Acrylic copolymer and optical film comprising the same
A kind of copolymer and acrylic technology, which is applied in the field of optical film, can solve the problems of high price and complicated process, and achieve the effect of excellent compatibility, excellent heat resistance and maintaining transparency
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Embodiment 1
[0072] An acrylic copolymer resin was prepared using 91 parts by weight of methyl methacrylate, 5 parts by weight of phenyl methacrylate and 4 parts by weight of phenylmaleimide monomer. The glass transition temperature and molecular weight of the obtained resin were measured, and as a result, a resin having a glass transition temperature of 125° C. and a weight average molecular weight of 110,000 was obtained. 90 parts by weight of the above resin and 10 parts by weight of polycarbonate were mixed to prepare a final resin composition. The above resin composition was formed into a film using a solution casting method, and then stretched at a glass transition temperature to measure the retardation value of the film. As a result, the in-plane retardation value / thickness retardation value were 30 / -80, respectively.
Embodiment 2
[0074] An acrylic copolymer resin was prepared using 86 parts by weight of methyl methacrylate, 10 parts by weight of phenyl methacrylate and 4 parts by weight of phenylmaleimide monomer. The glass transition temperature and molecular weight of the obtained resin were measured, and as a result, a resin having a glass transition temperature of 126° C. and a weight average molecular weight of 115,000 was obtained. 85 parts by weight of the above resin and 15 parts by weight of polycarbonate were mixed to prepare a final resin composition. The above resin composition was formed into a film using a solution casting method, and then stretched at a glass transition temperature to measure the retardation value of the film. As a result, the in-plane retardation value / thickness retardation value were 45 / -120, respectively.
Embodiment 3
[0076] An acrylic copolymer resin was prepared using 76 parts by weight of methyl methacrylate, 20 parts by weight of phenyl methacrylate and 4 parts by weight of phenylmaleimide monomer. The glass transition temperature and molecular weight of the obtained resin were measured, and as a result, a resin having a glass transition temperature of 128° C. and a weight average molecular weight of 115,000 was obtained. 80 parts by weight of the above resin were mixed with 20 parts by weight of polycarbonate to prepare a final mixed resin. The above mixed resin was formed into a film using a solution casting method, and then stretched at a glass transition temperature to measure the retardation value of the film. As a result, the in-plane retardation value / thickness retardation value were 60 / -280, respectively.
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