls, excessive potassium permanganate dosage will increase water color, and produce electronegative manganese dioxide by-products; chlorine pre-oxidation method, and the publication number is CN101723529A's patent "a method of adding chlorine to remove algae and odor in water treatment process" has high algae removal efficiency, especially the effect of removing the water odor produced by algae is better, but because of the addition of chlorine-containing chemicals, disinfection by-products such as Trichloromethane, halogenated hydrocarbons and other substances harmful to humans should also be used with caution; hydrogen peroxide is highly oxidizing and can cause algae cell rupture, causing the release of toxic intracellular substances, which have an impact on the water environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The first step is to use the source water of Jialing River containing needle algae as a research model during the period of the outbreak of needle algae in the Jialing River. Wastewater Monitoring and Analysis Methods "Editorial Board. Water and Wastewater Monitoring and Analysis Methods [M]. 4th Edition (Supplemented Edition). Beijing: China Environmental Science Press, 2002: 701 - 705.) Detection of the enrichment of needle-shaped algae The concentration is 1.8 million / L;

[0023] In the second step, take 1L of the concentrated Jialing River source water (containing 1.8 million needles / L) and add alum (KAl(SO 4 ) 2 · 12H 2 O) and cationic polymer polydiallyldimethylammonium chloride (FL45C) to make alum (KAl(SO 4 ) 2 · 12H 2 O) at a concentration of 32 mg / L and the cationic polymer polydiallyldimethylammonium chloride (FL45C) at a concentration of 2.8 mg / L;

[0024] In the third step, the above water sample was stirred for 3 minutes at a speed of 1000 rpm, the...

Embodiment 2

[0027] The first step is to use the source water of Jialing River containing needle algae as a research model during the outbreak of needle algae in the Jialing River, concentrate the needle algae in the source water of the Jialing River by 10 times, and detect the concentration of needle algae enrichment by algae counting method 1.8 million / L;

[0028] In the second step, take 1L of the above-mentioned concentrated source water (containing 1.8 million needles / L) and add alum (KAl(SO 4 ) 2 · 12H 2 O) and cationic polymer polydiallyldimethylammonium chloride (FL45C), so that the concentration of alum is 32 mg / L, and the concentration of cationic polymer polydiallyldimethylammonium chloride 3.3 mg / L;

[0029] In the third step, the above water sample was stirred for 3 minutes at a speed of 1000 rpm, then stirred for 17 minutes at a speed of 500 rpm, and flocculated for 20 minutes;

[0030] In the fourth step, the supernatant was taken, and the concentration of needle algae ...

Embodiment 3

[0032] The first step is to use the source water of Jialing River containing needle algae as a research model during the outbreak of needle algae in the Jialing River, concentrate the needle algae in the source water of the Jialing River by 10 times, and detect the concentration of needle algae enrichment by algae counting method 1.8 million / L;

[0033] In the second step, take 1L of the concentrated Jialing River source water (containing 1.8 million needles / L) and add alum (KAl(SO 4 ) 2 · 12H 2 O) at a concentration of 40 mg / L and cationic polymer polydiallyldimethylammonium chloride (FL45C) at a concentration of 3.3 mg / L;

[0034] In the third step, stir the above water sample at a speed of 1000 rpm for 5 minutes, then stir at a speed of 500 rpm for 15 minutes, and flocculate and settle for 25 minutes;

[0035] In the fourth step, the supernatant was taken, and the concentration of needle algae was detected to be 111,600 / L by the algae counting method, and the removal ra...

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Abstract

The invention provides a flocculant for removing synedra from water. The flocculant is formed by matching alum and diallyldimethylammonium chloride, wherein the diallyldimethylammonium chloride belongs to a cationic polymer, and the best weight ratio of the alum to the diallyldimethylammonium chloride is 9 to 12:1. The invention further provides a method for removing the synedra from the water. The method comprises the following steps: removing the synedra from the water by utilizing the flocculant, wherein the concentration of the alum in the water is controlled to be 32 to 48mg / L, and the concentration of the diallyldimethylammonium chloride in the water is controlled to be 2.7 to 4.0mg / L; and then carrying out mixing, flocculation, sedimentation and filtration, thereby removing the synedra. The method has the advantages that the operation is simple, i.e. the only requirement is to proportion the flocculant accurately and then put the flocculant in a distribution well of a water plant; and all the used reagents and operation processes cannot generate secondary pollution and have no harm on environment and human bodies, so that the method is green, clean and environment-friendly. In addition, the removing efficiency of the synedra in the water is high and reaches 90% to 94%.

Description

technical field [0001] The invention belongs to the technical field of water environment protection, and in particular relates to a method for removing needle algae in water supply. [0002] Background technique [0003] Algae outbreaks caused by eutrophication in drinking water sources directly pose a threat to water supply security. Algae blooms have the following major hazards to water supply safety: 1. Algae block the filter, making the filtration of water supply impossible; 2. Make the filter harden and deteriorate, increasing the cost of water supply; 3. Release microcystin and other toxins; 4. Decrease the sense of water body (such as increase of chroma and turbidity of water body, emitting fishy smell, etc.). In May 2007, algal blooms in Taihu Lake affected the normal supply of drinking water for 2 million people. Effectively removing the pollution of various algae in the water body is a difficult problem in the water supply industry at present. [0004] At prese...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/56
Inventor 刘力维郑怀礼肖浪马江雅袁秋红谢婉莹陈丽竹
Owner CHONGQING UNIV
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