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Super-hydrophobic porous aluminum alloy material and preparation method thereof

An aluminum alloy material and super-hydrophobic technology, applied in the coating process of metal materials, etc., can solve the problems of poor hydrophobic performance, high cost, complex manufacturing process equipment, etc., achieve good hydrophobicity, low cost, and good industrial application prospects Effect

Inactive Publication Date: 2013-06-26
重庆南涪铝业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to provide a super-hydrophobic porous aluminum alloy material and its preparation method to solve the above problems in view of the current problems of poor hydrophobic performance, complex manufacturing process equipment and high cost of super-hydrophobic porous aluminum alloy materials.

Method used

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  • Super-hydrophobic porous aluminum alloy material and preparation method thereof
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Firstly, the aluminum alloy plate is mechanically polished and polished to remove surface defects and oxide film, and cleaned with ethanol and deionized water for 15 minutes respectively. Soak the plate with 2mol / L hydrochloric acid solution for 15 minutes, wash it with deionized water, and dry it; mix 0.1mol / L copper nitrate and 4g / L sodium chloride and stir fully to make a bath; immerse the aluminum alloy plate in 30℃ ~40°C bath for 80 minutes, then fully washed with deionized water, and dried in an oven at 80-100°C. The superhydrophobic surface of the aluminum alloy can be prepared by immersing in stearic acid ethanol solution with a mass fraction of 1% for 30 minutes, drying at room temperature and atmospheric environment for 24 hours at a relative humidity of 60-75%. Test the wettability of this coating surface with OCA20 contact angle tester, the result shows that this surface and the contact angle of water are respectively 160 ± 2 ° and 154 ± 2 °, as figure 1 Sh...

Embodiment 2

[0024] First, the pure aluminum plate material is mechanically polished and polished to remove surface defects and oxide films, and then cleaned with ethanol and deionized water for 5 minutes respectively. Soak the plate with 0.5mol / L hydrochloric acid solution for 25 minutes, wash it with deionized water, and dry it; mix 0.015mol / L copper nitrate and 0.8g / L sodium chloride and stir fully to make a bath; immerse the aluminum plate material in 30 ℃~40℃ bath solution for 150 minutes, then fully washed with deionized water, and dried in an oven at 80-100℃. The superhydrophobic surface of the aluminum alloy can be prepared by immersing in stearic acid ethanol solution with a mass fraction of 0.2% for 50 minutes, drying at room temperature and atmospheric environment for 45 hours at a relative humidity of 60-75%. The wettability of the coating surface was tested with an OCA20 contact angle tester, and the results showed that the contact angles of the surface and water were 162±2° a...

Embodiment 3

[0026] First of all, the aluminum alloy plate is mechanically polished and polished to remove surface defects and oxide film, and cleaned with ethanol and deionized water for 35 minutes respectively. Soak the plate with 3mol / L hydrochloric acid solution for 5 minutes, wash it with deionized water, and dry it; mix 0.2mol / L copper nitrate and 5g / L sodium chloride and stir well to make a bath; immerse the aluminum alloy plate in 30℃ ~40°C bath for 30 minutes, then fully washed with deionized water, and dried in an oven at 80-100°C. The superhydrophobic surface of the aluminum alloy can be prepared by immersing in stearic acid ethanol solution with a mass fraction of 3% for 10 minutes, drying at room temperature and atmospheric environment for 24 hours at a relative humidity of 60-75%. The wettability of the coating surface was tested with an OCA20 contact angle tester, and the results showed that the contact angles of the surface and water were 161±2° and 154±2°, respectively.

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Abstract

The invention relates to the technical field of metal material treatment, and particularly provides a super-hydrophobic porous aluminum alloy material and a preparation method thereof. The super-hydrophobic porous aluminum alloy material provided by the invention is dark red in color, the contact angle between the surface and water is 150-166 degrees, and the rolling angle of water drops on the surface is less than 10 degrees, thereby achieving favorable hydrophobicity. According to the preparation method of the super-hydrophobic porous aluminum alloy material, the preparation method has the advantages of simple operating process and favorable reproducibility; no expensive equipment or complicated chemical treatment processes are needed; improvement can be made on the basis of the traditional process; and the cost is low. Thus, the invention has good industrial application prospects.

Description

technical field [0001] The invention relates to the technical field of metal material processing, in particular to a superhydrophobic porous aluminum alloy material and a preparation method thereof. Background technique [0002] In recent years, superhydrophobic surfaces (material surfaces with water contact angles greater than 150° and water droplets have small rolling angles on surfaces) have attracted extensive research interest. Since the contact area of ​​the liquid on the super-hydrophobic surface is very small, it can effectively inhibit surface oxidation, corrosion, frost, current conduction, etc. Therefore, superhydrophobic surfaces have broad application prospects in outdoor antennas, exterior wall coatings, ships, biomedical devices, microfluidics, and automotive windshields. Aluminum alloy is the most widely used non-ferrous metal structural material in the industry, and is widely used in aerospace, automobile, machinery manufacturing, shipbuilding and chemical ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/08C22C21/00C23C22/56C23C22/82
Inventor 陈洪吴若梅彭学军
Owner 重庆南涪铝业有限公司