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Retardation film, polarizing plate, and display panel device

A technology of retardation film and polarizer, which can be used in polarizing elements, instruments, optical elements, etc., and can solve problems such as improvement of brittleness and film cracking that have not been discussed.

Active Publication Date: 2013-08-14
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In terms of film processability, if the film strength is weak, there are problems of force when cutting the film into sheets, bending when bonding the films to each other or bonding the film to the panel, and reworking the film from the panel Under the action of bending, etc., there will be problems such as cracking on the film.
As one of the retardation films, for example, as shown in Patent Documents 1 and 2, a retardation film having a characteristic (also referred to as an inverse wavelength dispersion characteristic) in which the retardation value is larger as measured with longer-wavelength light has been developed, but The improvement of the brittleness of the membranes as described above is not addressed in these documents

Method used

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  • Retardation film, polarizing plate, and display panel device
  • Retardation film, polarizing plate, and display panel device
  • Retardation film, polarizing plate, and display panel device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0152] 8.8 g of polyvinyl alcohol-based resin [manufactured by Nippon Synthetic Chemicals Co., Ltd., trade name "NH-18" (polymerization degree = 1800, saponification degree = 99.0%)] was dried at 105 ° C for 2 hours, and then dissolved in 167.2 g of in dimethyl sulfoxide (DMSO). 2.98 g of 2-methoxy-1-naphthaldehyde and 0.80 g of p-toluenesulfonic acid monohydrate were added thereto, and stirred at 40° C. for 1 hour. 3.18 g of benzaldehyde was added to the reaction solution, stirred at 40° C. for 1 hour, and then 4.57 g of dimethyl acetal was added, and stirred at 40° C. for 3 hours. Then, 2.13 g of triethylamine was added to terminate the reaction. The obtained crude product was reprecipitated with 1 L of methanol. The filtered polymer was dissolved in tetrahydrofuran, and reprecipitated with methanol again. This was filtered and dried to obtain 11.9 g of a white polymer. The polymer is used 1 As a result of H-NMR measurement, it had a repeating unit represented by the fo...

Embodiment 2

[0157] The thickness of the film before stretching was set at 150 μm instead of 135 μm, the stretching temperature was set at 133° C. instead of 135° C., and the stretching ratio was set at 2.2 times instead of 2.1 times. 1 Stretched film (retardation film) A-2 was produced in the same way. Table 1 shows the properties of the obtained retardation film A-2.

Embodiment 3

[0159] The thickness of the film before stretching was set at 130 μm instead of 135 μm, the stretching temperature was set at 130° C. instead of 135° C., and the stretching ratio was set at 2.8 times instead of 2.1 times. 1 Stretched film (retardation film) A-3 was produced in the same way. Table 1 shows the properties of the obtained retardation film A-3.

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PUM

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Abstract

A retardation film which comprises a stretched polymer film and satisfies the following formulae (1) to (3): 0.70<Re[450] / Re[550]<0.97(1); 1.5×10-3<Deltan<6×10-3(2); and 1.13<NZ<1.50(3), wherein: Re[450] and Re[550] represent in-plane retardation values of the retardation film as measured at 23° C. using light with a wavelength of 450 nm and light with a wavelength of 550 nm, respectively; Deltan represents an in-plane birefringence equal to (nx-ny) (where nx and ny represent refractive indexes in a slow axis direction and a fast axis direction of the retardation film, respectively); and NZ represents a ratio of a thickness-direction birefringence equal to (nx-nz) (where nz represents a refractive index in a thickness direction of the retardation film) to the in-plane birefringence equal to (nx-ny).

Description

technical field [0001] The present invention relates to a retardation film comprising a stretched polymer film. Background technique [0002] In recent years, along with the spread of displays, various functions required for optical films used therein are also increasing. Therefore, it is required to develop membranes manufactured with new materials and new processes. [0003] In addition to the performance of the film, it is necessary to mass-produce a wide and thin film in order to cope with the increase in the size and thickness of displays and the increase in production volume. When producing such a thin-layer film, the strength of the film becomes an important design parameter in terms of runnability, processability, and product reliability. [0004] In terms of running properties, since a long film is continuously produced for mass production, the film is generally conveyed by rollers while being brought into contact with various rollers. In this case, there is a pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/30C08J5/18G02F1/1335G02F1/13363
CPCG02B27/286G02B1/11G02B5/3025C08J5/18G02B5/3083H10K59/50H10K50/86
Inventor 村上奈穗清水享
Owner NITTO DENKO CORP
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