A method for efficient treatment and reuse of chemical wastewater biochemical effluent
A technology for biochemical effluent and chemical wastewater, applied in the direction of oxidized water/sewage treatment, multi-stage water/sewage treatment, adsorption water/sewage treatment, etc. The effect of workload
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Embodiment 1
[0025] The water quality of biochemical effluent from a large chemical wastewater treatment plant is shown in Table 1. After adjusting the pH value to 5.5, ferrous sulfate and hydrogen peroxide were sequentially added to the water sample for Fenton oxidation to make Fe 2+ Concentration is 3mmol / L, H 2 o 2 The concentration is 5mmol / L, and the reaction time is 300 minutes. Fenton’s oxidized effluent reacts with amine-modified magnetic ultra-high cross-linked composite functional resins (resins in Examples 1-9, all of which are disclosed in patent documents with patent application number 201310106265.5) that account for 4% of the water volume , After reacting for 800 minutes, solid-liquid separation was carried out. The quality of the effluent after separation is shown in Table 1. The desorption solution containing 6wt.% sodium hydroxide and 80wt.% methanol is used for regeneration, and the regeneration time is 150 minutes. Regenerated resin continues to react as fresh resi...
Embodiment 2
[0029] The water quality of the biochemical effluent of a medium-sized chemical wastewater treatment plant is shown in Table 2. After adjusting the pH value to 6, ferrous sulfate and hydrogen peroxide were sequentially added to the water sample for Fenton oxidation to make Fe 2+ Concentration is 2.5mmol / L, H 2 o 2 The concentration is 4mmol / L, and the reaction time is 600 minutes. The Fenton oxidation effluent was reacted with the amine-modified magnetic ultra-high cross-linked composite functional resin accounting for 2% of the water volume, and after 600 minutes of reaction, solid-liquid separation was carried out. The water quality after separation is shown in Table 2. The regeneration is performed with a desorption liquid containing 10wt.% sodium hydroxide and 70wt.% methanol, and the regeneration time is 180 minutes. Regenerated resin continues to react as fresh resin. The waste water of this plant complies with the recycled water reuse standard, which is listed in T...
Embodiment 3
[0033]The water quality of the biochemical effluent of a medium-sized chemical wastewater treatment plant is shown in Table 3. After adjusting the pH value to 7, ferrous sulfate and hydrogen peroxide were added to the water sample for Fenton oxidation to make Fe 2+ Concentration is 2mmol / L, H 2 o 2 The concentration is 4.5mmol / L, and the reaction time is 400 minutes. Fenton oxidation effluent was reacted with amine-modified magnetic ultra-high cross-linked composite functional resin accounting for 3% of water volume, and solid-liquid separation was carried out after 500 minutes of reaction. The quality of the effluent after separation is shown in Table 3. Regenerate with a desorption solution containing 18wt.% sodium hydroxide and 50wt.% methanol, and the regeneration time is 60 minutes. Regenerated resin continues to react as fresh resin. The waste water of this plant complies with the recycling standard of reclaimed water, which is listed in Table 3 with reference to th...
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