Low-temperature impact-resistant and low stress whitening-resistant long glass fiber reinforced polypropylene material, and preparation method and application thereof

A polypropylene material, low stress technology, applied in the field of reinforced modified polypropylene materials, can solve the problems of filling materials not meeting the requirements, affecting the appearance of parts, and only focusing on materials, so as to improve the drop strength and stress whitening resistance , good drop resistance, and the effect of reducing stress whitening

Active Publication Date: 2013-08-14
CHENGDU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The defect of the above prior art is that it only pays attention to the stability and improvement of the initial mechanical properties of the material, and does not involve the low temperature characteristics of the material, and the general parts also have strength requirements in the low temperature process, such as home appliance parts, electric tools and packaging products. Under low temperature conditions, there are r

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  • Low-temperature impact-resistant and low stress whitening-resistant long glass fiber reinforced polypropylene material, and preparation method and application thereof
  • Low-temperature impact-resistant and low stress whitening-resistant long glass fiber reinforced polypropylene material, and preparation method and application thereof
  • Low-temperature impact-resistant and low stress whitening-resistant long glass fiber reinforced polypropylene material, and preparation method and application thereof

Examples

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[0038] Example 1:

[0039] The low-temperature impact resistance, low-stress whitening long glass fiber reinforced polypropylene material in this embodiment is composed of 60% long glass fiber reinforced polypropylene masterbatch in weight percentage, and high-temperature impact resistance, low-stress whitening mother batch 40% of the granules, of which the components in the long glass fiber reinforced polypropylene masterbatch are composed of the following components, and the specific proportions are shown in Table 1 by weight percentage: copolymer polypropylene, glass fiber, maleic acid grafted polypropylene, Antioxidant, processing aid stearic acid; the components in the low-temperature impact resistance, low-stress whitening masterbatch are composed of the following components, and the specific proportions are shown in Table 2: Copolypropylene, grafted elastomer POE, antioxidant, processing aid erucamide; long glass fiber reinforced polypropylene masterbatch and low-temperatu...

Example Embodiment

[0044] Example 2

[0045] The low-temperature impact-resistant, low-stress whitening long glass fiber reinforced polypropylene material in this embodiment is composed of 60% long glass fiber reinforced polypropylene masterbatch by weight, and 40 %, the components in the long glass fiber reinforced polypropylene masterbatch are composed of the following components, and the specific proportions are shown in Table 1 by weight percentage: copolymerized polypropylene, glass fiber, acrylic grafted polypropylene, antioxidant, processing Additive butyl stearate; the components in the low-temperature impact resistance, low-stress blushing masterbatch are composed of the following components, and the specific proportions are shown in Table 2: copolymer polypropylene, grafted EPDM elastomer, bromine Chemical epoxy resin, antioxidant, processing aid ethylene bis-stearamide; long glass fiber reinforced polypropylene masterbatch and low-temperature impact resistance, low-stress blushing master...

Example Embodiment

[0047] Example 3

[0048] The low-temperature impact-resistant, low-stress whitening long glass fiber reinforced polypropylene material in this embodiment is composed of 60% long glass fiber reinforced polypropylene masterbatch by weight, and 40 %, the components in the long glass fiber reinforced polypropylene masterbatch are composed of the following components, and the specific proportions are shown in Table 1 by weight percentage: copolymerized polypropylene, glass fiber, acrylic grafted polypropylene, antioxidant, processing Additive butyl stearate; the components in the low-temperature impact resistance, low-stress whitening masterbatch are composed of the following components, and the specific proportions are shown in Table 2: Copolypropylene, grafted POE elastomer, bromine Polystyrene, antioxidant, processing aid ethylene bis-stearamide; long glass fiber reinforced polypropylene masterbatch and low-temperature impact resistance, low-stress whitening masterbatch are all 12...

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Abstract

The invention discloses a low-temperature impact-resistant and low stress whitening-resistant long glass fiber reinforced polypropylene material, comprising, by weight, 10%-80% of long glass fiber reinforced polypropylene masterbatches and 20% -90% of low-temperature impact-resistant and low stress whitening-resistant masterbatches, wherein the long glass fiber reinforced polypropylene masterbatches comprise, by weight, 0%-80% of co-polypropylene, 0%-80% of homo-polypropylene, 10%-60% of glass fibers, 1%-10% of grafted polypropylene, 0.1%-2% of an antioxidant and 0.2-2% of a processing agent; the low-temperature impact-resistant and low stress whitening-resistant masterbatches comprise, by weight, 50%-95% of co-polypropylene, 0-30% of a grafted elastomer, 0-20% of a brominated flame retardant, 0.1%-2% of an antioxidant and 0.2-5% of a processing agent. The polypropylene material prepared by the method improves the characteristic of low-temperature impact resistance and reduce generation of stress whitening. A finished product prepared by the material has good drop impact resistance, and can be used for workpieces such as packing cases or electric tools, etc.

Description

technical field [0001] The invention relates to a reinforced modified polypropylene material, in particular to a low-temperature impact-resistant, low-stress whitening long glass fiber reinforced polypropylene material and a preparation method and application thereof. Background technique [0002] Polypropylene resin (PP) is a general-purpose plastic with a wide range of uses. It is obtained by polymerization of propylene monomer. The advantages of polypropylene resin are low density, low price, excellent chemical corrosion resistance, good mechanical properties, Good formability. As a typical crystalline material, its melting point is around 165°C. After adding glass fiber to strengthen it, its mechanical properties will be greatly improved, and it can be used as structural parts in household appliances, automotive materials or tool industries. [0003] In practical applications, long glass fiber reinforced polypropylene materials can replace steel and reinforced engineeri...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/14C08L51/06C08K7/14C08J3/22
Inventor 刘乐文李聪肖鹏陶四平杨泽姜向新叶南飚
Owner CHENGDU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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