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A cracking carbon five desulfurizer composition

A desulfurizer and composition technology, which is applied in the petroleum industry, refining with metal salts, and refining hydrocarbon oil, etc., can solve the problem of large amount of desulfurization reaction products, no secondary utilization value, and low C5 total sulfur removal rate. and other problems, to achieve the effect of obvious secondary utilization value, less production and lower desulfurization cost

Active Publication Date: 2016-02-17
NINGBO ZHONGYI PETROCHEM TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a cracking C5 desulfurizer composition to overcome the disadvantages of the current existing products, such as low removal rate of C5 total sulfur, high production cost, large amount of desulfurization reaction products, and no secondary utilization value

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Measure 40kg of diethylenetriamine, 35kg of monoethanolamine, 9.9kg of sodium hydroxide, 15kg of water, and 0.1kg of diethylhydroxylamine. According to the above preparation method and use method, after the cracked carbon five raw material containing disulfide and mercaptan 81.5ppm is treated with the desulfurizer composition, the product carbon five sulfur content is 9.2ppm.

Embodiment 2

[0018] Measure 35kg of diethylenetriamine, 55kg of diethanolamine, 9.7kg of diglycolamine, and 0.3kg of p-hydroxyanisole. According to the above preparation method and use method, after the cracked C5 raw material containing disulfide and mercaptan 130.2ppm is treated with the desulfurizer composition, the product C5S content is 13.3ppm.

Embodiment 3

[0020] Measure 45kg of diethylenetriamine, 34.95kg of N-methyldiethanolamine, 20kg of diglycolamine, and 0.05kg of hydroquinone. According to the above preparation method and use method, after the cracked carbon five raw material containing disulfide and mercaptan 130.2ppm is treated with the desulfurizer composition, the product carbon five sulfur content is 11.7ppm.

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Abstract

The invention relates to a cracking C5 desulfurization agent composition. The cracking C5 desulfurization agent composition comprises the following components in percentage by weight: 10-98% of first component, 0.1-85% of second component and 0.01-0.5% of third component. The cracking C5 desulfurization agent composition disclosed by the invention has the beneficial effects that on the premise of ensuring the quality of a product, by introducing the desulfurization agent composition, the total sulfur removal rate of the C5 can be greatly improved, the total sulfur content in the product and the desulfurization cost can be reduced, the output of desulfurization reaction products is little, and the desulfurization reaction products can be used as other chemical products, so that the cracking C5 desulfurization agent composition has secondary utilization values and obvious economic benefits and environment-friendly benefits.

Description

technical field [0001] The invention relates to the field of petrochemical technology, in particular to a cracking C5 desulfurizer composition. Background technique [0002] Cracking C5 (referred to as C5 fraction) can synthesize many high value-added products, which has become an important aspect of rational utilization of petroleum resources and reduction of ethylene production costs. However, the C5 raw material contains about 10-300ppm of sulfur-containing impurities, usually mercaptan, hydrogen sulfide, carbonyl sulfide, carbon disulfide, sulfide, disulfide and thiophene, etc. The sulfide will not only make the C5 fraction process Catalyst poisoning and equipment corrosion also have a negative impact on the quality and processing and application of C5 products. Especially in recent years, domestic refineries mainly process imported high-acid, high-sulfur and low-quality heavy crude oil, and the sulfur content in the cracked C5 fraction has a tendency to increase gradua...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G29/20C10G29/06
Inventor 祁永生王德志高秀聂通元蔡喜洋夏桂友郝勇高帅
Owner NINGBO ZHONGYI PETROCHEM TECH
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