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Composite auxiliary agent for honeycomb ceramic forming

A technology of honeycomb ceramics and composite additives, which is applied in the direction of ceramic products, applications, household appliances, etc., and can solve the problems of increased drying shrinkage and firing shrinkage of the honeycomb ceramic body, high dosage of forming aids, and density and density of honeycomb ceramic products. Low strength and other problems, to achieve the effect of improving shape retention ability, reducing the thickness of hydration film, and reducing the deformation defect rate

Active Publication Date: 2014-09-24
朱冲
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the existing binders, plasticizers or lubricants for forming honeycomb ceramics that do not contain tung oil, there are generally two problems. One is that the amount of forming aids is relatively high, generally accounting for more than 6% of the total mass of honeycomb ceramic raw materials , some as high as 30%. Although the addition of a large amount of forming aids meets the requirements of the forming process of most honeycomb ceramic products, it increases the forming moisture of the honeycomb ceramic mud, resulting in the drying shrinkage and firing shrinkage of the honeycomb ceramic body. Increase, the probability of defects such as deformation and cracking increases during drying and firing, and because a large amount of molding aids decompose and escape during firing, especially when the decomposition products are incompletely burned at low temperatures, it will cause environmental pollution. The density and strength of honeycomb ceramic products after firing are also low; second, for some thin-walled and large-sized honeycomb ceramic products, problems such as deformation and cracking are prone to occur, and the product qualification rate is low

Method used

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  • Composite auxiliary agent for honeycomb ceramic forming

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A composite auxiliary agent for forming a honeycomb ceramic regenerator, the parts by weight of each component are:

[0042] 3 parts of polyvinyl alcohol;

[0043] 6 parts of sodium carboxymethylcellulose;

[0044] 8 parts of hydroxypropyl methylcellulose;

[0045] 4 parts of polyethylene glycol;

[0046] Sodium citrate 1.5 parts;

[0047] Sodium tripolyphosphate 2.5 parts.

[0048] The specific preparation and application method of the composite auxiliary agent for forming the honeycomb ceramics are as follows:

[0049] (1) Weigh the above powdered raw materials according to the proportion, and mix them fully and evenly in the mixer to prepare the compound additive.

[0050] (2) Dry-mix the composite auxiliary agent accounting for 5% of the total weight of the honeycomb ceramic raw material dry basis with the honeycomb ceramic raw material powder to obtain a compounding material.

[0051] (3) Add 14.5% water to the batch material, and fully knead in the mud mixer...

Embodiment 2

[0061] A composite auxiliary agent for forming a honeycomb ceramic regenerator, the parts by weight of each component are:

[0062] 3 parts of polyvinyl alcohol;

[0063] 3 parts of sodium carboxymethyl cellulose;

[0064] 6 parts of hydroxypropyl methylcellulose;

[0065] 2 parts of polyethylene glycol;

[0066] 1 part sodium citrate;

[0067] Sodium tripolyphosphate 1.6 parts.

[0068] The specific preparation and application method of the composite auxiliary agent for forming the honeycomb ceramics are as follows:

[0069] (1) Weigh the above powdered raw materials according to the proportion, and mix them fully and evenly in the mixer to prepare the compound additive.

[0070] (2) Dry-mix the composite auxiliary agent accounting for 3% of the total weight of the honeycomb ceramic raw material on a dry basis with the honeycomb ceramic raw material powder to obtain a compounding material.

[0071] (3) Add 12.5% ​​water to the batch material, and fully knead in the mud ...

Embodiment 3

[0079] A composite auxiliary agent for forming a honeycomb ceramic catalyst carrier for a chemical reaction tower, the parts by weight of each component are:

[0080] 2 parts polyvinyl alcohol;

[0081] 5 parts of sodium carboxymethyl cellulose;

[0082] 5 parts of hydroxypropyl methylcellulose;

[0083] 3 parts of polyethylene glycol;

[0084] 1 part sodium citrate;

[0085] Sodium tripolyphosphate 1.8 parts.

[0086] The specific preparation and application method of the composite auxiliary agent for forming the honeycomb ceramics are as follows:

[0087] (1) Weigh the above powdered raw materials according to the proportion, and mix them fully and evenly in the mixer to prepare the compound additive.

[0088] (2) Dry-mix the composite auxiliary agent accounting for 5% of the total weight of the honeycomb ceramic raw material dry basis with the honeycomb ceramic raw material powder to obtain a compounding material.

[0089] (3) Add 14% water to the batch material, and ...

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Abstract

A composite auxiliary agent for forming honeycomb ceramics, the parts by weight of each component are: 0.5-6 parts of polyvinyl alcohol; 1-10 parts of carboxymethyl cellulose sodium; 2-10 parts of hydroxypropyl methylcellulose; 1~10 parts of polyethylene glycol; 0.2~3 parts of sodium citrate; 0.5~5 parts of sodium tripolyphosphate. It can replace the molding aids that use tung oil or other oily esters as binders and lubricants widely used in the production of honeycomb ceramics, which can effectively solve the environmental pollution caused by the volatilization and decomposition of tung oil and other toxic and harmful gases during use. and damage to the operator's health. The amount of the composite additive is only 2%~5% of the total mass of the honeycomb ceramic raw material, which can be adjusted according to the size of the honeycomb ceramic product and the thickness of the honeycomb wall, and can meet the plastic extrusion molding process of various honeycomb ceramic products need. The composite additive is non-toxic and odorless in the production process, and does not produce harmful gases to the environment during the firing process.

Description

technical field [0001] The invention relates to material preparation technology, and further relates to a composite auxiliary agent for forming honeycomb ceramics. Background technique [0002] Honeycomb ceramics is a porous ceramic material with regular through-holes and thin-walled structures. It has been widely used in environmental protection and energy-saving fields such as automobile exhaust purification, high-efficiency heat storage in kilns, and chemical catalyst carriers. Because of its special pore structure, the mud is required to have high plasticity and high lubricity during extrusion. In order to make the mud pass through the mold smoothly and give it the ability to maintain a specific shape, lubricants, plasticizers and reinforcing agents need to be added to the mud. At present, tung oil is mainly used in the production of domestic honeycomb ceramics as a comprehensive additive for lubrication, plasticization and reinforcement, and its effect is better among ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/00C04B35/636
Inventor 朱冲朱根源肖汉宁
Owner 朱冲
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